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Concurrent principle

Excited-State Relaxation. A further photophysical topic of intense interest is pathways for thermal relaxation of excited states in condensed phases. According to the Franck-Condon principle, photoexcitation occurs with no concurrent relaxation of atomic positions in space, either of the photoexcited chromophore or of the solvating medium. Subsequent to excitation, but typically on the picosecond time scale, atomic positions change to a new equihbrium position, sometimes termed the (28)- Relaxation of the solvating medium is often more dramatic than that of the chromophore... [Pg.389]

A key success factor for reducing the costs and lead times for vehicle manufacturers, for example, is the degree of integration of the suppliers within the product development process. This is seen as a natural extension to concurrent engineering principles (Wyatt et al., 1998). For many years, in engineering companies, a substantial proportion of the finished product, typically two thirds, consists of components or subassemblies produced by suppliers (Noori and Radford, 1995). [Pg.271]

An overarching principle of great importance in retrosynthetic analysis is the concurrent use of as many of these independent strategies as possible. Such parallel application of several... [Pg.15]

Scanning tunneling spectroscopy (STS) can, in principle, probe the electronic density of states of a singlewall nanotube, or the outermost cylinder of a multi-wall tubule, or of a bundle of tubules. With this technique, it is further possible to carry out both STS and scanning tunneling microscopy (STM) measurements at the same location on the same tubule and, therefore, to measure the tubule diameter concurrently with the STS spectrum. No reports have yet been made of a determination of the chiral angle of a tubule with the STM technique. Several groups have, thus far, attempted STS studies of individual tubules. [Pg.121]

Toward the end of the nineteenth centuiy, successful two-stroke engines operating on the Otto cycle were developed by Dugald Clerk, James Robson, Karl Benz, and James Day. In this engine, the intake, combustion, expansion, and exhaust events all occur with but two piston strokes, or one crankshaft revolution. In principle this should double the output of a four-stroke engine of equal piston displacement. However, instead of the intake and exhaust events taking place during sequential strokes of the piston, they occur concurrently while the piston is near BDC. This impairs the ability of the... [Pg.559]

In principle, there is also the possibility that concurrent reactions, with different kinetics, may proceed at more than one type of site or at different crystal faces. [Pg.45]

Such systems have the experimental advantage that kinetic data may be obtained by gravimetric or evolved gas pressure measurements. However, these data must be interpreted with care, since gas release is not necessarily concurrent with the solid—solid interaction but may, in principle, be a distinct rate process under independent kinetic control and occur either before or after reaction between the solids. Possible mechanisms to be considered, therefore, include the following. [Pg.272]

Reaction scheme, defined, 9 Reactions back, 26 branching, 189 chain, 181-182, 187-189 competition, 105. 106 concurrent, 58-64 consecutive, 70, 130 diffusion-controlled, 199-202 elementary, 2, 4, 5, 12, 55 exchange, kinetics of, 55-58, 176 induced, 102 opposing, 49-55 oscillating, 190-192 parallel, 58-64, 129 product-catalyzed, 36-37 reversible, 46-55 termination, 182 trapping, 2, 102, 126 Reactivity, 112 Reactivity pattern, 106 Reactivity-selectivity principle, 238 Relaxation kinetics, 52, 257 -260 Relaxation time, 257 Reorganization energy, 241 Reversible reactions, 46-55 concentration-jump technique for, 52-55... [Pg.280]

Measurement caused by concurrent reactions or incomplete reaction processes in the case of chemical principles, and by instrumental deviations and wrong adjustment in the case of physical methods. A frequently encountered reason for the occurrence of systematic deviations is erroneous calibration due to unsuitable calibration standards, matrix effects, or insufficient methodical or theoretical foundation. [Pg.93]

Lea97] Lea, D. 1997. Concurrent Programming in Java Design Principles and Patterns. Reading, Mass. Addison Wesley Longman. [Pg.734]

The four basic statistical principles of experimental design are rephcation, randomization, concurrent ( local ) control and balance. In abbreviated form, these may be summarized as follows. [Pg.873]

This effect, too, will cause the [P+J to be less than cQ. It is an as yet open question whether the complexed growing cations P+nM and P+nP can participate directly in BIE, The argument has been conducted in terms of unpaired ions, but paired ions may also be involved, so that there are concurrent Unary (Ostwald type) and BIE, However, this makes no difference in principle, as can be seen from the treatments of BIE, with ion-pairs by Grattan and Plesch (1979), Pask and Nuyken (1983) and Holdcroft and Plesch (1985). [Pg.529]

This still needs to be evaluated. The technology provider plans to test the new RDM at the vendor s facility prior to shipment. No proof of principle prior to this time is anticipated, especially demonstration of the efficacy of the tube-cutting concept for concurrent cutting of firing tubes and contained rockets. Also, the capability of the punch-and-drain and rocket-cutting operations to prevent agent contamination of energetics has not been demonstrated. [Pg.88]

Concurrent stream of the development of nanomaterials for solid-state hydrogen storage comes from century-old studies of porous materials for absorption of gasses, among them porous carbon phases, better known as activated carbon. Absorption of gases in those materials follows different principles from just discussed absorption in metals. Instead of chemisorption of gas into the crystalline structure of metals, it undergoes physisorption on crystalline surfaces and in the porous structure formed by crystals. The gases have also been known to be phy-sisorbed on fine carbon fibers. [Pg.23]


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See also in sourсe #XX -- [ Pg.109 , Pg.110 ]




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