Cohesion measurements

The last chapter (12) is concerned with evaluation methods of polymer-conditioned hair. The first part deals with single-fiber evaluation and includes contact angle, electroki-netic, fiuorimetiy, friction, and cuticle-cohesion measurements. The second part deals with hair assemblies and includes measurements of combing, body, optical properties, and static electrification. 

Linseis Plastometer. A device designed by M. Linseis for the evaluation of the plasticity of clay on the basis of two parameters cohesion (measured as tensile strength) and the capacity for relative movement of the clay particles without rupture. The apparatus is made by Netzsch Bros., Selb, Germany. 

A linear relationship exists between the cohesive energy density of an abrasive (10) and the WoodeU wear resistance values occurring between comndum H = 9) and diamond H = 42.5). The cohesive energy density is a measure of the lattice energy per unit volume. 

Diffusion Theory. The diffusion theory of adhesion is mosdy appHed to polymers. It assumes mutual solubiUty of the adherend and adhesive to form a tme iaterphase. The solubiUty parameter, the square root of the cohesive eaergy deasity of a material, provides a measure of the iatermolecular iateractioas occurring within the material. ThermodyaamicaHy, solutioas of two materials are most likely to occur whea the solubiUty parameter of oae material is equal to that of the other. Thus, the observatioa that "like dissolves like." Ia other words, the adhesioa betweea two polymeric materials, oae an adherend, the other an adhesive, is maximized when the solubiUty parameters of the two are matched ie, the best practical adhesion is obtained when there is mutual solubiUty between adhesive and adherend. The diffusion theory is not appHcable to substantially dissimilar materials, such as polymers on metals, and is normally not appHcable to adhesion between substantially dissimilar polymers. 

Neoprene—phenohc contact adhesives, known for thein high green strength and peel values, contain a resole-type resin prepared from 4-/-butylphenol. The alkyl group increases compatibiHty and reduces cross-linking. This resin reacts or complexes with the metal oxide, eg, MgO, contained in the formulation, and increases the cohesive strength of the adhesive. In fact, the reactivity with MgO is frequently measured to determine the effectiveness of heat-reactive phenoHcs in the formulation. 

In order to develop the proper dow pattern, knowledge of a material s dow properties is essential. Standard test equipment and procedures for evaluating sohds dow properties are available (6). Direct shear tests, mn to measure a material s friction and cohesive properties, allow determination of hopper wall angles for mass dow and the opening size required to prevent arching. Other devices available to evaluate sohds dowabiUty include biaxial and rotary shear testers. 

In order to characterize this bonding tendency, the flow function of a material must be deterrnined. Data on flow function can be generated in a testing laboratory by measuring the cohesive strength of the bulk soHd as a function of consoHdation pressure appHed to it. Such strength is directly related to the abihty of the material to form arches and ratholes in bins and hoppers. 

A material s flow function is usually measured on the same tester as the wall friction angle, although the cell arrangement is somewhat different (Fig. 6). ConsoHdation values are easily controUed, and the cohesive strength of the bulk soHd is determined by measuring interparticle shear stresses while some predeterrnined normal pressure is being appHed. 

Because fiber frictional properties are so important in the conversion of staple yams to spun yams, ASTM D2612 has been designed to measure the cohesive force encountered in the drafting or fiber alignment of sHver and top under static conditions. This frictional force is affected by surface lubrication, linear density, surface configuration, fiber length, and fiber crimp. 

Standard Test Method for Adhesion Between Steel Tire Cords and Rubber. Steel cords are vulcanised into a block of mbber and the force necessary to pull the cords linearly out of the mbber is measured as adhesive force. ASTM method D2229-93a can be used for evaluating mbber compound performance with respect to adhesion to steel cord. The property measured by this test method indicates whether the adhesion of the steel cord to the mbber is greater than the cohesion of the mbber, ie, complete mbber coverage of the steel cord or less than the cohesion of mbber (lack of mbber coverage). 

When making measurements in the soil box, it has to be remembered that soil samples can change from their original condition and this will have an effect on the resistivity. Soil resistivity measurements in the soil box only give accurate results with cohesive soils. However, the order of magnitude of the specific resis-... 

The internal pressure is a differential quantity that measures some of the forces of interaction between solvent molecules. A related quantity, the cohesive energy density (ced), defined by Eq. (8-35), is an integral quantity that measures the total molecular cohesion per unit volume. - p... 

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