Cyanides cyanogen iodide

Cyanogens Cyanogens Hydrogen cyanide Cyanogen chloride Cyanogen bromide Cyanogen iodide Acetonitrile Acrylic nitrile... [Pg.107]

Cyan-jodid, n. cyanogen iodide, -kali, n. potassium cyanide. [Pg.95]

We obtained diethyl phosphorocyanidate (V) in only small yield by the action of potassium cyanide on the corresponding phosphorochloridate. We were able to prepare it,6 however, by the action of cyanogen iodide on the phosphite. This is apparently a modified Arbusov reaction ... [Pg.110]

Cyanogen iodide is prepared by the reaction of iodine on sodium cyanide NaCN -I-12 —> CNI -I- Nal... [Pg.287]

Cyanogen iodide has been prepared from mercuric cyanide and iodine,3 potassium cyanide and iodine,4 and sodium cyanide and iodine.6... [Pg.31]

Cyanogen Fluoride or Fluorine Cyanide, FCN, mw 45.02 colorless, very irritant gas forms a wh.pulvurelent mass if cooled strongly. and sublimes at —72° insol in w. Can be prepd by interaction of AgF and cyanogen iodide. [Pg.513]

Cyanogen Iodide, NC.I, mw 152.94 col ndls, having a pungent odor acrid caste, mp 146.5°, d 2.84 sol in w, ale eth prepd by heating a metal cyanide with iodine. It is a very violent poison... [Pg.369]

Cyanides interfere because of the formation of cyanogen iodide they are therefore removed before the test either by heating with sodium hydrogen carbonate solution or by acidifying and heating ... [Pg.331]

DOT CLASSIFICATION 6.1 Label Poison, KEEP AWAY FROM FOOD SAFETY PROFILE A poison by ingestion and subcutaneous routes. Violent reaction with P. See other cyanogen entries CYANIDE and IODIDES. When heated to decomposition it emits very toxic fumes of NOx, CN, and I. ... [Pg.399]

Allyl Cyanide, Iso-thio-cyanate, etc.—From allyl chloride or the iodide there may be prepared by the customary reactions allyl cyanide and other of the cyanogen compounds. With potassium cyanide allyl iodide yields allyl cyanide. The reaction, however, instead of yielding a cyanide of the expected constitution is accompanied by a shifting of the double bond to the second carbon so that the cyanide has a constitution unlike that of the iodide from which it is made. [Pg.165]

Cyanogen iodide. Zinc cyanide, ethyl iodide. Calmels, Compt, rend., 1884, 99, 239 Bull, Soc, chim., 1885, [2], 43, 82. [Pg.20]

Diphenylcyanobis mu thine, (C6Hg)2BiCN.—When triphenylbismuthine and cyanogen iodide (1 - mols.) are refluxed in benzene, the cyano-derivative is isolated as small transparent needles melting with decomposition at 210° C. The same product is obtained when an aqueous alcohol solution of triphenylbismuthine dichloride is heated with potassium cyanide. It is sparingly soluble in benzene or alcohol and practically insoluble m ether or light petroleum. If its alcohol solution be concentrated, the compound is decomposed, triphenyl-bismuthme being produced,... [Pg.277]

A suitable method for destroying cyanogen iodide may consist of treatment with caustic soda, followed by adding sodium hypochlorite (laundry bleach) to oxidize the cyanide to nontoxic cyanate. [Pg.329]

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