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Diffusion constant, time dependant

Figure C2.1.18. Schematic representation of tire time dependence of tire concentration profile of a low-molecular-weight compound sorbed into a polymer for case I and case II diffusion. In botli diagrams, tire concentration profiles are calculated using a constant time increment starting from zero. The solvent concentration at tire surface of tire polymer, x = 0, is constant. Figure C2.1.18. Schematic representation of tire time dependence of tire concentration profile of a low-molecular-weight compound sorbed into a polymer for case I and case II diffusion. In botli diagrams, tire concentration profiles are calculated using a constant time increment starting from zero. The solvent concentration at tire surface of tire polymer, x = 0, is constant.
Monte Carlo simulations require less computer time to execute each iteration than a molecular dynamics simulation on the same system. However, Monte Carlo simulations are more limited in that they cannot yield time-dependent information, such as diffusion coefficients or viscosity. As with molecular dynamics, constant NVT simulations are most common, but constant NPT simulations are possible using a coordinate scaling step. Calculations that are not constant N can be constructed by including probabilities for particle creation and annihilation. These calculations present technical difficulties due to having very low probabilities for creation and annihilation, thus requiring very large collections of molecules and long simulation times. [Pg.63]

The amplitude of the elastic scattering, Ao(Q), is called the elastic incoherent structure factor (EISF) and is determined experimentally as the ratio of the elastic intensity to the total integrated intensity. The EISF provides information on the geometry of the motions, and the linewidths are related to the time scales (broader lines correspond to shorter times). The Q and ft) dependences of these spectral parameters are commonly fitted to dynamic models for which analytical expressions for Sf (Q, ft)) have been derived, affording diffusion constants, jump lengths, residence times, and so on that characterize the motion described by the models [62]. [Pg.479]

Skaret presents a general air and contaminant mass flow model for a space where the air volume, ventilation, filtration, and contaminant emission have been divided for both the zones and the turbulent mixing (diffusion) between the zones is included. A time-dependent behavior of the concentration in the zones with constant pollutant flow rate is presented. [Pg.624]

We first consider the stmcture of the rate constant for low catalyst densities and, for simplicity, suppose the A particles are converted irreversibly to B upon collision with C (see Fig. 18a). The catalytic particles are assumed to be spherical with radius a. The chemical rate law takes the form dnA(t)/dt = —kf(t)ncnA(t), where kf(t) is the time-dependent rate coefficient. For long times, kf(t) reduces to the phenomenological forward rate constant, kf. If the dynamics of the A density field may be described by a diffusion equation, we have the well known partially absorbing sink problem considered by Smoluchowski [32]. To determine the rate constant we must solve the diffusion equation... [Pg.129]

Observed monomer concentrations are presented by Figure 2 as a function of cure time and temperature (see Equation 20). At high monomer conversions, the data appear to approach an asymptote. As the extent of network development within the resin advances, the rate of reaction diminishes. Molecular diffusion of macromolecules, initially, and of monomeric molecules, ultimately, becomes severely restricted, resulting in diffusion-controlled reactions (20). The material ultimately becomes a glass. Monomer concentration dynamics are no longer exponential decays. The rate constants become time dependent. For the cure at 60°C, monomer concentration can be described by an exponential function. [Pg.281]

What kind of experiments can be done to elucidate the special features of the time-dependent diffusion theory as applied above One of several possibilities is to choose a sample/can geometry in such a way that the initial change in slope of the outer volume concentration as a function of time is pronounced. This is equivalent to saying that the final exhalation rate should be significantly lower than the free exhalation rate and that the gradient reshaping time should be fairly short, of the order of hours. Results from such an experiment are displayed in Figure 7. Notice the characteristic constant slope (about 11 kBq m" h l) of... [Pg.217]

In liquids, collisional energy transfer takes place by multistep diffusion (the rate determining step) followed by an exchange interaction when the pair is very close. The bimolecular-diffusion-controlled rate constant is obtained from Smoluchowski s theory the result, including the time-dependent part, may be written as... [Pg.86]

A key assumption in deriving the SR model (as well as earlier spectral models see Batchelor (1959), Saffman (1963), Kraichnan (1968), and Kraichnan (1974)) is that the transfer spectrum is a linear operator with respect to the scalar spectrum (e.g., a linear convection-diffusion model) which has a characteristic time constant that depends only on the velocity spectrum. The linearity assumption (which is consistent with the linear form of (A.l)) ensures not only that the scalar transfer spectra are conservative, but also that if Scap = Scr in (A.4), then Eap ic, t) = Eyy k, t) for all t when it is true for t = 0. In the SR model, the linearity assumption implies that the forward and backscatter rate constants (defined below) have the same form for both the variance and covariance spectra, and that for the covariance spectrum the rate constants depend on the molecular diffusivities only through Scap (i.e., not independently on Sc or Sep). [Pg.383]

All the solutions with constant diffusion coefficients can therefore be used for problems with time-dependent diffusion coefficients upon replacement of 3>t/X2 by t. [Pg.454]


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Constant Diffusivities

Constant Diffusivity

Diffusion constant

Diffusion dependencies

Diffusion time

Diffusion time constant

Diffusivity dependence

Time constant

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