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Compositional changes, methods analysis

An associated technique which links thermal properties with mechanical ones is dynamic mechanical analysis (DMA). In this, a bar of the sample is typically fixed into a frame by clamping at both ends. It is then oscillated by means of a ceramic shaft applied at the centre. The resonant frequency and the mechanical damping exhibited by the sample are sensitive measurements of the mechanical properties of a polymer which can be made over a wide range of temperatures. The effects of compositional changes and methods of preparation can be directly assessed. DMA is assuming a position of major importance in the study of the physico-chemical properties of polymers and composites. [Pg.495]

The three basic experimental features of gas-phase kinetic studies are temperature control, time measnrement, and the determination of concentrations. Of these, the principal problem is that of following the composition changes in the system. Perhaps the most generally applicable technique is the chemical analysis of aliqnots however, continuons methods are much more convenient. By far the easiest method is to follow the change in total pressure. This technique will be used in the present experiment. Obvionsly the pressure method is possible only for a reaction that is accompanied by a change in the niunber of moles of gas. Also the stoichiometry of the reaction should be straightforward and well understood, so that pressure changes can be related directly to extent of reaction. [Pg.291]

Ideally, the catalytic chemist would desire a technique capable of analysing the surface composition of bimetallic nanoparticles. Currently, no truly reliable methods exist for this type of analysis. XPS and EXAFS are not sufficiently accurate and CO adsorption may itself induce compositional changes in the surface layer. However, these techniques, perhaps used in tandem with high resolution techniques such as HRTEM, do provide useful qualitative insight into the surface composition of bimetallic particles. [Pg.522]

The study of electrical conductivity of molten salts is one of the indirect methods used for the determination of molten salts structure and of component interaction in molten mixtures. The change in composition of a molten mixture is often accompanied by structural changes, which affect the dependence character of the electrical conductivity on composition. Consequently, an analysis of this dependence should provide some information regarding the present ionic species and their arrangement in the melt. Supplementary information, i.e. concerning the formation and decomposition of complex ions, the character of the cation-anion bond, and the character of conductivity, cationic, anionic, electronic, etc., can be obtained from analysis of the dependence of the activation energy on composition. [Pg.329]

The methods suitable for control of surface cleanliness are mainly those discussed in Section 3.1.2. Compositional changes on and near the surface of glass (i.e. to a depth of about 20 A) can be measured with Auger electron spectroscopy (AES), electron spectroscopy for chemical analysis (ESCA), ion-scattering spectroscopy... [Pg.69]

In theory, if composition of the mixture is known, then calculation of any characteristic property of the multi-component mixture can be performed by the classical physical and chemical analysis methods. For binary liquid system, it is possible only if all chemical forms (including all possible associates), their stoichiometry, stability constants, and their individual physical and chemical properties are well determined. A large volume of correct quantitative thermodynamic data required for these calculations is not available. Due to these obstacles, data on permittivity, viscosity and other macro-properties of mixed solvents with interacting components are obtained by empirical means. Data on empirical physical properties of liquid systems can be found in published handbooks.Principles of characteristic changes due to the compositional change of liquid mixtures with interacting components are discussed here. Assessment of nature of such interactions can only be made after evaluation of the equilibrium constant (energy) of such interactions between solvents. [Pg.518]

Finally, the comparison of both local (EDS) and bulk chemical analysis (AA) gives the opportunity to follow the compositional changes occurring in the clay platelets during the pillaring reaction. Furthermore, the true composition of the clay fraction, which is precluded from traditional chemical analysis, can be obtained by BIDS methods. [Pg.106]

Other methods related to the moving boundary method include the indirect moving boundary method (where the concentration in the trailing edge behind the boundary is monitored) and the analytical boundary method. The latter approach involves analysis of the compositional change within the moving boundary zone and is a hybrid of the Hittorf and standard moving boundary techniques. [Pg.858]


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See also in sourсe #XX -- [ Pg.253 ]




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