Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Rational efficiency

To conclude, the models proposed below are in good agreement with the empirical data and allow a first approach to an efficient rational design of homochiral bases. However, they only take the major NMR or X-ray observable solution HCLA complexes into consideration minor aggregates involving allylic alcoholate or protonated amine products, that might be reactive and contribute to the product formation, are ignored ... [Pg.1183]

It is incumbent that all health care workers, and nurses in particular, react professionally, efficiently, rationally, and effectively when disaster strikes. To do so, they need some fundamental principles and knowledge... [Pg.674]

Equation (4-95) provides efficient rationalization of the cooling fluid s temperature profile in the limit as /c 0 at constant /Joutside- This corresponds to pure heat exchange between the cooling fluid and the surroundings when the inner pipe does not exist. Hence, (4-95) reduces to ... [Pg.95]

One class of Al-based computational chemistry programs are de novo programs. These programs generally try to efficiently automate tedious tasks by using some rational criteria to guide a trial-and-error process. For example. [Pg.109]

Structural drawings of carbohydrates of this type are called Haworth formulas, after the British chemist Sir Walter Norman Haworth (St Andrew s University and the University of Birmingham) Early m his career Haworth contributed to the discovery that carbohydrates exist as cyclic hemiacetals rather than m open chain forms Later he col laborated on an efficient synthesis of vitamin C from carbohydrate precursors This was the first chemical synthesis of a vitamin and provided an inexpensive route to its prepa ration on a commercial scale Haworth was a corecipient of the Nobel Prize for chem istry m 1937... [Pg.1034]

Based on the Monte Carlo simulations, it is seen that the presence of positional disorder causes the mobiUty to decrease with increasing field at low fields (37). This is the case because the introduction of positional disorder into the system provides the carrier with energetically more favorable routes, which occasionally are against the field direction. These detour routes are most efficient at low fields, but are eliminated at high fields. This rationalizes the decrease of hole mobilities with increasing field. [Pg.412]

Chemoinformatics (or cheminformatics) deals with the storage, retrieval, and analysis of chemical and biological data. Specifically, it involves the development and application of software systems for the management of combinatorial chemical projects, rational design of chemical libraries, and analysis of the obtained chemical and biological data. The major research topics of chemoinformatics involve QSAR and diversity analysis. The researchers should address several important issues. First, chemical structures should be characterized by calculable molecular descriptors that provide quantitative representation of chemical structures. Second, special measures should be developed on the basis of these descriptors in order to quantify structural similarities between pairs of molecules. Finally, adequate computational methods should be established for the efficient sampling of the huge combinatorial structural space of chemical libraries. [Pg.363]

A computer program is provided for ease of calculation and efficient use of the standard. This rational method of assessing hot environments allows identification of the relative importance of different components of the thermal environment, and hence can be used in environmental design. The WBGT index is an empirical index, and it cannot be used to analyze the influence of the individual parameters. The required sweat rate (SW. ) has this capability, but lack of data may make it difficult to estimate the benefits of protective clothing. [Pg.385]

For an open circuit (non-cyclic) gas turbine plant (Fig. 1.3) a different criterion of performance is sometimes used—the rational efficiency (tjr). This is defined as the ratio of the actual work output to the maximum (reversible) work output that can be achieved between the reactants, each at pressure (po) and temperature (To) of the environment, and products each at the same po. Tq. Thus... [Pg.6]

AGo] is not readily determinable, but for many reactions [—A/fol is numerically almost the same as [—AGq]. Thus the rational efficiency of the plant is frequently approximated to... [Pg.6]

Many preliminary analyses of gas turbines are based on the assumption of a closed air standard cyclic plant, and for such analyses the use of tj as a thermal efficiency is entirely correct (as discussed in the early part of Chapter 3 of this book). But most practical gas turbines are of the open type and the rational efficiency should strictly be used, or at least its approximate form, the arbitrary overall efficiency tjq. We have followed this practice in the latter part of Chapter 3 and subsequent chapters even though some engineers consider this differentiation to be a somewhat pedantic point and many authors refer to tjo as a thermal efficiency (or sometimes the lower heating value thermal efficiency ). [Pg.6]

The work output and rational efficiency of an open circuit gas turbine... [Pg.24]

The rational efficiency may be defined as the ratio of the actual work output [Wcvlx to the maximum possible work output, approximately [—AGq],... [Pg.25]

There is an apparent paradox here that as the cooled cycle contains an irreversible process (constant pressure mixing), its efficiency might be expected to be lower than the original uncooled cycle. The answer to this paradox follows from consideration of all the irreversibilities in the cycle and we refer back to the analysis of Section 3.2.1.1, for the rational efficiency of the [CHT]ru cycle. The irreversibility associated with the heat supply is unchanged, as given in Eq. (3.3), but the irreversibility associated with the heat rejection between temperatures T(, and T) = Ta becomes... [Pg.51]

Young and Wilcock [7] have recently provided an alternative to this simple approach. They also follow step (a), but rather than obtaining as in (b) they determine the constituent entropy increa.ses (due to the various irreversible thermal and mixing effects). Essentially, they determine the downstream state from the properties To and the entropy. v, rather than T), and po- This approach is particularly convenient if the rational efficiency of the plant is sought. The lost work or the irreversibility ( f = "lay be subtracted... [Pg.60]

Subsequently, we refer briefly to other comparable studies, including the calculations of exergy losses and rational efficiency. Finally, we show the real gas exergy calculations for two practical plants—[CBT]i and [CBTX]i. [Pg.71]

Nevin, R. and Watson, G. (1998). Evidence of Rational Market Valuations lor Home Energy Efficiency. The Appraisal Journal (October) 4U1-4U9. [Pg.211]


See other pages where Rational efficiency is mentioned: [Pg.343]    [Pg.245]    [Pg.4]    [Pg.416]    [Pg.343]    [Pg.245]    [Pg.4]    [Pg.416]    [Pg.2341]    [Pg.29]    [Pg.318]    [Pg.295]    [Pg.337]    [Pg.675]    [Pg.188]    [Pg.22]    [Pg.51]    [Pg.60]    [Pg.82]    [Pg.83]    [Pg.83]    [Pg.15]    [Pg.431]    [Pg.40]    [Pg.126]    [Pg.441]    [Pg.445]    [Pg.63]    [Pg.132]    [Pg.139]    [Pg.325]    [Pg.378]    [Pg.488]   
See also in sourсe #XX -- [ Pg.6 , Pg.22 , Pg.24 ]




SEARCH



Rational

Rationalism

© 2024 chempedia.info