Chlorination sulfides

Wlieii thiomethoxymethyl hexachloroaiitimoiiate was treated with pyridine, a methylthio derivative 28 was isolated in low yield in addition to the expected chlorinated sulfides (71T4209). Several A, A -haloalkyl-bis-4,4 -pyridiniumethenes 29 have been reported in a Japanese patent (80JAP75479). Tliese compounds are promising candidates for the construction of electrochromic display devices (Scheme 7). 

See Chloric acid Metal sulfides Chlorine Sulfides Potassium nitrate Metal sulfides... 

Chlorine Cyanide Chlorine Fluoride Chlorine Fluoride Chlorine Pentafluoride Chlorine Sulfide Chlorine Trifluoride Chlormethine Chlormethinum... 

Another major use is in making photographic emulsions. In analytical chemistry, potassium iodide is used in iodometric titration with starch indicator to analyze dissolved oxygen, dissolved chlorine, sulfide, and other analytes in water. 

Later, additional stack gas samples from two different waste incinerators were found to contain TeCDTs and PeCDTs. Two samples contained the gas phase only, and two samples contained both the gas phase and particles. One of the stack gas samples which did not contain any TeCDTs and PeCDTs was strongly suspected to contain TriCTAs and TeCTAs [32]. These samples had previously been found to contain some tri- and tetrachlorinated diphenylsulfides. The detailed analysis of these samples for the chlorinated sulfides have been reported elsewhere [54]. 

Chlorine peroxide. See Chlorine dioxide Chlorine sulfide. See Sulfur dichloride Chlorite... 

Synonyms Chloride of sulfur Chlorine sulfide Dichlorosulfane Diclorosulfide Monosulfur dichloride... 

Waste incineration/superheaters up to 480 °C chlorination, sulfidation, oxidation, molten salts... 

A low O2 condition is produced at a corrosion interface in the presence of protective scales, and complex corrosion reactions such as chlorination, sulfidation and oxidation occur below the corrosive deposit layer. Thick scales have pores and cracks due to temperature fluctuations and the vaporization of chlorides. As the thickness increases, the scales easily peel off from the surface. In particular, severe thermal cycles or increased gas velocities due to soot blowing accelerate the breakdown and spalling of the scale. Also, as a result of continuously repeated variations of gas conditions on the scales, the balance of chlorination, sulfidation and oxidation reactions at the corrosion interface and in the scales is forced to be changed by the penetration of O2. An increase of the partial pressure of O2 ( /qj ) temporarily halts the chlorination and sulfidation reactions. Therefore, a multi-layered scale stracture is produced. The presence of multi-layered oxides formed by corrosion resistant elements such as chromium, nickel, aluminum, silicon and molybdenum increases the protective effect of the scales against the... 

Sometimes analyses are required for particular compounds such as sulfur, chlorine and lead, or for specific components such as mercaptans, hydrogen sulfide, ethers and alcohols. 

Anti-wear and extreme pressure additives phosphoric esters, dithiophosphates, sulfur-containing products such as fatty esters and sulfided terpenes or chlorinated products such as chlorinated paraffins. 

The iodides of the alkaU metals and those of the heavier alkaline earths are resistant to oxygen on heating, but most others can be roasted to oxide in air and oxygen. The vapors of the most volatile iodides, such as those of aluminum and titanium(II) actually bum in air. The iodides resemble the sulfides in this respect, with the important difference that the iodine is volatilized, not as an oxide, but as the free element, which can be recovered as such. Chlorine and bromine readily displace iodine from the iodides, converting them to the corresponding chlorides and bromides. 

Peroxomonosulfuric acid oxidi2es cyanide to cyanate, chloride to chlorine, and sulfide to sulfate (60). It readily oxidi2es carboxyflc acids, alcohols, alkenes, ketones, aromatic aldehydes, phenols, and hydroquiaone (61). Peroxomonosulfuric acid hydroly2es rapidly at pH <2 to hydrogen peroxide and sulfuric acid. It is usually made and used ia the form of Caro s acid. 

Nitrogen and sodium do not react at any temperature under ordinary circumstances, but are reported to form the nitride or azide under the influence of an electric discharge (14,35). Sodium siHcide, NaSi, has been synthesized from the elements (36,37). When heated together, sodium and phosphoms form sodium phosphide, but in the presence of air with ignition sodium phosphate is formed. Sulfur, selenium, and tellurium form the sulfide, selenide, and teUuride, respectively. In vapor phase, sodium forms haHdes with all halogens (14). At room temperature, chlorine and bromine react rapidly with thin films of sodium (38), whereas fluorine and sodium ignite. Molten sodium ignites in chlorine and bums to sodium chloride (see Sodium COMPOUNDS, SODIUM HALIDES). 

Fluorinated and Ghlorfluorinated Sulfonic Acids. The synthesis of chlorinated and fluorinated sulfonic acids has been extensively reviewed (91,92). The Hterature discusses the reaction of dialkyl sulfides and disulfides, sulfoxides and sulfones, alkanesulfonyl haHdes, alkanesulfonic acids and alkanethiols with oxygen, hydrogen chloride, hydrogen fluoride, and oxygen—chloride—hydrogen fluoride mixtures over metal haHde catalysts, such as... 

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