Ethylenediamine Tetracetic Acid

Ethylenediamine tetracetic acid (H4Y) undergoes ionization at four, different stages, namely ... 

Ethylenediamine tetracetic acid is found to be sparingly soluble in water ( 0.2% w/v) whereas its corresponding disodium salt is almost 50 times more soluble than the parent compound (solubility 10% w/v). Therefore, it is the disodium salt of EDTA which is normally used in complexometric titrations. 

These titrations arc used in the estimation of metal salts. Ethylenediamine tetracetic acid (EDTA) shown in Figure 3.10 is the usual titrant used. It forms stable 1 1 complexes with all metals except alkali metals such as sodium and potassium. The alkaline earth metals such as calcium and magnesium form complexes which are unstable at low pH values and are titrated in ammonium chloride buffer at pH 10. The general equation for the titration is ... 

Ethylenediamine Tetracetic Acid Diethylene Glycol Monobutyl Ether Acetate... 

Magnesium Nitrate may be detd by a gravimetric method, weighing Mg PgOf as the final product or by titrating an aliquot of the water extract with EDTA (Ethylenediamine-tetracetic Acid) at a pH of ca 10 using Eriochrome Black T indicator. This method is described in Ref 17, D90-5d, pi5... 

Xanthine (2,6-dihydroxy purine) sodium salt, ethylenediamine tetracetic acid (EDTA), superoxide dismutase 4980U mg-1, dialysis membrane (art. D-9777) supplied by Sigma (Milan). Xanthine oxidase 0.39 U mg 1 supplied by Fluka AG, Buchs (Switzerland). 

Ethylene diamine tetracetic acid Ethylenediamine tetracetic acid. TETRALON Allied Colloids... 

We noted in Chapter 10 two rather symmetrical arrangements of 7 nearest neighbours found in oxy- and fluoro-compounds of transition metals, namely, pentagonal bipyramidal (ZrF "), and monocapped trigonal prism (NbF ). The ions formed from ethylenediamine tetracetic acid and the closely related diamino cyclohexane acid are potentially sexadentate ligands, for there are 4 0 atoms and... 

Therefore, the overall reaction for the reduction of Cu(II) ions (usually chelated by an anion of ethylenediamine tetracetic acid Y4-) by formaldehyde—which exists dominantly in the form of methylene glycol and its anion—may be rewritten as follows (assuming that methylene glycol anion, and CuY(OH)3- [92] are reacting species in alkaline Cu(II)-EDTA solutions at pH 12-14) ... 

Acids Acetic EDTA (ethylenediamine/ tetracetic acid) Hydrochloric Hychofluoric Nitric Phosphoric Sulfuric... 

The two most useful titrimetric methods for the determination of the rare earths are the determination of Ce by the titration of Ce(IV) with a standard solution of some reducing reagent, commonly Fe(II), and the titration of the rare earths as a group with a complexing reagent such as ethylenediamine tetracetic acid, EDTA. 

Ethylenediamine Tetracetic Acid T richlorophenoxyacetate Ethyl 2-Hydroxypropanoate Ethyl Lactate... 

ETHYLENEDIAMINE TETRACETIC ACID (EDTA, VERSENE, SEQUESTRENE)... 

When a Ugand is used that can bond to several sites, it is referred to as a multi-dentate ligand. One of the most important examples is ethylenediamine tetracetic acid (EDTA) ... 

The schematic of the process is shown in Fig. 28.29. The manufacturing procedure is divided into five major steps the synthesis of azine, the removal of low boilers, high boilers separation, hydrolysis of azine, and the dehydration of hydrazine. The synthesis of azine requires a residence time of 7 hours. Ammonia, hydrogen peroxide, and methyl ethyl ketone (MEK) are fed into the reactors along with methanol and acetonitrile at about 50°C. Small amounts of the disodium salt of ethylenediamine tetracetic acid are added to the reactants. In the low-boilers removal step, the unreacted ammonia, MeOH, MEK, and acetonitrile are separated and recycled to the reactors. The high-boilers solution contains water, MEK-azine, and acetamide. The acetamide is formed in the following reaction ... 

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