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Environment Forming

Because of symmetry considerations, in both compounds the Fe(II) ion lies on the threefold axis and has an inversion centre. It is in an octahedral environment formed by six crystallographically related N-4 coordinating 1-tetrazole moieties. The almost perfect Oh symmetry for the FeN6 core is therefore present in the high-spin and low-spin state. Three bis(tetrazole)alkane ligands, in a bent syn conformation, link the Fe(II) centres to form reg-... [Pg.155]

Nitrites added to meat or fish products decompose easily in an acid environment, forming very reactive nitrosating agents ... [Pg.307]

Ullrafine particles (UFPs) of metal and semiconductor nitrides have been synthesized by two major techniques one is the reactive gas condensation method, and the other is the chemical vapor condensation method. The former is modified from the so-called gas condensation method (or gas-evaporation method) (13), and a surrounding gas such as N2 or NII2 is used in the evaporation chamber instead of inert gases. Plasma generation has been widely adopted in order to enhance the nitridation in the particle formation process. The latter is based on the decomposition and the subsequent chemical reaction of metal chloride, carbonate, hydride, and organics used as raw materials in an appropriate reactive gas under an energetic environment formed mainly by thermal healing, radiofrequency (RF) plasma, and laser beam. Synthesis techniques are listed for every heal source for the reactive gas condensation method and for the chemical vapor condensation method in Tables 8.1.1 and 8.1.2, respectively. [Pg.406]

Catalytic Site. The catalytic site of COMT is a rather simple environment formed by the metal ion and by the amino acids important for substrate binding and catalysis of the methylation reaction. [Pg.349]

A plasma is a globally neutral environment formed by atoms in equilibrium between their neutral and ionised (1 to 2%) state and by electrons (1018/cm3). Plasmas are considered the fourth state of matter. Essentially, plasmas that are inductively coupled are used in atomic emission analysis. The colour of the plasma depends on the gas used to form it. [Pg.274]

Let us consider that the solvent has nonoverlapping domains that have distinct static and dynamic characteristics. The diffusion in such a system can be considered as a random walk in a random environment formed by the independently relaxing domain [95], Hence the diffusions in three dimensions is the weighted average of the diffusion in all these different domains [84], The average diffusion D can then be written as... [Pg.146]

Other Chemical Methods These methods rely chiefly on destroying the foam stabilizer or neutralizing its effect through methods other than displacement and are applicable when the process will permit changing the chemical environment. Forms stabilized with alkali esters can be broken by acidification since the equivalent free... [Pg.129]

Miller has developed various short peptides containing 3-(l-imidazolyl)-(S)-alanine as the catalytic core these biomimetic enantioselective acyl transfer catalysts allow the formation of an acyl imidazolium intermediate in a chiral environment formed by folding of the peptide [109-123]. The first catalyst of this type to be reported was tripeptide 27 in 1998 [109]. This peptide incorporates a C-terminal (R)-methylbenzylamide to encourage order-inducing stacking interactions in the acylimidazolium intermediate (Scheme 8.6). [Pg.297]

High operational reliability when surrounded by an environment formed mainly by combustible dusts and a very high degree of dust ingress protection - this is the users experience over long periods and opens the field of application for p-enclosures in zones 11, or 21 and 22. [Pg.428]

Figure 8.3 Heating dusty olivine grains in a reducing environment forms forsterite grains with small iron-rich blebs ( Figure 8.3 Heating dusty olivine grains in a reducing environment forms forsterite grains with small iron-rich blebs (<l xm) toward the middle of the olivine grains and metallic globules (1—50 xm) in the glass matrix at the boundaries of the olivine grains. From Leroux et al. (2003).
Fe, common in surhcial oxic environments, forms hydroxides, complexes formerly called hmonite (a collection of mst-Uke precipitates, chemically designated as Fe(OH)3). The aggregate has now been shown to contain several oxyhydroxide species, FeOOH, and the oxides, hematite, Fe203, and magnetite, Fe304, and some new minerals have been identified (Schwertmann and Fitzpatrick, 1992, tables 1-3, pp. 10-11). [Pg.3998]

The transition from the paper environment to the early electronic environment was direct and intuitive. New computing models and technologies, however, are raising questions about the validity of this paradigm for complex information capture, access, and retention. In the current technology environment, forms, documents, data are not frozen, but dynamic and interactive. Communications and collaborations are as frequently machine to machine exchanges as direct human interactions. [Pg.2558]

The other interesting polar interaction involves Lys-40. The positive charge on the side chain of Lys-40 appears to interact with the isoprene tail of the retinol, with the NZ atom located above the plane of the conjugated 7r-electron field. The /3-ionone ring is located in a hydrophobic environment formed by the two helices and /3C-j8D and /3E-j8F turns. Eight water molecules were also identified in the cavity. All of them make hydrogen bonds to internal polar side chains or water molecules. [Pg.135]


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See also in sourсe #XX -- [ Pg.7 , Pg.21 , Pg.24 ]




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