Detection of temperature

Liquid crystals have found widespread application in optical display devices as well as in detection of temperature uniformity and impurities. These properties are related to the orientational order of molecules in the temperature region between and the melting point. The possible applications of ferroelectric liquid crystals are promising. Superconductors (type II) can be used to create high magnetic fields at low power the ability of type I superconductors to trap magnetic flux within the domains of the normal material may also have applications. 

Orlovskaya (2005), et al, Detection of Temperature- and Stress-induced Modifications of LaCo03 by Micro-Raman Spectroscopy , Physical Review, B 7, 014122. 

Like taste, touch is a combination of sensory systems that are expressed in a common organ—in this case, the skin. The detection of pressure and the detection of temperature are two key components. Amiloride-sensitive sodium channels, homologous to those of taste, appear to play a role. Other systems are responsible for detecting painful stimuli such as high temperature, acid, or certain specific chemicals. Although our understanding of this sensory system is not as advanced as that of the other sensory systems, recent work has revealed a fascinating relation between pain and taste sensation, a relation well known to anyone who has eaten "spicy" food. 

Figure 2.32. Detection of temperature change of sample with a close-proximity thermocouple detector (53. ...

Thermistor array for detection of temperature changes with high resolution... 

N. Orlovskaya, D. Steinmetz, S. Yarmolenko, D. Pai, J. Sankar and, T. Goodenough, Detection of Temperature- and Stress-Induced Modifications of LaCoOiby Micro-Raman Spectroscopy, Phvs. 

Instruments for the detection of temperature are thermocouples, resistance thermometers and radiation pyrometers. With the first two types of instrument the sensor comes into direct contact with the medium whose temperature is to be measured, so that this part of the instrument is liable to suffer wear or damage. On the other hand, the radiation pyrometer picks up thermal radiation emitted from the surface of a body, i. e., the instrument does not come into direct contact with the medium, but it must nevertheless be protected from excessive heat, which might harm its electronic equipment, or from dust deposits forming on its lens. It is obviously important that the pyrometer should really receive the radiation that is representative of the temperature to be measured. The optimum direction of sighting the instrument must be adjusted at the outset. 

The next property worth discussing is the enthalpy of dilution, which, in the field of simple electrolytes, is considered to be a very rigorous test for the theory. Since the heat effect is very small if a polyelectrolyte solution is diluted, it was necessary to build a sensitive calorimeter [26, 27] which makes possible the detecting of temperature differences as small as 2x 10" °C. 

Detection of nearsurface casting defects with temperature analysis... 

Abstract An Eddy current method applying a High Temperature Superconductor ( HTS ) DC SQUID sensor operating at Uquid nitrogen temperature (77K) is presented. The method is developed for the detection of surface or surface near defects. We compare the performance of the SQUID system with the performance gained from a commercial Eddy current system, while using identical probes. The experimental data are obtained on defects in gas turbine blades. The advantage of planar conformable probes for the use with the SQUID is discussed. 

Pulsed ENDOR offers several distinct advantages over conventional CW ENDOR spectroscopy. Since there is no MW power during the observation of the ESE, klystron noise is largely eliminated. Furthemiore, there is an additional advantage in that, unlike the case in conventional CW ENDOR spectroscopy, the detection of ENDOR spin echoes does not depend on a critical balance of the RE and MW powers and the various relaxation times. Consequently, the temperature is not such a critical parameter in pulsed ENDOR spectroscopy. Additionally the pulsed teclmique pemiits a study of transient radicals. 

Thenual desorption spectroscopy (TDS) or temperature progranuned desorption (TPD), as it is also called, is a simple and very popular teclmique in surface science. A sample covered with one or more adsorbate(s) is heated at a constant rate and the desorbing gases are detected with a mass spectrometer. If a reaction takes place diirmg the temperature ramp, one speaks of temperature programmed reaction spectroscopy (TPRS). 

Optical metiiods, in both bulb and beam expermrents, have been employed to detemiine tlie relative populations of individual internal quantum states of products of chemical reactions. Most connnonly, such methods employ a transition to an excited electronic, rather than vibrational, level of tlie molecule. Molecular electronic transitions occur in the visible and ultraviolet, and detection of emission in these spectral regions can be accomplished much more sensitively than in the infrared, where vibrational transitions occur. In addition to their use in the study of collisional reaction dynamics, laser spectroscopic methods have been widely applied for the measurement of temperature and species concentrations in many different kinds of reaction media, including combustion media [31] and atmospheric chemistry [32]. 

Phosphatase Test. The phosphatase [9001-78-9] test is a chemical method for measuring the efficiency of pasteurization. AH raw milk contains phosphatase and the thermal resistance of this enzyme is greater than that of pathogens over the range of time and temperature of heat treatments recognized for proper pasteurization. Phosphatase tests are based on the principle that alkaline phosphatase is able, under proper conditions of temperature and pH, to Hberate phenol [108-95-2] from a disodium phenyl phosphate substrate. The amount of Hberated phenol, which is proportional to the amount of enzyme present, is determined by the reaction of Hberated phenol with 2,6-dichloroquinone chloroimide and colorimetric measurement of the indophenol blue formed. Under-pasteurization as well as contamination of a properly pasteurized product with raw milk can be detected by this test. 

Laser sources that emit in the mid-ir region of the spectmm (2—5 -lm) are useful for detection of trace gases because many molecules have strong absorption bands in that region. Other appHcations include remote sensing and laser radar. Semiconductor lead—salt (IV—VI) lasers that operate CW at a temperature of 200 K and emission wavelength of 4 p.m are commercially available however, they have relatively low output powers (<1 mW) (120). 

Radiometry. Radiometry is the measurement of radiant electromagnetic energy (17,18,134), considered herein to be the direct detection and spectroscopic analysis of ambient thermal emission, as distinguished from techniques in which the sample is actively probed. At any temperature above absolute zero, some molecules are in thermally populated excited levels, and transitions from these to the ground state radiate energy at characteristic frequencies. Erom Wien s displacement law, T = 2898 //m-K, the emission maximum at 300 K is near 10 fim in the mid-ir. This radiation occurs at just the energies of molecular rovibrational transitions, so thermal emission carries much the same information as an ir absorption spectmm. Detection of the emissions of remote thermal sources is the ultimate passive and noninvasive technique, requiring not even an optical probe of the sampled volume. 

Another classification of detector is the bulk-property detector, one that measures a change in some overall property of the system of mobile phase plus sample. The most commonly used bulk-property detector is the refractive-index (RI) detector. The RI detector, the closest thing to a universal detector in lc, monitors the difference between the refractive index of the effluent from the column and pure solvent. These detectors are not very good for detection of materials at low concentrations. Moreover, they are sensitive to fluctuations in temperature. 

Seam correlations, measurements of rank and geologic history, interpretation of petroleum (qv) formation with coal deposits, prediction of coke properties, and detection of coal oxidation can be deterrnined from petrographic analysis. Constituents of seams can be observed over considerable distances, permitting the correlation of seam profiles in coal basins. Measurements of vitrinite reflectance within a seam permit mapping of variations in thermal and tectonic histories. Figure 2 indicates the relationship of vitrinite reflectance to maximum temperatures and effective heating time in the seam (11,15). 

Thermal-Conductivity Analyzer. The thermal-conductivity analy2er operates on the principle that the loss of heat from a hot wire by gaseous conduction to a surface at a lower temperature varies with the thermal conductivity of the gas, and is virtually independent of pressure between 1.3 kPa (10 mm Hg) and 101 kPa (1 atm). This technique is frequently used in continuous monitors for tritium in binary gas mixtures for immediate detection of process change. 

One early program carried out at AUied-Signal, Inc. proposed the use of conductive polymers in remotely readable indicators (210). Conductivity changes induced in the conductive polymer could be read externally and the history of the sample known. Systems designed to detect time—temperature, temperature limit, radiation dosage, mechanical abuse, and chemical exposure were developed. 

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