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Density performed

When no humidification is used on the cathode side of a fuel cell. Song, Uchida, and Watanabe [115] showed that the low current density performance between treated (10 and 30 wt% PEP) and untreated CFPs (TGP-H-120) was... [Pg.231]

High current density performance of PEFCs is known to be limited by transport of reactants and products. In addition, at high current densities, excess water is generated and condenses, filling the pores of electrodes with liquid water and hence limiting the reactant transport to catalyst sites. This phenomenon known as flooding is an important limiting factor of PEFC performance. A fundamental... [Pg.503]

NH4-CH4]+ complex in the gas phase [36]. Topological analysis of the electron density performed in the framework of AIM theory shows the bond critical points on the H- H directions with pc values of 0.013 an. It is interesting that the electron density in this complex is larger than that obtained for the BH4 - CH4 dihydrogen-bonded system (pc = 0.007 an), the CH4 molecule of which acts as a proton donor. In accordance with the electronic density, the H- H distances in the BH4 - H4C complex were remarkably longer than 2.4 A (2.797, 2.929,... [Pg.139]

AIM topological analysis of the electron density performed for two complexes and for isolated components is shown in Table 6.15. The bond critical points found in the H H directions are characterized by the small electronic density with Pc = 0.002 and 0.009 au in the CILj- HF and SilLj- HF systems, respectively. The Laplacian, V pc, is also small but takes positive values in accordance with the AIM criteria for dihydrogen bonding. [Pg.140]

Actual calculations of compressed-atom densities, performed with suitably modified SCF software, show that the increased pressure raises all electronic energy levels, at different rates that depend on the shell structure. The effect is more pronounced on those levels of highest effective quantum number l and it is not uncommon for levels of different l to cross during compression. The interpretation of photoelectron spectra in terms of free-atom electron configurations may therefore be misleading in the study of surface chemistry and catalytic effects, for which they are routinely used. [Pg.66]

It has been shown that the oxidation is controlled by the diffusion of the pollutants toward the electrode surface, where the hydroxyl radicals are produced, and the current efficiency is favored by high mass-transport coefficient, high organic concentration, and low current density. Performing electrolysis under optimum conditions, without diffusion limitation, the current efficiency approaches 100%. [Pg.44]

Developed a unique flow field design via modeling and basic principles of gas transport that optimizes the uniformity of hydrogen and air mass flow velocities for the matched EB media and increases high current density performance over conventional designs. [Pg.380]

Improved semiconductor devices and circuits tend to be achieved primarily through advances in either device density, performance or functionality. At times, all three elements are realized simultaneously. The improvements can be accomplished in several ways. One approach is to design new circuit families, which very often create enhanced device functionalities and performances. In contrast to this, device density gains typically demand a much greater investment of process efforts in the form of a relentless pursuit of better tolerance control of all the various process and tool parameters. It may, however, also be coupled with the introduction of new process methods and/or tools with enhanced process capabilities. [Pg.242]

The final atomic radii equation that has to be solved in terms of Mulliken electronegativity is authors formulation above. However, before to arrive at the effective atomic radius equation, it should be first transformed according to the forms of atomic potential and associate homogeneous density. Performing this substitutions for the main ingredients of S-DFT electronegativity expression (4.354) we get successively (Putz, 2012b,c) ... [Pg.306]

Clearly, the electron density will depend on the method that obtains it. Nonetheless, even the simple Hartree-Fock (HF) electron density performs well to obtain first-order electron densities. The electron density in this MO LCAO framework is given by... [Pg.143]

The performance characteristic of a DEFC employing 1 mg/cm 20 % Pt3Cri/C ethanol tolerant ORR catalyst at the cathode and 20 % PtSn/C at the anode is shown in Fig. 3.5. Non-preheated ethanol was pumped to the anode side without backpressure at a flow rate of 2 ml/min. The performance curves at 60 °C and 90 °C are presented. The expected enhancement in cell voltage vs. current density performances is observed with the increased temperature in Ref. [19]. [Pg.73]

Alkenes are good nucleophiles by virtue of their ji electron density. Performic acid is electrophilic at the terminal hydroxyl group, as a result of the weak 0-0 bond and the good leaving group. [Pg.54]

Figure 13.12 presents the energy absorption of six 3D Kevlar fabrics with comparison to the 2D plain weave fabric, which is widely used for body amour production for police and military personnel. It was foimd that (a) 3D honeycomb fabrics and the same layer 2D plain fabric The two- and four-layered 3D fabrics performed better than the assembly with the same layer 2D plain woven fabric of similar yam density. The twolayered fabric with lower yam density performed less well than the one with higher yam density, (b) AU the 2D woven fabrics have the ability to absorb more projectile impact energy compared to the three 3D angle-interlock fabrics. [Pg.351]

The value of the resistance that is most relevant to the power density performance of an EDLC, the cell resistance, increased in the order of BF4, Pp6 and TFSI. Of the ionic liquids tested, MEMP-BF4 and DEME-BF4, both of which have a methoxyethyl group on nitrogen atom, showed the highest durability in a continuous charging life test. We conclude that ionic liquids containing the tetrafluoroborate anion have the best performance and stability for electric double layer capacitor applications. [Pg.131]

In a PEFC, the high-cuirent-density performance can be low as a result of flooding the electrode or anode dryout. How could you experimentally delineate the difference ... [Pg.480]

We have discussed the current density, performance and ideal behaviour of different fuel cells. The SOFC, its working, design principles and performance variables are studied in Chap. 3. Hence, we do not discuss it in the current chapter. [Pg.77]

The best carbon in phenol ads 400 followed by BHT and AG 3 equilibrium isotherm for the Fig.3) are at the lower end r adsorption volume wo and a m hand, WRK a.nd Hy 71 have smal has a very large micropcre measurements TVAX has apparen but this is due to its low bed density performance (Table 3)... [Pg.497]


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See also in sourсe #XX -- [ Pg.50 ]




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