Edge weakness

Niklas [42] discusses edge weaknesses in nickel electroformed sieves due to acute angle comers. Additives used during photo-etching increases these defects [43] Stork [44] also describe sieve preparation by electrodepositing a thin metal skeleton on to a substrate, removal of the skeleton from the substrate, followed by deposition of two or more layers of metal on both sides of the substrate. Additives encourage growth perpendicular to the surface of the skeleton. 

FIGURE 4.52 Edge weakness and the formation of blowholes when molding narrow grooves (a) model (b) nickel layer (c) edge weakness (d) formation of blowholes ... 

When molding narrow slits, the risk of a blowhole formation is added to the angle or edge weakness. The problem can be bypassed by using steel pieces to be galvanized, which are previously inserted into models. 

The electroplating of ejector and slide openings would also cause edge weakness. In order to avoid these problems, it is recommended to subsequently incorporate, mechanically or through spark erosion, bore holes and breaktroughs for sliders, ejectors, etc., (see Figure 4.53). The gate channels should be subsequently manufactured. 

Fig. 3.16 The efect of introducing a weak potential into the ID lattice is to lift the degeneracy of the energy levels mar to the edge of the Brillouin zone (shown in both extended-zone and reduced-zone representation).

These aspects of the optical spectra of solids are illustrated in the upper portion of Figure 1, which displays the reflectance curve (R) at room temperature for a typical semiconductor, GaAs. The fundamental absorption edge around 1.4 eV produces only a weak shoulder. Some structure is apparent in the two features around 3 eV and the large, broad peak near 5 eV. However, the dominant aspect of the line shape is the slowly varyii background. The derivative namre of Modulation Spectroscopy suppresses the uninteresting background effects in favor of sharp, deriva-... 

Extended energy-loss fine structures (EXELES) are analogous to the EXAES effect observed in X-ray absorption [2.224, 2.225]. These weak modulations (cf Eig. 2.39a), still observable ca. 100 eV away from the edge onset, occur because the excited elec-... 

Another special case of weak heterogeneity is found in the systems with stepped surfaces [97,142-145], shown schematically in Fig. 3. Assuming that each terrace has the lattice structure of the exposed crystal plane, the potential field experienced by the adsorbate atom changes periodically across the terrace but exhibits nonuniformities close to the terrace edges [146,147]. Thus, we have here another example of geometrically induced energetical heterogeneity. Adsorption on stepped surfaces has been studied experimentally [95,97,148] as well as with the help of both Monte Carlo [92-94,98,99,149-152] and molecular dynamics [153,154] computer simulation methods. 

The small and weakly time-dependent CPG that persisLs at longer delays can be explained by the slower diffusion of excitons approaching the localization edge [15]. An alternative and intriguing explanation is, however, field-induced on-chain dissociation, a process that does not depend on the local environment but on the nature of the intrachain state. The one-dimensional Wannier exciton model describes the excited state [44]. Dissociation occurs because the electric field reduces the Coulomb barrier, thus enhancing the escape probability. This picture is interesting, but so far we do not have any clear proof of its validity. 

The rate and mechanism are different on the basal plane and edge sites of carbon. The reactions involving oxygen are two to three orders of magnitude slower on the basal plane than on the edge sites, because of the weak adsorption of oxygen molecules on the basal plane surface [34]. 

---