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Degradation surface area

SEW FT-IR Gold sputtered sohd samples PE-Wax, PHBP Xanthan, polysaccharide, Avicel. solid or liquid samples Bacterial degradation, surface area Surface analytical procedme Fingerprinting technique [41,75,78,96] [77,39,101]... [Pg.152]

Fypass Flow Effects. There are several bypass flows, particularly on the sheUside of a heat exchanger, and these include a bypass flow between the tube bundle and the shell, bypass flow between the baffle plate and the shell, and bypass flow between the shell and the bundle outer shroud. Some high temperature nuclear heat exchangers have shrouds inside the shell to protect the shell from thermal transient effects. The effect of bypass flow is the degradation of the exchanger thermal performance. Therefore additional heat-transfer surface area must be provided to compensate for this performance degradation. [Pg.489]

The gel-based products have traditionally been the most expensive and highest performance activated alumina products. They have very good mechanical properties, high surface area, and their purity and ganima-aluniina stmcture make them somewhat resistant to thermal degradation. On the other hand, they are the most difficult to manufacture and disposal of by-product salts can present an environmental problem. [Pg.156]

Catalyst lifetimes are long in the absence of misoperation and are limited primarily by losses to fines, which are removed by periodic sieving. Excessive operating temperatures can cause degradation of the support and loss of surface area. Accumulation of refractory dusts and chemical poisons, such as compounds of lead and mercury, can result in catalyst deactivation. Usually, much of such contaminants are removed during sieving. The vanadium in these catalysts may be extracted and recycled when economic conditions permit. [Pg.203]

Thermal Degradation and Sintering Thermally iaduced deactivation of catalysts may result from redispersion, ie, loss of catalytic surface area because of crystal growth ia the catalyst phase (21,24,33) or from sintering, ie, loss of catalyst-support area because of support coUapse (18). Sintering processes generally take... [Pg.508]

As one can see, the larger-diameter wires suffer a much more rapid degradation in ac resistance with increasing frequency than do smaller-diameter wires. So it is advantageous to use multiple strands of smaller wires instead of one large diameter wire. The ac current density of the smaller wires (>30 AWG) can actually be pushed to two to three times the assumed current density used in the charts because their surface area to cross-sectional area ratio is much greater. [Pg.253]

Silica gel and aluminium oxide layers are highly active stationary phases with large surface areas which can, for example, — on heating — directly dehydrate, degrade and, in the presence of oxygen, oxidize substances in the layer This effect is brought about by acidic silanol groups [93] or is based on the adsorption forces (proton acceptor or donor effects, dipole interactions etc) The traces of iron in the adsorbent can also catalyze some reactions In the case of testosterone and other d -3-ketosteroids stable and quantifiable fluorescent products are formed on layers of basic aluminium oxide [176,195]... [Pg.88]

The particle size of the powder should be 150-300 /zm. If the particles are too big they will not completely melt and a poor surface finish will result. The flame will inevitably cause some degradation to the surface of the particles. Since the surface area to mass ratio increases as the particle size decreases, very fine particles should be avoided. [Pg.748]

The efficiency of extraction was observed to be inversely proportional to the corn cob particle size. This was expected because the size reduction corresponds to an increase in total particle surface area. An increase in the time of the alkaline extraction and in the NaOH concentration also improves the efficiency of xylan extraction. This happened because when the NaOH concentration was lower, the xylan present in corn cobs could not be fully dissolved in the solution. Thus, it resulted in lower efficiency of xylan extraction. However, when the NaOH concentration was higher than 2 M, the yields decreased with continuously increasing of the NaOH concentration. This is probably due to the alkaline degradation of xylan chains, proceeding at the higher NaOH concentration, which indicated that the ideal NaOH concentration in the extraction was between 1.5 and 1.8 M (Unpublished data). [Pg.65]

Figure 1 shows the results of those experiments. It is important to recognize that in this experiment the polymer was present in a form affording high surface area when compared to other studies where rods, pellets, plates, fibers, and so forth were used. It is often quite difficult to compare exact degradation times from various independent studies due to differences in implant surface area and... [Pg.6]

The incrrase of surface area and pore volume enhanced the production of ethylbenzene by promoting further hydrogenation of the degraded styrene fragments. High degradation temperature favored the selectivity to styrene monomer. [Pg.436]

One of the critical issues with regard to low temperamre fuel cells is the gradual loss of performance due to the degradation of the cathode catalyst layer under the harsh operating conditions, which mainly consist of two aspects electrochemical surface area (ECA) loss of the carbon-supported Pt nanoparticles and corrosion of the carbon support itself. Extensive studies of cathode catalyst layer degradation in phosphoric acid fuel cells (PAECs) have shown that ECA loss is mainly caused by three mechanisms ... [Pg.300]

A PP sample after ozonization in the presence of UV-irradiation becomes brittle after 8 hrs of exposure, whereas the same effect in ozone is noticeable after 50-60 hours.Degradation of polymer chain occurs as a result of decomposition of peroxy radicals. The oxidation rapidly reaches saturation, suggesting the surface nature of ozone and atomic oxygen against of PP as a consequence of limited diffusion of both oxygen species into the polymer. Ozone reacts with PP mainly on the surface since the reaction rate and the concentration of intermediate peroxy radicals are proportional to the surface area and not the weight of the polymer. It has been found that polyethylene is attacked only to a depth of 5-7 microns (45). [Pg.197]

Newport In terms of physical limits, we tend to think of DNA, but on the other hand there is RNA degradation and protein turnover. This is how an egg is made. Even though it is only a tetraploid organism, RNA degradation is slowed down significantly, so less DNA is needed. The other physical limitation is the surface area volume relationship. How many receptors or growth factors can be inserted into a membrane ... [Pg.38]


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See also in sourсe #XX -- [ Pg.423 ]




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