Combustion with fuel modification

Six cycles with oxidant modification are listed as D1 the simple PO open CBT cycle—involving staged combustion of the fuel ... 

The basic approach taken in the analytical studies of composite-propellant combustion represents a modification of the studies of double-base propellants. For composite propellants, it has been assumed that the solid fuel and solid oxidizer decompose at the solid surface to yield gaseous fuel and oxidizing species. These gaseous species then intermix and react in the gas phase to yield the final products of combustion and to establish the flame temperature. Part of the gas-phase heat release is then transferred back to the solid phase to sustain the decomposition processes. The temperature profile is assumed to be similar to the situation associated with double-base combustion, and, in this sense, combustion is identical in the two different types of propellants. 

Flue gas recirculation Flue gas recirculation, alone or in combination with other modifications, can significantly reduce thermal NO,. Recirculated flue gas is a diluent that reduces flame temperatures. External and internal recirculation paths have been applied internal recirculation can be accomplished by jet entrainment using either combustion air or fuel jet energy external recirculation requires a fan or a jet pump (driven by the combustion air). When combined with staged-air or staged-fuel methods, NO emissions from gas-fired burners can be reduced by 50 to 90 percent. In some applications, external flue-gas recirculation can decrease thermal efficiency. Condensation in the recirculation loop can cause operating problems and increase maintenance requirements. 

A car with this modification produces NO carbon dioxide and NO carbon monoxide, but since air is mixed with the gas combustion, it is likely that the greenhouse gas Nitrous Oxide is produced. But Nitrous Oxide dissolves reasonably well in water, so since the exhaust gasses are passed through the header tank which contains the water fuel, it is likely that this engine arrangement is a good deal greener than most. 

The complicated situation in which methyl radicals participate in the equilibrium with oxygen and methylperoxy and the methylperoxy radicals can react further by at least two alternative routes, is capable of explaining many of the features of acetone slow combustion. Similar arguments, with appropriate modifications, can be developed for the combustion of other fuels. 

There are several approaches available to a utility to construct a boiler that will meet New Source Performance Standards. These approaches can be classified according to the position in the combustion system at which pollutant control technology is applied. Precombustion control involves removal of sulfur, nitrogen, and ash compounds from the fuel before it is burned. For coal combustion this approach involves the application of coal-cleaning technology. Combustion control relies on modifications to the combustion process itself or the addition of material to the combustion process to reduce pollutant formation or capture the pollutants formed in the combustion chamber. Examples of combustion control include staged combustion, boiler limestone injection, and fluidized-bed combustion with limestone addition. Post-combustion control involves removal of pollutants after they have been formed but before they are released into the atmosphere. Traditionally, flue gas desulfurization has meant the application of postcombustion control either alone or in conjunction with another... 

Selection of pollution control methods is generally based on the need to control ambient air quaUty in order to achieve compliance with standards for critetia pollutants, or, in the case of nonregulated contaminants, to protect human health and vegetation. There are three elements to a pollution problem a source, a receptor affected by the pollutants, and the transport of pollutants from source to receptor. Modification or elimination of any one of these elements can change the nature of a pollution problem. For instance, tall stacks which disperse effluent modify the transport of pollutants and can thus reduce nearby SO2 deposition from sulfur-containing fossil fuel combustion. Although better dispersion aloft can solve a local problem, if done from numerous sources it can unfortunately cause a regional one, such as the acid rain now evident in the northeastern United States and Canada (see Atmospheric models). References 3—15 discuss atmospheric dilution as a control measure. The better approach, however, is to control emissions at the source. 

The WP L cyclone boiler will bum I DE continuously with coal, as about 5% of its fuel mix, with htfle or no modification. By contrast, pulverized-coal boilers, which account for about 80% of the coal-fired capacity in the United States, probably caimot bum tire chips without significant modifications. In these boilers, which bum very fine coal particles in suspension, the heavy chips will fall from the area where best combustion occurs. 

These ideas form the basis of most approaches to NO control with N-containing fuels. In principal, they are readily appHcable to the modification of certain combustors in which the desired divisions in the combustion process exist for other reasons. Although such improvements have been demonstrated, it is difficult in practice to make the required revisions in the air and fuel distribution without adverse effects on other emissions or on performance. It has also been shown that when steam is used to reduce thermal NO production, the formation of NO from fuel N is enhanced, or the reduction is less than otherwise expected. 

Plants (B) with modification of the fuel in combustion-turbine (CRGT) cycles... 

In particular, the cycles involving fuel or oxidant modification do not look sufficiently attractive for their development to be undertaken, with the possible exception of the multiple PO combustion plant proposed by Harvey et al. [14]. The Matiant plant has the advantage of relatively simple CO2 removal and high efficiency and may prove to be attractive, but it again looks complex and expensive. 

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