Detector visible

A UV/Vis absorbance detector can also be used if the solute ions absorb ultraviolet or visible radiation. Alternatively, solutions that do not absorb in the UV/Vis range can be detected indirectly if the mobile phase contains a UV/Vis-absorbing species. In this case, when a solute band passes through the detector, a decrease in absorbance is measured at the detector. 

In one instrument, ions produced from an atmospheric-pressure ion source can be measured. If these are molecular ions, their relative molecular mass is obtained and often their elemental compositions. Fragment ions can be produced by suitable operation of an APCI inlet to obtain a full mass spectrum for each eluting substrate. The system can be used with the effluent from an LC column or with a solution from a static solution supply. When used with an LC column, any detectors generally used with the LC instrument itself can still be included, as with a UV/visible diode array detector sited in front of the mass spectrometer inlet. 

For radiofrequency and microwave radiation there are detectors which can respond sufficiently quickly to the low frequencies (<100 GHz) involved and record the time domain specttum directly. For infrared, visible and ultraviolet radiation the frequencies involved are so high (>600 GHz) that this is no longer possible. Instead, an interferometer is used and the specttum is recorded in the length domain rather than the frequency domain. Because the technique has been used mostly in the far-, mid- and near-infrared regions of the spectmm the instmment used is usually called a Fourier transform infrared (FTIR) spectrometer although it can be modified to operate in the visible and ultraviolet regions. 

Eor LEDs utilized in visible/display appHcations, the human eye serves as the detector of radiation. Thus a key measure of performance is luminous efficiency which is weighted to the eye sensitivity (CIE) curve. The relative eye sensitivity, V (L), peaks in the green at A 555 nm where it possesses a value of 1.0. It drops sharply as the wavelength is shifted to the red or blue, reaching a value of 0.5 at 510 and 610 nm. The luminous efficiency, in units of Im/W, of an LED is given by equaton 11 ... 

Scintillation detectors are substances which fluoresce when stmck by x-radiation. Scintillation can, therefore, serve to convert x-ray photons into visible or ultraviolet light. Scintillation materials include thaUium-activatedcrystals of sodium iodide, NaI(Tl), potassium iodide, KI(T1), or cesium iodide, CsI(Tl) crystals of stilbene (a, P-diphenylethylene) [588-59-0] and anthracene [120-12-7] bismuth germanium oxide [12233-56-6] ... 

Scintillators are also used in the detectors of CT scanners. Here an electronic detector, the photomultiplier tube, is used to produce an electrical signal from the visible and ultraviolet light photons. These imaging systems typically need fast scintillators with a high efficiency. 

Detectors aie all intrinsic unless otherwise noted. See Fig. 1. Visible bandwidth near infrared = 0.700-1.00 fim. 

Interferometry is difficult in the uv because of much greater demands on optical alignment and mechanical stabiUty imposed by the shorter wavelength of the radiation (148). In principle any fts interferometer can be operated in the uv when the proper choice of source, beam spHtter, and detector is made, but in practice good performance at wavelengths much shorter than the visible has proved difficult to obtain. Some manufacturers have claimed operating limits of 185 nm, and Fourier transform laboratory instmments have reached 140 nm (145). 

A new cyanide dye for derivatizing thiols has been reported (65). This thiol label can be used with a visible diode laser and provide a detection limit of 8 X 10 M of the tested thiol. A highly sensitive laser-induced fluorescence detector for analysis of biogenic amines has been developed that employs a He—Cd laser (66). The amines are derivatized by naphthalenedicarboxaldehyde in the presence of cyanide ion to produce a cyanobenz[ isoindole which absorbs radiation at the output of He—Cd laser (441.6 nm). Optimization of the detection system yielded a detection limit of 2 x 10 M. 

An x-ray area detector can be used to collect the intensities of many reflections at a time. The crystal must be oriented in many different settings with respect to the incident beam but the detector needs to be positioned at only a few positions to collect all of the data. A charge coupled device (CCD) is used as the area detector on the Siemens SMART single crystal diffractometer system. The SMART detector consists of a flat 6-cm circular phosphorescent screen that converts x-ray photons to visible light photons. The screen is coupled to a tapered fiber optics bundle which is then coupled to a one inch by one inch square CCD chip. The CCD chip has 1024 x 1024 pixels each of which stores an electrical charge proportional to the number of... 

The photoconductive detector is primarily used in the visible-infrared region rather than the ultraviolet—visible range. 

Turbidity Gauges These operate with visible light beams and detectors. They are used to monitor feed and effluent turbidity. 

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