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Cyanuric acid, organic chlorinated compounds

Among other electrophilic reagents ctq>able of twinging about the Pummerer rearrangement are halides of organic and inorganic acids. As these halides transform sulfoxides into a-chlorosulfides they complement the sulfide chlorination route to these compounds. Thionyl chloride reacts readily with sulfoxides and 3-keto sulfoxides methyl phenyl sulfoxide furnishes chloromethyl phenyl sulfide (equation 37). Benzoyl chloride and acetyl chloride behave similarly. d yanuric chloii is transformed into cyanuric acid by dimethyl sulfoxide, which in turn is transformed into methyl chloromethyl sulfide (equation 3g).54,S5... [Pg.203]

Triazines are one of the oldest known compound classes in organic chemistry. First reports date back to 1776 when cyanuric acid (l,3,5-triazine-2,4,6-triol 1,3,5-triazine-2,4,6(l//,3//,5f/)-trione) was obtained by the pyrolysis of uric acid.1 The same method was also utilized in 1820 2 however, triazine compounds were probably first prepared in 1704 upon trimerization of cyanide derivatives when the Berlinerblau -complex salt, the first known cyano compound, was discovered.468 Cyanuric chloride was synthesized in 1828 from hydrogen cyanide and chlorine.3 Another method, discovered in 1834, involves treatment of potassium thiocyanate with chlorine. When heated, cyanuric chloride is obtained.4 Melamine (1,3,5-triazine-2,4,6-triamine) was also prepared in 1834 by heating potassium thiocyanate with ammonium chloride.5 Although 2,4,6-substituted 1,3,5-triazine derivatives were identified very early, the unsubstituted parent compound was not synthesized before 1895.6 At that time, however, the isolated compound was assigned to a dimeric species and not to the trimeric hydrogen cyanide. This was finally proven much later."... [Pg.667]

V-Chlorosuccinimide is a convenient reagent for the electrophilic substitution and addition of chlorine to organic compounds. Other chlorinating agents of use include Chlorine, Sulfuryl Chloride, Chloramine-T, tert-Butyl Hypochlorite, and Trichloroiso-cyanuric Acid. The primary advantages of using NCS include the ease in handling, the mild conditions under which chlorination proceeds, and the ease of removal of the inoffensive byproduct succinimide. [Pg.98]


See other pages where Cyanuric acid, organic chlorinated compounds is mentioned: [Pg.122]    [Pg.50]    [Pg.362]    [Pg.62]    [Pg.467]    [Pg.387]    [Pg.954]   
See also in sourсe #XX -- [ Pg.423 ]




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Acidic organic compounds

Chlorinated compounds

Chlorinated organic compounds

Cyanurates

Cyanuric acid

Cyanuric acid chlorination

Cyanuric compounds

Organic chlorinated

Organic chlorine

Organic chlorine compounds

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