Cooling secondary

The secondary cooling circuit B comprises the heat exchanger 27 wherein heat is extracted from the hot water in tlie primary circuit A, a pipe 82 that conveys the hot 40 water in the secondary circuit to a cooling tower 83 where the water is cooled by evaporation, and a return pipe 84 that conveys the cooled secondary water stream back to the heat exchanger 27 in response to a circulating pump 85. 

Gidropress according to the Russian norms. The Russian designer and manufacturer made the feed water pipelines (secondary side) from carbon steel (GOST norms 20K and 22K). The water inlet pipe was connected to the T-junction. From this point, two pipelines with nozzles distributed the cooling secondary water within the space between the primary pipes. Several problems that had occurred in other NPPs were published in [195,197,198,203]. One disadvantage of such steam generators is the poor accessibility to the T-junction and the pipes in the bundle. 

Two independent water-cooled secondary cooling systems are designed Air is used as the final heat sink by water/air heat exchangers. CLEAR-I incorporates a reactor vessel air cooling system to remove the decay heat in case the normal heat removal path is unavailable. 

The sketch in Fig. 16.4 indicates clockwise flow in the hot primary loop and the cool secondary loop. This arrangement indicates countercurrent flow in the BCs and coupling HEXs. Note that there are four equally likely arrangements of the flow in the loops for the system shown in the figure clockwise or counter-clockwise in either loop. 

The corresponding model equations for the cool secondary loop are... 

The chloroplatinates prepared as above are sufficiently pure for direct analysis without recrystallisation. The chloroplatinates of the amines are usually freely soluble in hot water, but recrystallisation (when required) should not be attempted until the process has been found to be successful with a small test-portion of the chloroplatinate. The chloroplatinates of many primary and secondary amines decompose in hot water, the amine being oxidised, and the chloroplatinate reduced to the metal some amines furthermore co-ordinate readily with the metal when the chloroplatinate is boiled with water and a mixed product is obtained on cooling. 

The term distillation is applied to vaporisation and subsequent condensation according to (i) it should also be applied to (ii) since it is really the liquid which is converted into vapour and is first formed by condensation. Strictly speaking, the term sublimation should be applied to changes according to (iii). However, in practice, a substance when heated may first melt and then boil, but on cooling it may pass directly from the vapour to the solid the process is then also called sublimation. Indeed the mode of vaporisation, whether directly from solid to vapour or through the intermediate formation of a liquid, is of secondary importance it is the direct conversion of vapour to solid which is really the outstanding feature of sublimation in the laboratory. 

Add 0-5-1 ml. of the alcohol, cork the flask loosely, and heat on a water bath for 10 minutes secondary and tertiary alcohols require longer heating (up to 30 minutes). Cool the mixture, add 10 ml. of 5 per cent, (or saturated) sodium bicarbonate solution, break up the resulting solid ester with a stirring rod (alternatively, stir until crystalline), and filter at the pump wash with a little sodium bicarbonate solution, followed by water, and then suck as dry as possible. Dissolve the crude... 

Place a mixture of 0-5 g. of finely powdered thiourea, 0-5 g. of the alkyl halide and 5 ml. of alcohol in a test-tube or small flask equipped with a reflux condenser. Reflux the mixture for a j)eriod depending upon the nature of the halide primary alkyl bromides and iodides, 10-20 minutes (according to the molecular weight) secondary alkyl bromides or iodides, 2-3 hours alkyl chlorides, 3-5 hours polymethy lene dibromides or di-iodides, 20-50 minutes. Then add 0 5 g. of picric acid, boil until a clear solution is obtained, and cool. If no precipitate is obtained, add a few drops of water. RecrystaUise the resulting S-alkyl-iso-thiuronium picrate from alcohol. 

Dissolve 1 g. of the secondary amine in 3-5 ml. of dilute hydrochloric acid or of alcohol (in the latter case, add 1 ml. of concentrated hydrochloric acid). Cool to about 5° and add 4-5 ml. of 10 per cent, sodium nitrite solution, and allow to stand for 5 minutes. Add 10 ml. of water, transfer to a small separatory funnel and extract the oil with about 20 ml. of ether. Wash the ethereal extract successively with water, dilute sodium hydroxide solution and water. Remove the ether on a previously warmed water bath no flames should be present in the vicinity. Apply Liebermann s nitroso reaction to the residual oil or solid thus. Place 1 drop or 0 01-0 02 g. of the nitroso compovmd in a dry test-tube, add 0 05 g. of phenol and warm together for 20 seconds cool, and add 1 ml. of concentrated sulphuric acid. An intense green (or greenish-blue) colouration will be developed, which changes to pale red upon pouring into 30-50 ml. of cold water the colour becomes deep blue or green upon adding excess of sodium hydroxide solution. 

Method 2. Place a 3 0 g. sample of the mixture of amines in a flask, add 6g. (4-5 ml.) of benzenesulphonyl chloride (or 6 g. of p-toluenesulphonyl chloride) and 100 ml. of a 5 per cent, solution of sodium hydroxide. Stopper the flask and shake vigorously until the odour of the acid chloride has disappeared open the flask occasionally to release the pressure developed by the heat of the reaction. AUow the mixture to cool, and dissolve any insoluble material in 60-75 ml. of ether. If a solid insoluble in both the aqueous and ether layer appears at this point (it is probably the sparingly soluble salt of a primary amine, e.g., a long chain compound of the type CjH5(CH2) NHj), add 25 ml. of water and shake if it does not dissolve, filter it off. Separate the ether and aqueous layers. The ether layer will contain the unchanged tertiary amine and the sulphonamide of the secondary amine. Acidify the alkaline aqueous layer with dilute hydrochloric acid, filter off the sulphonamide of the primary amine, and recrystaUise it from dilute alcohol. Extract the ether layer with sufficient 5 per cent, hydrochloric acid to remove all the tertiary amine present. Evaporate the ether to obtain the sulphonamide of the secondary amine recrystaUise it from alcohol or dilute alcohol. FinaUy, render the hydrochloric acid extract alkaline by the addition of dilute sodium hydroxide solution, and isolate the tertiary amine. 

Below the NTC region, iatramolecular abstraction appears to generate P-dicarbonyl iatermediates that are consumed duriag cool flames (161—164). Secondary attack on nonradical monofunctionals does not appear to be a significant source for these difunctional iatermediates. 

The flame-space walls are stainless steel and are water cooled. No mechanical coke scraper is required. A water quench cools the cracked gas stream rapidly at the poiat of maximum acetyleae and this is followed by a secondary water quench. The primary quench poiat can be adjusted for variation ia throughput, to accommodate the depeadeace of acetyleae yield oa resideace time ia the flame space. 

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