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Dirty Shift

FeS also catalyzes the shift reaction, but its activity is only half that of Fe,04 [592]-[594], In principle the catalyst can tolerate up to 500 or 1000 ppm H2S, but with a considerable loss of mechanical strength, which is additionally affected by other contaminants in the gas, such as soot and traces of formic acid. For this reason the so-called dirty shift catalyst is used in this case, which was originally introduced by BASF [639]. This cobalt-molybdenum-alumina catalyst [603], [630], [640]-[644] is present under reaction conditions in sulfidized form and requires for its performance a sulfur content in the gas in excess of 1 g S/m3. Reaction temperatures are between 230 and 500 °C. COS is not hydrolyzed on dirty shift catalysts, but may be removed in the subsequent sour-gas removal stage using the Rectisol process. Separate hydrolysis on alumina based catalysts is possible at temperatures below 200 °C [603],... [Pg.120]

In later developments aditionally potassium carbonate promotion of the dirty shift catalysts was introduced [645], [646] which increased the activity at low temperatures to achieve CO values sufficiently low to use a methanation step after C02 removal. But according to [647] it is also possible to achieve such low CO concentrations with nonalkalized dirty shift catalyst as shown in Figure 65. [Pg.120]

Equations to describe reaction rate measurements on dirty shift catalyst are given in [648], [649],... [Pg.120]

Where dirty or wet processing occurs continuously within a building, personnel at the end of the day or shift may consider the provision of baths and showers for use. [Pg.59]

The latter half of this equation will ultimately shift for Newman the Jews history comes to seem neither alien nor dirty, as his own victimization as a Jew forces the realization that racial Jewishness is not the stable essence he had always supposed, but a highly unstable categorical convention based upon certain social practices and ways of seeing. By the novel s end Newman the sometime anti-Semite could perhaps say of the Jews, after Theodore H erzl, We are one people—our enemies have made... [Pg.203]

Doppler ultrasonic flowmeters depend upon the reflection of a continuous ultrasonic wave (frequency 0.5-10 MHz) from particulate matter (scatterers) contained in the fluid. Hence they may be used to monitor the rate of flow of dirty liquids. The transducer involved can act both as transmitter and receiver and is generally of the clamp-on type (Fig. 6.4). If the scatterers can be assumed to be moving at the velocity of the liquid, then the volumetric rate of flow Q is related to the Doppler frequency shift AtoD by ... [Pg.444]

NG from the North Sea, is following the same pattern as oil. Still, production from NG reserves in Norway, a member of the European Economic Area, may represent 23 years of consumption at current levels. However, we should consider that, on the one hand, consumption of NG is likely to increase in result of a partial shift from dirty fossil fuel to a somewhat cleaner NG is some applications, including transportation. [Pg.87]

Now, much of the emphasis, in terms of national security, has shifted to the use of unconventional weapons unleashed on civilian targets by terrorists. Sometimes referred to as superterrorism, this includes the possible use of nuclear (that is, a fission-reaction explosion), radiological (as in the so-called dirty bomb), biological, or chemical weapons. In the context of terrorism, this chapter concerns itself with the latter two types. [Pg.366]

Certainly, at the beginning of our DCM inspired process at University of Nevada, Reno, rubric was almost a dirty word. However, our focus groups and subsequent star rubric (yes, we have embraced the word) have become a source of pride for our assessment. The shift from avoidance to acceptance was spurred by the conversations among instructors regarding what they needed to assess portfolios for programmatic purposes. The star rubric that resulted from hours of dialogue provides a way for all of our audiences to benefit from the assessment results. McBride and Detweiler... [Pg.42]

A zero degree corresponds to a constant shift of absorbance, encountered when the spectrophotometric cell is dirty, for example. [Pg.41]

In other words, the scene started with the excited shout, "Hurry up, the bus is here," and ended with "Look at the water " Like shots, sequences, and acts, scenes like this contain a beginning, middle, and end, and often, they culminate in a reversal, called a turning point, that motivates a shift in action of the overall story. Here, the reversal ties in with some of the film s themes. Boarding a bus in a congested, dirty city, the children arrive at the bright, open seaside. This reversal motivates the next scene—enjoying and photographing the beach. [Pg.53]

The removal of sand from internal scrap can be applied in all new and existing foimdries. The use of clean scrap for melting can be applied in all foimdry t3 es, but the choice of the scrap grade should be related to the techniques installed for melting and gas cleaning. If the whole sector shifts to clean scrap, this will generate a problem for the recycling of dirty scrap. [Pg.151]

Shift difficulty or can not shift Large free stroke of clutch pedal clutch Pipe has air Failure of clutch cylinder Failure of clutch master cylinder The installation position of clutch disc is not in position large deviation oil on the friction lining or broken The clutch disc is dirty or with foreign material Failure of clutch cover Adjust the free stroke of pedal Disehaige the air in clutch system Replaee replace Inspect the clutch disc replace Repair if necessary Replace... [Pg.32]

Figure 29 Top SANS data and form factor fits of a PNIPMAM-PNIPAM(50/50) copolymer microgel in D2O at different temperatures two data sets are shifted verticaiiy. Bottom schematic drawing of the internal nanophase-separated dirty snowball morphology of the PNIPMAM-PNIPAM(50/50) copoiymer microgei in D2O at the transition temperature. Note that the fuzziness of the microgel surface is not illustrated. Figure 29 Top SANS data and form factor fits of a PNIPMAM-PNIPAM(50/50) copolymer microgel in D2O at different temperatures two data sets are shifted verticaiiy. Bottom schematic drawing of the internal nanophase-separated dirty snowball morphology of the PNIPMAM-PNIPAM(50/50) copoiymer microgei in D2O at the transition temperature. Note that the fuzziness of the microgel surface is not illustrated.
The 3200 person strong workforce on Ikamva Shaft are lowered and raised through the 2 vertical shafts on a 3 shift system daily. The chilled hydropower water at a temperatare of 1 degree Celsius is fed down the shafts at a rate of 250 litres per second during peakhoms. Dirty water is pumped to surface via 4 in line major pump systems at a rate of 14 mega htres per day. [Pg.546]

Fig. 23. Measured shifts (meV) in the leading edges of the photoemission spectra for four samples, taken at cro.ssings along the Fermi surface, plotted relative to the quantity (cos, -cosA /2. Samples X III, X vn, and X III 2 exliibit strong linear correlations, consistent with an order parameter having d 2 symmetry. The extended region of zero shift in sample X V may be indicative of dirty d-wave behavior. Fig. 23. Measured shifts (meV) in the leading edges of the photoemission spectra for four samples, taken at cro.ssings along the Fermi surface, plotted relative to the quantity (cos, -cosA /2. Samples X III, X vn, and X III 2 exliibit strong linear correlations, consistent with an order parameter having d 2 symmetry. The extended region of zero shift in sample X V may be indicative of dirty d-wave behavior.

See other pages where Dirty Shift is mentioned: [Pg.105]    [Pg.132]    [Pg.150]    [Pg.105]    [Pg.132]    [Pg.150]    [Pg.208]    [Pg.254]    [Pg.102]    [Pg.2]    [Pg.637]    [Pg.6]    [Pg.275]    [Pg.89]    [Pg.91]    [Pg.55]    [Pg.181]    [Pg.285]    [Pg.141]    [Pg.128]    [Pg.33]    [Pg.125]    [Pg.253]    [Pg.163]    [Pg.196]    [Pg.69]    [Pg.534]    [Pg.88]    [Pg.4477]    [Pg.4583]    [Pg.67]    [Pg.49]    [Pg.133]    [Pg.254]   
See also in sourсe #XX -- [ Pg.150 ]




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