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Diamines, aliphatic diacid chloride reaction

Monomer structure can affect the competition between cyclization and linear polymerization. For example, phthalic acid (ortho isomer) is more prone to cyclization than terephthalic acid (para isomer) at the very-low-molecular-weight end, for example, the dimer stage. The ortho structure makes more likely the conformations that are more favorable for cyclization. Stiff linear chains such as those formed in the reaction between an aromatic diamine and aromatic diacid chloride are much less prone to cyclization than the flexible chains formed from the corresponding aliphatic monomers. [Pg.72]

In 1951, Flory reported the condensation reaction of diacid chlorides, e.g. with potassium salts of imides, e.g. the condensation of sebacyl chloride with potassium phthalimide. In this way, A -acyl diimides are formed. Flory pointed out the possibility of forming polymers, when components with higher functionality are used. Poly(imide)s (PI)s from pyromeUitic acid were reported in 1955 by Edwards and Maxwell at DuPont. Tbe diamines used were of aliphatic nature. Later, in addition, aromatic diamines were used. The two major types of Pis are ... [Pg.475]

Monomers derived from trimellitic anhydride, mainly V-carboxyphenyltrimel-litimides and V-(co-carboxyalkylene)trimellitimides have been also used many times as starting materials for the synthesis of poly (amide imide)s. These poly (amide imide)s have been traditionally prepared by low temperature solution polycondensation, from diamines and imide-diacid chlorides [182], but they have been also successfully synthesized by the phosphorylation method of direct polyamidation [184], from diamines and imide-diacids [185-188] as depicted in Scheme (36). Trimellitic acid imide (4-carboxyphthal-imide) has also been used for the preparation of poly(amide imide)s, by reaction with aliphatic and aromatic diamines in solution at moderate temperatures [189]. [Pg.580]


See other pages where Diamines, aliphatic diacid chloride reaction is mentioned: [Pg.164]    [Pg.100]    [Pg.610]    [Pg.100]    [Pg.989]    [Pg.190]    [Pg.580]    [Pg.108]    [Pg.352]   
See also in sourсe #XX -- [ Pg.58 ]




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Aliphatic Chlorides

Aliphatic diacids

Diacid

Diacid aliphatic

Diacids

Diamination reactions

Diamines aliphatic

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