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Cinnamic acid structures

As shown in Schemes 10-44 and 10-45, two products may be formed in a Meerwein reaction Scheme 10-44 shows a simple aryl-de-hydrogenation of cinnamic aldehyde, whereas Scheme 10-45 shows an aryl-de-hydrogenation combined with the addition of HC1 to the double bond of the methyl ester of cinnamic acid. No systematic studies have been made as to which of the two products will be formed in a given reaction, what experimental conditions will favor one or the other product, and what substituents or other structural characteristics of the alkene influence the ratio of the two types of product. The addition product can, in most cases, easily be converted... [Pg.244]

To date, the crystal structures of more than 200 mesogenic compounds are known. In this review, we wish to present a general overview of the crystal structures of mesogenic compounds up to the end of 1997. Unfortunately, it is not possible to consider the crystal structure determinations of carbohydrate liquid crystals [13, 14], metallomesogens [15-18], phasmid and biforked mesogens [19-22], perfluorinated mesogenic compounds [23-27], benzoic acids [6, 28-31], cinnamic acids [7, 32, 33], dicarboxylic acids [34, 35], cinnamate compounds [8, 36-40], and discotic liquid crystals [41-43] due to the lack of space. [Pg.141]

Figure 10.6 Chemical structure of the polystyrene component labeled with trans-cinnamic acid (PSC). Figure 10.6 Chemical structure of the polystyrene component labeled with trans-cinnamic acid (PSC).
Two hypotheses have been proposed to explain how phenolic acids directly increase membrane permeability. The first is that the compounds solubilize into cellular membranes, and thus cause a "loosening" of the membrane structure so that minerals can leak across the membrane (28-30, 42). Support for this hypothesis comes from the fact that the extent of inhibition of electrical potentials correlates with the log P (partition coefficient of a compound between octanol and water) for various benzoic and cinnamic acid derivatives (Figure 5). [Pg.173]

A single-to-single crystal phase transition was found to take place at 333 K in a new polymorph of ort/zo-ethoxy-trans-cinnamic acid [77]. In this study, the structures of the title compound obtained at two temperatures above the transition point were determined in addition to the structures of the stabilized forms existing at lower temperatures. It was found that the phase transition involved a cooperative conformational transformation coupled with a shift in layers of the constituent molecules. [Pg.273]

The structural changes that accompanied the [2 + 2] photodimerization of the metastable a -polymorph of ort/zo-ethoxy-tranx-cinnamic acid have been studied [93]. In this study, the photochemical reaction was carried out at 293 K, and observed in situ by single-crystal X-ray diffraction. In the structure of the title compound, the three molecules in the asymmetric unit are arranged to form two potential reaction sites, but only one of these was found to be photoreactive. Since only two out of three molecules in the asymmetric unit take place in the photodimerization reaction, the crystal of the final product contains an ordered arrangement of the photodimer and the unreacted monomer. [Pg.276]

Recently, we developed a new matrix based on nanoparticle technologies, which have a completely different chemical structure from benzoic or cinnamic acid derivatives.17 Derivatives of these matrices may enhance specific molecules in IMS. [Pg.377]

Hydroxy cinnamic acids are included in the phenylpropanoid group (C6-C3). They are formed with an aromatic ring and a three-carbon chain. There are four basic structures the coumaric acids, caffeic acids, ferulic acids, and sinapic acids. In nature, they are usually associated with other compounds such as chlorogenic acid, which is the link between caffeic acid and quinic acid. [Pg.56]

Figure 39. Four ribbons of cinnamide (phenyl = ) molecules. Ribbons / and l, d and d are related by translation. Ribbons d and /, d and l make plane-to-plane contacts of 4 A across centers of symmetry. Ribbon / is above d, and ribbon d is below l. Cinnamic acid molecules (filled circles) have been introduced into the structure in the allowed sites, assuming the crystal grows from the center in the two opposite directions +b and —b. The dimers obtained at the two opposite sides are enantiomeric. Figure 39. Four ribbons of cinnamide (phenyl = <t>) molecules. Ribbons / and l, d and d are related by translation. Ribbons d and /, d and l make plane-to-plane contacts of 4 A across centers of symmetry. Ribbon / is above d, and ribbon d is below l. Cinnamic acid molecules (filled circles) have been introduced into the structure in the allowed sites, assuming the crystal grows from the center in the two opposite directions +b and —b. The dimers obtained at the two opposite sides are enantiomeric.
The hydrogenation reaction is carried out with a substituted cinnamic acid. The acetamido group is of particular importance because it functions as a secondary complexation function in addition to the alkene functionality. In the first step the alkene co-ordinates to the cationic rhodium species (containing an enantiopure phosphine DIPAMP in Figures 4.4 and 4.5 with the chirality at phosphorus carrying three different substituents, Ph, o-An, CH2) for which there are several diasteromeric structures due to ... [Pg.80]

This limitation is well Illustrated by the failure of those methods to uncover the presence of another important group, the flavanoid, coumarin and cinnamic acid phenols (85 - 117). On the other hand, some 32 of these compounds were identified when isolation procedures specific for these types of compounds were employed. Using isolation and identification techniques which are particularly useful for alkaloids, it would be possible to determine whether any representatives of this class are present and, if so, to conduct subsequent studies for structure determination. [Pg.297]

Lignin has a complex structure that varies with the source, growing conditions, etc. This complex and varied structure is typical of many plant-derived macromolecules. Lignin is generally considered as being formed from three different phenylpropanoid alcohols— coniferyl, coumaryl, and sinapyl alcohols, which are synthesized from phenylalanine via various cinnamic acid derivatives and commercially is sometimes treated as being composed of a Cg repeat unit where the superstructure contains aromatic and aliphatic alcohols and ethers, and aliphatic aldehydes and vinyl units. [Pg.294]

The examples of ex situ steady-state X-ray photodiffraction utihzed to follow the photodimerizations of olefin bonds in a single-crystal-to-single-crystal (or nearly so) manner are ubiquitous in the chemical literature. The interest of sohd-state chemists in this reaction dates back to the work of Cohen and Schmidt [30, 31], and it has become much of a guinea pig in organic solid-state photochemistry. In 1993, Enkelmann and collaborators published two seminal papers in the Journal of the American Chemical Society [32] and in Angewandte Chemie [33], where they presented a series of structures of a-tra s-cinnamic acid crystals reacted to various extents. These reports laid the way for a plethora of later studies on the olefin photodimerization reaction. The convenience of the high conversion and the simple mechanism, combined with the relatively small structural perturbation that it requires, has turned this reaction into a very useful tool to probe intermolecular... [Pg.121]

Fig. 6 Results from Rietveld refinement of the disordered crystal structure of the P polymorph of p-formyl-tranj--cinnamic acid. The disorder concerns two orientations of the formyl group as shown in (a). The crystal structure in (b) shows only the disorder component of higher occupancy. The results from Rietveld refinement shown at the bottom are for (c) an ordered model comprising only the major orientation of the formyl group, and (d) the final disordered model (right side). Apart from the description of the order/disorder of the formyl group, all other aspects of these refinement calculations were the same. A slight improvement in the quality of the Rietveld fit for the disordered model is evident... Fig. 6 Results from Rietveld refinement of the disordered crystal structure of the P polymorph of p-formyl-tranj--cinnamic acid. The disorder concerns two orientations of the formyl group as shown in (a). The crystal structure in (b) shows only the disorder component of higher occupancy. The results from Rietveld refinement shown at the bottom are for (c) an ordered model comprising only the major orientation of the formyl group, and (d) the final disordered model (right side). Apart from the description of the order/disorder of the formyl group, all other aspects of these refinement calculations were the same. A slight improvement in the quality of the Rietveld fit for the disordered model is evident...

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Acids cinnamic acid

Cinnamate

Cinnamates

Cinnamic 4-

Cinnamic acid

Cinnamic acid/cinnamate

Cinnamics

Crystal structure cinnamic acids

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