Electron mixed

In the second step the angular momentum of the Rydberg molecule may be randomized in collisions with ambient electrons (/-mixing and possibly m-mixing),... 

A simple situation concerns the 18-electron mixed-ligand complexes [MsLL ] whose oxidation potential was shown [19] to be the average of those of the corresponding complexes with two identical (L or L ) ligands, [MsL2] and [MsL (Eq. 8), provided that the metal sites MsL and MsL present analogous polarizabilities. 

Average squared electronic mixing between donor and acceptor... 

Fig. 13.18. Heterodyne mixed signals from ultrasonic vibration around 9 MHz of the sample and the cantilever, with difference frequencies (a) 5 kHz, (b) 15 kHz. The upper traces are from conventional electronic mixing of the excitation waveforms, the lower signals are from the cantilever response, with mixing occurring mechanically at the tip-sample contact. The electronically mixed waveforms were rectangular, giving rise to the triangular beat waveforms (Kolosov and Briggs 1996).

Fig. 9.23. Square-well model for electronic mixing between two discrete states. The displacement toward resonance is derived from modulation of the energy levels by the coupling of the electronic levels to the nuclear motion of the surrounding medium. In configuration A, the electron is localized at the donor site B corresponds to the condition of quantum resonance between the two states C corresponds to the nuclear configuration in which the electron becomes localized on the acceptor site (Reprinted from R. J. D. Miller, G. McLendon, A. J. Nozik, W. Schmickler, and F. Willig, Surface Electron Transfer Processes, p. 4, copyright 1995 VCH-Wiley. Reprinted by permission of John Wiley Sons, Inc.)...

First, as the donor binding energy decreases from Fe1 to Zn1, the electronic mixing, expressed in the dependence of rate on distance k exp-(oR) should change. In tl simplest barrier tunneling theory a s (IP. - IP. . ) For this theory, then,... 

Heyduk, A. F. Nocera, D.G. Hydrogen produced from hydrohalic acid solutions using a two-electron mixed-valence photocatalyst. Science 2001, 293,1639. 

Rosenthal J, Bachman J, Dempsey JL, et al. Oxygen and hydrogen photocatalysis by two-electron mixed-valence coordination compounds. Coord Chem Rev 2005 249 1316-26. 

Various alternatives to the conventional one-electron photochemistry were reviewed recently [116,122], A rational framework for advancing the multi-electron photochemistry of new metal complexes has been developed using two-electron mixed-valence complexes as the redox platform. Two-electron mixed valence is a useful design concept for hydrogen and oxygen photocatalysis. As single-electron... 

Esswein AJ, Veige AS, Nocera DG. A photocycle for hydrogen production from two-electron mixed-valence complexes. / Am Chem Soc 2005 127 16641-51. 

The one-electron mixed valence world defined by Henry Taube... 

Can a two-electron (and four) chemistry be uncovered with two-electron mixed valency ... 

The spin-orbit interaction associated with the unpaired pn core electron mixes the 3IIi and 1IIi components of the same n value (AO = 0). In the case (a) basis, the secular equation is [see Eq. (3.4.14)]... 

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