Effect of organic phase

Fan, W. Tsai, R. S. El Tayar, N. Carrupt, P.-A. Testa, B, Solute-water interactions in the organic phase of a biphasic system. 2. Effects of organic phase and temperature on the water-dragging effect, J. Phys. Chem. 98, 329-333 (1994). 

The effect of organic phase continuous versus aqueous phase continuous operation... 

Figure 4. Effect of organic-phase composition on distribution of benzene and nitrobenzene between phases at 33°C (acid phase was 20 mole % sulfuric add)...

Birnbaum DT, Kosmala JD, Henthorn DB, Brannon-Peppas L. Controlled release of beta-estradiol from PLAGA microparticles The effect of organic phase solvent on encapsulation and release. Journal of Controlled Release. April 3, 2000 65(3) 375-387. PubMed PMID 10699296. 

R. S. Tsai, W. Fan, N. El Tayar, P.-A. Carrupt, and B. Testa, /. Phys. Chem., 98,329 (1994). Solute-Water Interactions in the Organic Phase of a Biphasic System. 11. Effects of Organic Phase and Temperature on the Water-Dragging Effect. 

Relationships connecting stmcture and properties of primary alkylamines of normal stmcture C, -C gin chloroform and other solvents with their ability to extract Rh(III) and Ru(III) HCA from chloride solutions have been studied. The out-sphere mechanism of extraction and composition of extracted associates has been ascertained by UV-VIS-, IR-, and H-NMR spectroscopy, saturation method, and analysis of organic phase. Tertiary alkylamines i.e. tri-n-octylamine, tribenzylamine do not extract Ru(III) and Rh(III) HCA. The decrease of radical volume of tertiary alkylamines by changing of two alkyl radicals to methyl make it possible to diminish steric effects and to use tertiary alkylamines with different radicals such as dimethyl-n-dodecylamine which has not been used previously for the extraction of Rh(III), Ru(III) HCA with localized charge. 

The volumetric ratio of the two liquid phases (j6 = Forg/ Faq) can affect the efficiency of substrate conversion in biphasic media. The biocatalyst stability and the reaction equilibrium shift are dependent on the volume ratio of the two phases [29]. In our previous work [37], we studied the importance of the nonpolar phase in a biphasic system (octane-buffer pH 9) by varying the volume of solvent. The ratio /I = 2/10 has been the most appropriate for an improvement of the yield of the two-enzyme (lipase-lipoxygenase) system. We found that a larger volume of organic phase decreases the total yield of conversion. Nevertheless, Antonini et al. [61] affirmed that changes in the ratios of phases in water-organic two-phase system have little effect upon biotransformation rate. 

McCalley, D. V., Effect of organic solvent modifier and nature of solute on the performance of bonded silica reversed-phase columns for the analysis of strongly basic compounds by high-performance liquid chromatography, /. Chromatogr A, 738(2), 169, 1996. 

Taking into consideration its physico-chemical properties, removal efficiencies, low biodegradability, predicted environmental levels, toxicity, and the need to provide sufficient safety margins for aquatic organisms, the demand for alternative cationic surfactants arose. Since 1991, DTDMAC has been replaced in some European countries due to producer s voluntary initiatives with new quaternary ammonium compounds, the esterquats. These contain an ester function in the hydrophobic chain (Table 1.3) that can be easily cleaved, releasing intermediates that are susceptible to ultimate degradation [24-26]. The effects of the phasing-out and replacement of DTDMAC can be demonstrated by the results of a Swiss study, where the surfactant... 

EFFECT OF LIQUID PHASE COMPOSITION ON BURNING RATE. Many of the evaporation constants for drops of pure organic compounds burning in air at 20° C. are in the range 0.0070 to 0.0110 sq. cm. per second (Table IV). Values for some of the lighter petroleum fractions also fall in this range. 

In sub-FC, a detailed study of the influence of mobile phase additives on the chiral resolution of isoxazoline-based Ilb/IIIb receptor antagonists was carried out by Blackwell [145] on Chiralcel OD-H CSPs. The different mobile phase additives used were acetic acid, trifluoroacetic acid, formic acid, water, triethylamine, triethanolamine, n-hexylamine, trimethyl phosphate, and tri-w-butyl phosphate. In general, n-hexylamine and tri-/ -butyl phosphate mobile phase additives resulted in better resolution. The chiral separation of four 1,3-dioxolane derivatives on an amylose-based column has been described [151]. The effects of mobile phase composition, temperature, and pressure have been investigated. The nature of the modifier is the main parameter it has the highest impact on chiral resolution and is more important than the polarity of the mobile phase. Therefore, the organic modifier that gave the best enantiomeric separation was different for each compound. 

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