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Quinoline, 2,3-Dimethyl

These effects are not entirely understood because cyclizations forming 5,8-dimethyl quinolines are not problematic as shown below by the conversion of 46 into 47. [Pg.395]

Derivatives. Small amounts of alkyl quiaolines are present ia the tars resulting from the carbonization and Hquefaction of coal (111). Good yields of 4-methyl quinoline, 4,6-dimethyl quinoline [826-77-7], and 4,8-dimethyl quinoline [13362-80-6] are obtained from 4-(diethylamino)-2-butanone and the appropriate aniline. This approach is a promising addition to the traditional syntheses discussed eadier (112). Vlaylacetylene reacts with mercuric chloride and either aniline or -toluidine to yield 4-methyl- and 4,6-dimethyl quinoline, respectively (113). [Pg.395]

Blocking of reaction sites The interaction of adsorbed inhibitors with surface metal atoms may prevent these metal atoms from participating in either the anodic or cathodic reactions of corrosion. This simple blocking effect decreases the number of surface metal atoms at which these reactions can occur, and hence the rates of these reactions, in proportion to the extent of adsorption. The mechanisms of the reactions are not affected and the Tafel slopes of the polarisation curves remain unchanged. Behaviour of this type has been observed for iron in sulphuric acid solutions containing 2,6-dimethyl quinoline, /3-naphthoquinoline , or aliphatic sulphides . [Pg.811]

The effects of substituents in the ring undergoing substitution have also been measured in the cyclisation of 4-anilino-pent-3-en-2-ones to give 2,4-dimethyl-quinoline and its derivatives377-380, viz. [Pg.161]

Reduction of the heterocyclic ring and incorporation of a nitro function affords a compound with antischistosomal activity, oxamniquine (60). Its synthesis begins with chlorination of 2,6-dimethyl-quinoline, which proceeds regiospecifically on the methyl group adjacent to the ring nitrogen (56). [Pg.372]

The reaction of o-aminobenzaldehyde with DMAD gives rise to dimethyl quinoline-2,3-dicarboxylate (28) [Eq. (11)]. Similarly, the... [Pg.287]

Chloro 2.2 dimethyl propionic acid dimethazone 7 Chloro 3.8 dimethyl quinoline quinmerac... [Pg.1029]

C11H9N03 indole-3-pyruvic acid 392-12-1 25.00 1.2743 2 21710 C11H11N 3,4-dimethyl quinoline 2436-92-2 20.86 1.0491 2... [Pg.256]

C11H9N05 ethyl 5-nitrobenzofuran-2-carboxylate 69604-00-8 25.00. 3780 2 21720 C11H11N 2,5-dimethyl quinoline 26190-82-9 20.86 1.0491 2... [Pg.256]

C11H11N 4,6-dimethyl quinoline 826-77-7 20.680 149.180 1,2 22403 C11H160 2-tert-butyl-6-methyl phenol 2219-82-1 17.068 171.152 1,2... [Pg.627]

Spinner and Yeoh42 have synthesized a number of 1,3-dihydro derivatives of the system. The starting point was dimethyl quinolinate N-oxide, which was converted by conventional reactions into the dichloro compound (20) and thence into 5-methoxy- and 5-hydroxy-1,3-dihydrothieno[3,4-A)pyridine (which exists predominantly in the 4H-5-one form see Section IV,G.). [Pg.78]

A widely used class of compounds are pyridine and alkylpyridines, including 2,6-lutidine, 2,4,6-coUidine, DTBP, quinoline, 4-methylquinohne, and 2,4-dimethyl-quinoline (565,582). These molecules interact with acidic hydroxyls through their N-atoms with formation of protonated species. Because they are strong bases, the possibility to extract protons from their original positions cannot be ruled out. An advantage (but in some cases disadvantage) of many pyri dines with bulky substituents is that, for steric reasons, they do not interact with Lewis acid sites through the N-atoms, or this interaction at least is hindered. [Pg.235]

C Hi,N]- CHj H Photoreduction of 2,4-dimethyl-quinoline/ CH3OH and CD3OH glasses EPR/ 77,113 71A111... [Pg.689]

The /-values on silica gel 6 layers, using chloroform, of quinoline and isoquinoline compounds show only small differences, with the sole exception of those between monomethyl- and dimethyl-quinolines, which are railier larger [28, 30]. A methyl group in the 8-position, however, reduces the adsorption affinity strongly (e. g., 2-methylquinoline hBf 16 8-methylquinoline 31 2,4-dimethylquinoline 8 2,8-dimethyl-quinoline 47). [Pg.505]

Cyclimmonium salts by aromatlzatlon. 1,2-Dihydro-1,2-dimethyl-quinoline... [Pg.630]

Evocarpine, 1 -methyl-2-[(Z)-tridec-7-enyl]quinolin-4(lH)-one, 1 -methyl-2-undecylquinolin-4(lH)-one, dihydroevocarpine, 1 -methyl-2-pentadecylquinolin (lH)-one, l-methyl-2-[(4Z,7Z)-tridec-4,7-dienyl]quinolin-4(lH)-one, and 1-methyl-2-[(6Z,9Z)-pentadec-6,9-dienyl]quinolin-4(lH)-one from Euodia ruticarpa (Table ID showed strong antibacterial activity against H. pylori, both in vitro and in vivo, by inhibiting respiration. The results reinforced previous indications of this class of alkaloids as novel, potential therapeutic agents for the treatment of ulcers, as shown above with the alkaloids from microbial sources (68,241-243). The related alkaloids l-methyl-2-n-nonylquinolin-4(lH)-one, 2-M-nonylquinolin-4(lH)-one, and l,2-dimethyl-quinolin-4(lH)-one from Boronia (Table II) showed mild to moderate activities against B. subtilis, S. aureus, Sarcina lutea, exterotoxigenic E. coli. Salmonella typhi, and Klebsiella sp. (244). [Pg.191]

The name found its origin in the fact that the first dyes known were all derived from quinoline as, for example, 2,2 -cyanine (Scheme 1). In the case of an asymmetrical or symmetrical dye involving one or two nuclei that are different from the quinoline ring, the name of the nucleus becomes the prefix in the name of the dye. So 3.3 -dimethyl-4-phenyl thiazolo cyanine is the dye of structure 1 and 3.1 -dimethyl 4-phenyl thiazolo 2 -cyanine is represented by the formula structure 2 (Scheme 2). [Pg.25]

As early as 1889 Walker (320), using samples of thiazole, 2,4-dimethylthiazoie, pyridine, and 2,6-dimethylpyridine obtained from Hantzsch s laboratory, measured the electrical conductivity of their chlorhydrates and compared them with those of salts of other weak bases, especially quinoline and 2-methylquinoline. He observed the following order of decreasing proton affinity (basicity) quinaldine>2,6-dimethyl-pyridine>quinoline>pyridine>2,4-dimethylthiazole> thiazole, and concluded that the replacement of a nuclear H-atom by a methyl group enhanced the basicity of the aza-aromatic substrates. [Pg.91]


See other pages where Quinoline, 2,3-Dimethyl is mentioned: [Pg.390]    [Pg.391]    [Pg.353]    [Pg.395]    [Pg.219]    [Pg.219]    [Pg.256]    [Pg.256]    [Pg.256]    [Pg.256]    [Pg.257]    [Pg.368]    [Pg.503]    [Pg.503]    [Pg.334]    [Pg.323]    [Pg.100]    [Pg.201]    [Pg.202]    [Pg.161]    [Pg.215]    [Pg.398]    [Pg.214]    [Pg.228]    [Pg.142]    [Pg.35]   
See also in sourсe #XX -- [ Pg.395 ]




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Quinoline 2.3- dimethyl-4-phenyl

Quinoline 4,6-dimethyl-, ring synthesis

Quinoline 5.8- dimethoxy-2,4-dimethyl

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