Compounds trihalides

Atmospheric boron is in the form of particulates or aerosols of borides, boron oxide, borates, boranes, organoboron compounds, trihalide boron compounds, or borazines. The half-time persistence of airborne boron particles is short, usually on the order of days (USPHS 1991). 

In Electropositive character Tendency to form covalent T1 Lewis acid strength of compounds trihalides of B increases from BF3 BBr3... 

Fig. 8. Comparison of energetics of dissolution of an ionic lanthanide compound (trihalide shown in this example) versus an isostructural actinide compound. Note that the enthalpy of solution of the lanthanide...

With tetiaaiyltin compounds, the reaction can proceed further to the aryltin trihalides ... 

The boron trihalides are volatile, highly reactive, monomeric molecular compounds which show no detectable tendency to dimerize (except perhaps in Kr matrix-isolation experiments at 20K). In... 

The boron trihalides form a great many molecular addition compounds with molecules... 

All 4 trihalides are volatile reactive compounds which feature pyramidal molecules. The fluoride is best made by the action of CaF2, Znp2 or Asp3 on PCI3, but the others are formed by direct halogenation of the element. PF3 is colourless, odourless and does not fume in air, but is very hazardous due to the formation of a complex with blood haemoglobin (cf. 

Many of the trihalides of As, Sb and Bi hydrolyse readily but can be handled without great difficulty under anhydrous conditions. AsFs and SbFs are important reagents for converting non-metal chlorides to fluorides. SbFs in particular is valuable for preparing organofluorine compounds (the Swans reaction) ... 

A coordination compound, or complex, is formed when a Lewis base (ligand) is attached to a Lewis acid (acceptor) by means of a lone-pair of electrons. Where the ligand is composed of a number of atoms, the one which is directly attached to the acceptor is called the donor atom . This type of bonding has already been discussed (p. 198) and is exemplified by the addition compounds formed by the trihalides of the elements of Group 13 (p. 237) it is also the basis of much of the chemistry of the... 

All the trihalides are mixed valence compounds. PtF3 is isostructural with PdF3- PtX3 (X = Cl, Br, I) cannot be made by straightforward thermal decomposition of PtX4 [22] under open conditions but by routes involving continuous decomposition and formation under closed, equilibrium conditions. 

As with the trihalides , some formally platinum(III) compounds are in fact mixed-valence species [161]. Thus ... 

The B atom has an incomplete octet in all its trihalides. The compounds consist of trigonal planar molecules with an empty 2p-orbital perpendicular to the molecular plane. The empty orbital allows the molecules to act as Lewis acids, which accounts for the catalytic action of BF3 and BC13. 

A very useful route to monoalkyltin trihalides involves the reaction of stannous bromide with alkyl bromides in the presence of 5 mol % of a trialkylantimony compound (47). A typical example is shown in the following equation. 

This reaction is similar to the previous one. The utility of the method is limited by the lack of availability of trihalides, though these compounds can be prepared by addition of CCI4 and similar compounds to double bonds (15-44) and by the free... 

Unlike the di-f dihalides, such compounds differ little in energy from both the equivalent quantity of metal and trihalide, and from other combinations with a similar distribution of metal-metal and metal-halide bonding. So the reduced halide chemistry of the five elements shows considerable variety, and thermodynamics is ill-equipped to account for it. All four elements form di-iodides with strong metal-metal interaction, Prl2 occurring in five different crystalline forms. Lanthanum yields Lai, and for La, Ce and Pr there are hahdes M2X5 where X=Br or I. The rich variety of the chemistry of these tri-f compounds is greatly increased by the incorporahon of other elements that occupy interstitial positions in the lanthanide metal clusters [3 b, 21, 22]. 

A. Synthetic Methods.—Electrophilic addition of P compounds to olefinic compounds is a well-established route to phosphonic acids, although yields are often disappointing. With phosphorus pentachloride it has been found that yields are greatly improved when phosphorus trichloride is added to the reaction mixture. Since the orientation of the addition implies that electrophilic addition to phosphorus rather than chlorine is the initial step, it seems likely that the trihalide participates by decreasing the free concentration of chlorine rather than by a more active role. This... 

When the phosphorus compound is a phosphorus trihalide or phosphoryi (or... 

A correlation of isomer shift, electronic configuration, and calculated -electron densities for a number of ruthenium complexes in analogy to the Walker-Wertheim-Jaccarino diagram for iron compounds has been reported by Clausen et al. [ 127]. Also useful is the correlation between isomer shift and electronegativity as communicated by Clausen et al. [128] for ruthenium trihalides where the isomer shift appears to increase with increasing Mulliken electronegativity. 

Exceptions to the rule are observed for compounds with low polarity, i.e. when covalent bonds predominate. Fluorides and oxides (including silicates) usually fulfill the rule, whereas it is inapplicable to chlorides, bromides, iodides, and sulfides. For instance, in metal trifluorides like FeF3 octahedra sharing vertices are present, while in most other trihalides octahedra usually share edges or even faces. 

Boron-based Lewis acids are often used in organic syntheses. Since the boron atom has an empty / -orbital, many boron compounds can function as Lewis acids. Typical boron Lewis acids are boron trihalides, for which Lewis acidity increases according to the order of fluoride < chloride < bromide < iodide, the reason for this order being the relative abilities of the different halogens to act as 7r-donors to boron. 

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