Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Emission spectroscopy, lead

Trace-element analysis of metals can give indications of the geographic provenance of the material. Both emission spectroscopy (84) and activation analysis (85) have been used for this purpose. Another tool in provenance studies is the measurement of relative abundances of the lead isotopes (86,87). This technique is not restricted to metals, but can be used on any material that contains lead. Finally, for an object cast around a ceramic core, a sample of the core material can be used for thermoluminescence dating. [Pg.421]

In determining the purity or percentage of lead in lead and lead-base alloys, the impurities or minor components are deterrnined and the lead content calculated by difference. Quality control in lead production requires that the concentration of impurities meet standard ASTM specifications B29 (see Table 7). Analyses of the individual impurities are performed using various wet chemical procedures and instmmental methods such as emission spectroscopy. [Pg.52]

The potential energy surface [47] for this reaction (Fig. 5) shows many potentially competitive pathways, labeled A-F, leading to the two most exothermic product channels. Many of these pathways can be isotopically separated by reaction of 02 with HCCO in normal abundance, as diagramed in Fig. 5. Zou and Osbom used time-resolved Fourier transform emission spectroscopy to detect the CO and CO2 products of this reaction [47]. Rotationally resolved infrared (IR) spectroscopy can easily identify all the possible isotopologs. For example. Fig. 6 shows a single... [Pg.234]

The nuclear decay of radioactive atoms embedded in a host is known to lead to various chemical and physical after effects such as redox processes, bond rupture, and the formation of metastable states [46], A very successful way of investigating such after effects in solid material exploits the Mossbauer effect and has been termed Mossbauer Emission Spectroscopy (MES) or Mossbauer source experiments [47, 48]. For instance, the electron capture (EC) decay of Co to Fe, denoted Co(EC) Fe, in cobalt- or iron-containing compormds has been widely explored. In such MES experiments, the compormd tmder study is usually labeled with Co and then used as the Mossbauer source versus a single-line absorber material such as K4[Fe(CN)6]. The recorded spectrum yields information on the chemical state of the nucleogenic Fe at ca. 10 s, which is approximately the lifetime of the 14.4 keV metastable nuclear state of Fe after nuclear decay. [Pg.413]

IR emission spectroscopy makes use of the reciprocal effect of IR absorption spectroscopy. At temperatures above 0 °K, molecules undergo a number of vibrational, vibrational-rotational or purely rotational movements. The relaxation of these excited states leads to the emission of thermal radiation, primarily in the IR region. [Pg.124]

Emission spectroscopy has been employed for the analysis of various alloys, namely aluminium, copper, magnesium, zinc, lead, and tin. [Pg.368]

Step-V The thermal excitation of some atoms into their respective higher energy levels will lead ultimately to a condition whereby they radiate energy (flame emission) measured by Flame Emission Spectroscopy (FES), and... [Pg.371]

Emission Spectroscopy (ICP-MS-ES). Cadmium, uranium and molybdenum are anomalous over part of the Lisbon field and most of the Lightning Draw Southeast field (Fig. 4). Mercury, lead and organic carbon are also anomalous over both fields. [Pg.391]

An easy calibration strategy is possible in ICP-MS (in analogy to optical emission spectroscopy with an inductively coupled plasma source, ICP-OES) because aqueous standard solutions with well known analyte concentrations can be measured in a short time with good precision. Normally, internal standardization is applied in this calibration procedure, where an internal standard element of the same concentration is added to the standard solutions, the samples and the blank solution. The analytical procedure can then be optimized using the internal standard element. The internal standard element is commonly applied in ICP-MS and LA-ICP-MS to account for plasma instabilities, changes in sample transport, short and long term drifts of separation fields of the mass analyzer and other aspects which would lead to errors during mass spectrometric measurements. [Pg.193]

Approximate contents of 14 minor and trace elements in oils produced from three coals by the catalytic hydrogenation process of Gulf Research and Development Co. were determined by emission spectroscopy. The results were compared with corresponding data for the original coals and the solid residues from the process. The contents of ash, sulfur, vanadium, lead, and copper are near or below the limits specified for an oil to be fired directly in a gas turbine while sodium and probably calcium are too high. Titanium appears to be somewhat enriched in the oils analyzed relative to other elements, suggesting its presence in organo-metallic complexes. [Pg.196]

The total salt concentration was 0.100 (to.010) N, known to three significant figures. At the high end of the isotherm, the starting solution contained only the ingoing cation at the low end, the solution contained both of the exchanging cations. The equilibrations were carried out for a minimum of three days in a New Brunswick Scientific Company AQUATHERM Water Bath Shaker at 5°, 25°, and 50°C, with temperature control to i0.5°C. Prior to analysis of the equilibrium solutions, the solid and solution phases were rapidly separated by filtration through a Millipore filter immediately after removal from the constant temperature bath. Lead and sodium analyses of the filtrate were obtained by atomic absorption spectroscopy. The cadmium analyses of the filtrate were obtained by plasma emission spectroscopy. These analyses showed that two Na+ ions entered the solution for every Cd2+ or Pb2+ that left ( 2%). [Pg.188]

Adsorption capacities were studied -by Atomic Emission Spectroscopy (Vista-Pro ICP-OES from VARIAN) for lead analysis and -by UV Spectrometry (Nicolet Evolution 300 from ThermoElectron Corporation) for p-nitrophenol determination. [Pg.214]

Atomic emission spectroscopy Arsenic, antimony, lead, hthium, mercury, thallium... [Pg.46]

Figure 7 Principle of field electron emission spectroscopy, (a) Electrons in a free electron solid occupy states of surface density N(E) (i), tunnel through a triangular barrier (ii), to yield a TED spectrum (iii), and R(E) of unity (iv). (b) The enhanced density of occupied states lying AE below Fermi level Ef (i), produced by the broadened level of adatom A (ii), leads to change in the TED (iii), and a resultant peak in R(E) at AE below Ef (iv)... Figure 7 Principle of field electron emission spectroscopy, (a) Electrons in a free electron solid occupy states of surface density N(E) (i), tunnel through a triangular barrier (ii), to yield a TED spectrum (iii), and R(E) of unity (iv). (b) The enhanced density of occupied states lying AE below Fermi level Ef (i), produced by the broadened level of adatom A (ii), leads to change in the TED (iii), and a resultant peak in R(E) at AE below Ef (iv)...

See other pages where Emission spectroscopy, lead is mentioned: [Pg.85]    [Pg.857]    [Pg.443]    [Pg.448]    [Pg.455]    [Pg.294]    [Pg.7]    [Pg.367]    [Pg.46]    [Pg.413]    [Pg.115]    [Pg.312]    [Pg.62]    [Pg.308]    [Pg.184]    [Pg.523]    [Pg.295]    [Pg.19]    [Pg.126]    [Pg.224]    [Pg.172]    [Pg.201]    [Pg.185]    [Pg.110]    [Pg.294]    [Pg.1962]    [Pg.668]    [Pg.309]    [Pg.205]    [Pg.3808]    [Pg.227]    [Pg.85]    [Pg.113]    [Pg.166]   
See also in sourсe #XX -- [ Pg.12 ]




SEARCH



Emission spectroscopy)

Lead emissions

© 2024 chempedia.info