Cooling Helical

Karimi [120] applied his analysis to solve the reflux condenser geometry shown in Fig. 14.19. In this situation, vapor condenses on the outside of a cooled, helically coiled tube and flows... 

Amorphous or "plastic" sulfur is obtained by fast cooling of the crystalline form. X-ray studies indicate that amorphous sulfur may have a helical structure with eight atoms per spiral. Crystalline sulfur seems to be made of rings, each containing eight sulfur atoms, which fit together to give a normal X-ray pattern. 

Tetramethylsilane (TMS) [75-76-3] M 88.2, b 26.3, n 1.359, d 0.639. Distilled from cone H2SO4 (after shaking with it) or LiAlH4, through a 5ft vacuum-jacketted column packed with glass helices into an ice-cooled condenser, then percolated through silica gel to remove traces of halide. 

Martensite transformations are not limited just to metals. Some ceramics, like zirconia, have them and even the obscure system of (argon + 40 atom% nitrogen) forms martensite when it is cooled below 30 K. Helical protein crystals in some bacteria undergo a martensitic transformation and the shape change helps the bacteria to burrow into the skins of animals and people ... 

Head coefficient, 156 Head equation, adiabatic, 3 t Head equation, poly tropic, I Head, centrifugal, 156 Head, reciprocating, 58 Heat run test (dry), 413 Helical compressor, 5, 7 adiabatic efficiency, Itil applicalion mnge, 7. ly asymmetric profile, 96 bearings, 116 capacity control, 95 casings, 114 circular profile, 95 cooling, I i 1 discharge temperature (dry), I 17... 

To the cooled mixture 6N hydrochloric acid is added drop wise with stirring, until no solid remains. The organic layer is separated, washed four times with 30-ml. portions of water (Note 6), dried over powdered calcium chloride (Note 7), and distilled through a 1 X 15 cm. column packed with Fenske helices (Note 8). The yield of benzene is 5.5-6.5 g. (70-83%), b.p. 80-82°, n20d 1.5007. The fraction boiling at 82-180° contains no unreacted chlorobenzene (Notes 9, 10, 11). 

Cyclopentadiene was prepared2 by heating dicyclopentadiene (purchased from Eastman Organic Chemicals) and a pinch of hydro-quinone (1,4-benzenediol) under a column of glass helices or a Vigreux column at 175° and collecting the distillate in a receiver cooled with a 2-propanol-dry ice bath. The monomer was dried over Linde 4A Molecular Sieves at —20° and could be stored at this temperature for several weeks without excessive dimerization. 

Helical coils, heat transfer in 496 -- cooling coils 496... 

An example of a low conversion reactor would be a conventionally agitated kettle with large turbine agitators and jacket cooling. The utility of this type of reactor can be extended to intermediate conversions by the use of anchor or helical agitators to partially overcome heat transfer and mixing problems at higher viscosities. 

This patent then calls for two or more reflux cooled conical CSTR s with helical ribbon agitators operating in series in an "intermediate conversion zone" ranging from 65 to 85% conversion. The conversion in succeeding reactors in this zone should show a relative difference of 15-25%. As with the earlier patent,... 

Because of the conversion of orthorhombic sulfur to monoclinic form, the above values of melting points are difficult to observe, as the resulting allotropic mixture melts at only 115 C. Amorphous or plastic sulfur can be produced through the rapid cooling of molten sulfur. X-ray crystallographic studies show that the amorphous form may have a helical structure with eight atoms per turn. This form is metastable at room temperature and gradually reverts back to crystalline within hours to days but this conversion can be rapidly catalyzed. 

The introduction of a second chiral atom in the system leads to a reduction in the mesogenic properties and only a monotropic chiral nematic transition is observed for compound 23. However, when this compound is cooled down from the isotropic liquid state at a cooling rate of 0.5 °Cmin , very unusual blue phases BP-III, BL-II and BP-I are observed in the range 103-88 °C. Blue phases usually require pitch values below 500 nm. Hence the pitch value of the cholesteric phase for 23 must be very short, suggesting that the packing of two chiral carbons forces a faster helical shift for successive molecules packed along the perpendicular to the director. 

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