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Electron mobility geometry

The variation in the measured electron mobilities from sample to sample in sintered materials (also observed by Hahn, ref. 24), may be due to any of several effects. The most probable reason for this variation in the well-sintered samples studied is a difference in history the individual samples are obtained with different numbers of conduction electrons per cm. frozen in in the necks. That is, the different history has allowed different amounts of oxygen to be adsorbed on the surface. Thus the concentration of electrons in the grain, as measured by the Hall coefficient, will have little relation to the concentration of electrons in the neck, as measured by the conductivity, and the mobility, obtained from the product of the Hall coefficient and the conductivity, will be neither the true mobility nor constant from sample to sample. The different samples may also end up with varying geometry of their necks, according to their previous treatment. [Pg.276]

As we can see from the Table all the three chains (and this is the case also for further two other polyacetylene and three polydiacetylene chains (7) which also have been calculated) have broad valence and conduction bands with widths between 4.4 and 6.5 eV-s. Comparing the band structure of the two polyacetylene chains we can find that the position of the bands and their widths is not very strongly influenced by the different geometries. This is again the case if we compare the here not described band structures of the further polyacetylene and polydiacetylene chains. On the other hand the position of the valence and conduction bands and the widths of the valence bands of the polydiacetylene chains is more different from those of the polyacetylene chains. To conclude we can say that due to the broad valence and conduction bands of these systems (which mean rather large hole and electron mobilities,respectively) one can expect that if doped with electron acceptors or donors these systems will become good conductors, which is, as it is experimentally estab-... [Pg.74]

Equation (8) describes the state when the MOSFET is shut, Eq. (9) the saturated state (Id independent of the drain-source voltage difference, Uds), and Eq. (10) the unsaturated region of the characteristic. The constant Kj depends on the electron mobility in the channel, its geometry and the capacitance of the gate insulator. [Pg.374]

To characterize dendrimers, analytical methods used in synthetic organic chemistry as well as in macromolecular chemistry can be applied. Mass spectrometry and NMR spectroscopy are especially useful tools to estimate purity and structural perfection. To get an idea of the size of dendrimers, direct visualization methods such as atomic force microscopy (AFM) and transmission electron microscopy (TEM), or indirect methods such as size exclusion chromatography (SEC) or viscosimetry, are valuable. Computer aided simulation also became a very useful tool not only for the simulation of the geometry of a distinct molecule, but also for the estimation of the dynamics in a dendritic system, especially concerning mobility, shape-persistence, and end-group disposition. [Pg.13]


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