Device operation lifetime

In additions to improvements in Si, a variety of devices based on compound semiconductors can be expected. Blue lasers witli high brightness and long operating lifetimes already exist in tlie laboratory. LEDs are likely to be used for all lighting purjDoses. The bandwidtli of optical communications will continue to increase witli ever faster semiconductor lasers. 

State-of-the-art polymer LEDs now have operating lifetimes and luminous efficiencies suitable for a wide variety of commercial applications. Furthermore, it is clear that the fundamental limits of polymer LED performance have not yet been reached. With improvements in material synthesis, fabrication techniques, and device design, significant increases in LED performance are to be expected. These improvements should lead to the extensive use of polymer LEDs in future display applications. 

More fluorescence features than just the emission intensity can be used to develop luminescent optosensors with enhanced selectivity and longer operational lifetime. The wavelength dependence of the luminescence (emission spectmm) and of the luminophore absorption (excitation spectrum) is a source of specificity. For instance, the excitation-emission matrix has shown to be a powerful tool to analyze complex mixtures of fluorescent species and fiber-optic devices for in-situ measurements (e.g. 

As mentioned in this review, AMPLEDs are especially attractive for motion picture applications. The Pay-Per-View effect in OLED displays reduces power consumption and extends operation lifetime. Motion picture applications also minimize image retention and optimize display homogeneity. AMOLED has been widely viewed as a promising display technology in competing with AMLCD and plasma displays. The dream of using organic semiconductor films for optoelectronic device applications has become a reality. 

Several groups have studied naphthalene substituted anthracene derivatives as hosts or emitter materials in blue OLEDs (121, 202-205) (Scheme 3.63). The Kodak group used ADN as a host and TBP as a dopant in ITO/CuPc/NPD/ADN TBP/Alq3/Mg Ag [241]. They achieved a narrow vibronic emission centered at 465 nm with CIE (0.154, 0.232) and a luminescent efficiency as high as 3.5 cd/A. In comparison, the undoped device shows a broad and featureless bluish-green emission centered at 460 nm with CIE (0.197, 0.257) and an EL efficiency below 2.0 cd/A. The operational lifetimes of the doped device and the undoped device were 4000 and 2000 h at an initial luminance of 636 cd/m2 and 384 cd/m2, respectively. 

PE Burrows, SR Forrest, TX Zhou, and L Michalski, Operating lifetime of phosphorescent organic light emitting devices, Appl. Phys. Lett., 76 2493-2495, 2000. 

M.S. Weaver, L.A. Michalski, K. Rajan, M.A. Rothman, J.A. Silvernail, and J.J. Brown, Organic light emitting devices with extended operating lifetimes on plastic substrates, Appl. Phys. Lett., 81 2929-2931, 2002. 

Sources and detectors Specific discussions of sources and detectors have been covered elsewhere in this article. The issues here are more service and performance related. Most sources have a finite lifetime, and are service replaceable items. They also generate heat, which must be successfully dissipated to prevent localized heating problems. Detectors are of similar concern. For most applications, where the interferometer is operated at low speeds, without any undesirable vibrational/mechanical problems, the traditional lithium tantalate or DTGS detectors are used. These pyroelectric devices operate nominally at room temperature and do not require supplemental cooling to function, and are linear over three or four decades. 

Finally, the operational lifetimes of both devices were analyzed. Figure 9.14 shows the normalized luminance of the devices tested under accelerated test conditions of high-dc current injection (40 mA cm-2), corresponding to an initial... 

Third, achieving the largest possible order parameter will be important for optimizing electro-optic activity. Moreover, this order parameter must be stable over the operational lifetime of a device utilizing the electro-optic material. 

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