Degradation of electrolyte

On the other hand, Hiiatsuka and co-woikers [165] reported that the oxygen excess on the electrodes surfaces induces the self-discharge of the EDL capacitors, b> accelerating the degradation of electrolytes. Similar results about the negative effect of oxygen excess on the discharge properties of ACF cloths electrodes modified with plasma were reported by... 

Stray current corrosion is an electrolytic degradation of a metal caused by unintentional electrical currents. Bad grounds are the most prevalent causes. The corrosion is actually a typical electrolysis reaction. 

A problem common to electrochemical cells is the analyzer can fail (degradation of the anode material and electrolyte or loss of sensor sensitivity), but still indicate a safe oxidant level when in reality it may not be so. Adherence to the manufacturer s recommendation as to how... 

Nail sickness Nail sickness is chemical decay associated with corroded metals in marine situations. Chemical degradation of wood by the products of metal corrosion is brought about by bad workmanship or maintenance, or unsuitable (permeable) timber species, all of which permit electrolyte and oxygen access which promotes corrosion. Chemical decay of wood by alkali occurs in cathodic areas (metal exposed oxygen present). Softening and embrittlement of wood occurs in anodic areas (metal embedded oxygen absent) caused by mineral acid from hydrolysis of soluble iron corrosion products. 

Figure 24. Degradation of n-Si/electrolyte (0.1 M NaS04, pH 3) interface as seen from the hysteresis of the PMC signal and the photocurrent (dotted line).

Licht et al. [17] developed a method of numerical analysis to describe the above-quoted equilibria of the 11 participating species (including alkali metal cations) in aqueous polysulfide solution, upon simple input to the algorithm of the temperature and initial concentration of sulfur, alkali metal hydroxide, and alkali metal hydrosulfide in solution. The equilibria constants were evaluated by compensation of the polysulfide absorption spectrum for the effects of H8 absorption and by computer analysis of the resultant spectra. Results from these calculations were used to demonstrate that the electrolyte is unstable, and that gradual degradation of polysulfide-based PECs (in the long term) can be attributed to this factor (Chap. 5). 

In principle, the oxidation of proceeds at an electrode potential that is more negative by about 0.7 V than the anodic decomposition paths in the above cases however, because of the adsorption shift, it is readily seen that practically there is no energetic advantage compared to CdX dissolution in competing for photogenerated holes. Similar effects are observed with Se and Te electrolytes. As a consequence of specific adsorption and the fact that the X /X couples involve a two-electron transfer, the overall redox process (adsorption/electron trans-fer/desorption) is also slow, which limits the degree of stabilization that can be attained in such systems. In addition, the type of interaction of the X ions with the electrode surface which produces the shifts in the decomposition potentials also favors anion substitution in the lattice and the concomitant degradation of the photoresponse. 

For all these reasons, the stability of the superconducting state and ways to control it are questions of prime importance. Many studies have addressed the degradation of the properties of HTSC under the influence of a variety of factors. They included more particularly the corrosion resistance of HTSC materials exposed to aqueous and nonaqueous electrolyte solutions as well as to water vapor and the vapors of other solvents. It was seen that the corrosion resistance depends strongly both on the nature (chemical composition, structure, etc.) of the HTSC materials themselves and on the nature of the aggressive medium. 

Although it was initially believed that polyacetylene was unstable in contact with water under all conditions, it has been successfully chemically doped in aqueous solutions with no apparent degradation of the material [82] and its electrochemistry has also been investigated [135-137] from which it is clear that no degradation occurs in concentrated aqueous electrolytes. Reaction with water can occur under some circumstances however giving rise to sp3 carbons and carbonyl-type structures [129, 138-141],... 

Many acrylic acid copolymers are water-soluble but unlike poly(vinyl alcohol) they are not degraded by alkali. In fact they need alkali for effective desizing as they are more soluble at alkaline pH than in neutral solutions. They are sensitive to acidic media, which should not be used. Solubilisation occurs by the formation of sodium carboxylate groups from the anionic polyacid. The polyelectrolyte formed in this way is readily soluble and shows a rapid rate of dissolution. However, the presence of electrolytes such as magnesium or calcium salts from hard water can inhibit removal [191]. 

Each breakdown is accompanied by some sound effect and is followed by a steady degradation of properties.284 It can also lead to a complete destruction of the oxide with visible fissures and cracks.286 The particular behavior observed depends on a large number of factors (electrolyte concentration,287 defect concentration in the oxide,288 etc.). The breakdown of thin-film systems (M-O-M and M-O-S structures) as a rule leads to irreversible damage of oxide dielectric properties.289... 

Malto-oligosaccharide aldonolactones react with ethylenediamine to give Ar-(2-aminoethyl)aldonamides (113-115), which have been successfully grafted onto carriers via amide linkages. The malto-oligosaccharides were produced by degradation of amylose with alpha amylase. After purification of the oligosaccharides, they were converted into the lactones by hypoiodite or electrolytic oxidation. 

If the wafer is not fixed in the cell, a mechanical wafer support is advisable. The ohmic contact can be an integral part of such a sample fixture, as shown in Fig. 1.5 a. During formation of mesoporous silicon on highly doped substrates at low bias (0-1.5 V), it was found that such a contact can even be immersed into the electrolyte without a significant degradation of its electrical properties. It is remarkable that mesoporous silicon formation takes place under the contact, too, without significant degradation of the contact properties. 

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