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Cinnamaldehyde, reactions

Fig. 44.6 Product inhibition in the ruthenium-catalyzed hydrogenation of cinnamaldehyde. Reaction conditions 0.1 mmol RuCI3, 0.5 mmol TPPTS, H20 Toluene ratio 5 mL 5 mL. Fig. 44.6 Product inhibition in the ruthenium-catalyzed hydrogenation of cinnamaldehyde. Reaction conditions 0.1 mmol RuCI3, 0.5 mmol TPPTS, H20 Toluene ratio 5 mL 5 mL.
ChOLESTANE, 30-METHOXY-, 41, 9 Cholestanol, etherification of, 41, 9 Cholestanyl methyl ether, 41, 9 Cinnamaldehyde, reaction with Wittig reagent, 40,86... [Pg.111]

As for us and for basic practical reasons we have chosen to study the selective hydrogenation of 2-pentyl-2-nonenal and, in certain cases, compare the selectivity of this reaction with the one of cinnamaldehyde reaction Furthermore we have used as catalysts, systems whose preparation involved steps similar to those involved in the preparation of ZIEGLER type catalysts which, though initially developed for the polymerization of olefins, have been used since for various reactions. In particular in our laboratory, we have used them for the selective hydrocondensation of carbon monoxide, or methanol, into light olefins (19,20)... [Pg.203]

A number of other valuable aroma chemicals can be isolated from essential oils, eg, eugenol from clove leaf oil, which can also, on treatment with strong caustic, be isomerked to isoeugenol, which on further chemical treatment can be converted to vanillin (qv). Sometimes the naturally occurring component does not requke prior isolation or concentration, as in the case of cinnamaldehyde in cassia oil which, on dkect treatment of the oil by a retro-aldol reaction, yields natural ben2aldehyde (qv). This product is purified by physical means. [Pg.297]

Physical and Chemical Properties. The (F)- and (Z)-isomers of cinnamaldehyde are both known. (F)-Cinnamaldehyde [14371-10-9] is generally produced commercially and its properties are given in Table 2. Cinnamaldehyde undergoes reactions that are typical of an a,P-unsaturated aromatic aldehyde. Slow oxidation to cinnamic acid is observed upon exposure to air. This process can be accelerated in the presence of transition-metal catalysts such as cobalt acetate (28). Under more vigorous conditions with either nitric or chromic acid, cleavage at the double bond occurs to afford benzoic acid. Epoxidation of cinnamaldehyde via a conjugate addition mechanism is observed upon treatment with a salt of /-butyl hydroperoxide (29). [Pg.174]

Manufacture. Cinnamaldehyde is routinely produced by the base-cataly2ed aldol addition of ben2aldehyde /7(9(9-with acetaldehyde [75-07-0], a procedure which was first estabUshed in the nineteenth century (31). Formation of the (H)-isomer is favored by the transition-state geometry associated with the elimination of water from the intermediate. The commercial process is carried out in the presence of a dilute sodium hydroxide solution (ca 0.5—2.0%) with at least two equivalents of ben2aldehyde and slow addition of the acetaldehyde over the reaction period (32). [Pg.175]

Health and Safety. FEMA has examined cinnamaldehyde and estabhshed its GRAS status (No. 2286). The material has been used in some fragrance compositions, but RJEM (34) has noted its potential for sensiti2ation and limited the use in perfumes for skin contact at 1% in the formula. Eugenol and limonene have been used in conjunction with cinnamaldehyde as quenchers to neutrali2e the irritation reaction that some individuals have toward this aldehyde. [Pg.175]

Diphenylbutadiene has been obtained from phenylacetic acid and cinnamaldehyde with lead oxide, by the dehydrogenation of l,4-diphenyl-2-butene with butyllithium, and by the coupling reaction of benzenediazonium chloride and cinnamyl-ideneacetic acid." The present method gives better yields than those previously reported, is adaptable to the preparation of a variety of substituted bistyryls, and is relatively easy to carry out. [Pg.38]

A substituted a,/3-unsaturated aldehyde, cinnamaldehyde, has been observed to undergo the same type of two-step 1,3-cycloaddition reaction with a cyclohexanone enamine as acrolein does, forming in this case a stereo-isomeric mixture of substituted bicycloaminoketones in excellent yield (29a,31a,31b). [Pg.218]

Cook and Heilbron report the formation of highly crystalline Schiff bases via the reaction of 5-aminothiazoles and acetone, aldehydes such as cinnamaldehyde, or ketones such as... [Pg.278]

Maleic anhydride is a convenient dienophile because of its rapid reaction with most dienes as well as its stability and ease in handling (although it is poisonous). The diene for this reaction, 1,4-diphenyl-1,3-butadiene, is readily prepared by the Wittig reaction with benzyltriphenylphosphonium chloride and cinnamaldehyde (Chapter 11, Section I). [Pg.71]

A 500-ml, three-necked, round-bottom flask is equipped with a condenser, a dropping funnel, and a thermometer in the reaction mixture. In the flask is placed a mixture of 85% hydrazine (115 ml, 118 g) and 225 ml of 95% ethanol with a few boiling chips. The solution is brought to reflux (mantle) and cinnamaldehyde (100 g, 0.76 mole) is added dropwise over about 30 minutes followed by an additional 30 minutes of refluxing. A still head is attached to the flask and volatiles (ethanol, water, hydrazine hydrate) are slowly distilled at atmospheric pressure until the pot temperature reaches 200° (about 3 hours). Hereafter, phenylcyclopropane is collected over the range 170-180°. When the pot temperature exceeds 250°, the recovery is complete. The crude product (55-65 g) is washed twice with 50-ml portions of water and dried (anhydrous potassium carbonate). Distillation under vacuum through a short column affords the product, bp 60°/13 mm, 79-80°/37 mm, n f 1.5309, about 40 g (45%). [Pg.139]

Cinnamaldehyde, the aromatic constituent of cinnamon oil, can be synthesized by a mixed aldol condensation. Show the starling materials you would use, and write the reaction. [Pg.909]

Chrysene, 46, 95 Cinnamaldehyde, 46, 36 reaction with hydrazine, 47, 99 2,4,6-Collidine in hydrolysis of esters to acids, 46, 8... [Pg.124]

The lithio-derivative derived from cyclohexyl phenyl sulfone underwent 1,2-addition to cyclohexenylideneacetaldehyde or cinnamaldehyde to give the corresponding / -hydroxysulfones387. Reactions of 2,2-dimethyl-4-lithio-1,3-oxathiane 3,3-dioxide 308... [Pg.641]

Beller and coworkers reported hydrosilylation reactions of organic carbonyl compounds such as ketones and aldehydes catalyzed by Fe(OAc)2 with phosphorus ligands (Scheme 21). In case of aldehydes as starting materials, the Fe(OAc)2/PCy3 with polymethylhydrosiloxane (PMHS) as an H-Si compound produced the corresponding primary alcohols in good to excellent yields under mild conditions [67]. Use of other phosphorus ligands, for instance, PPhs, bis(diphenylphosphino) methane (dppm), and bis(diphenylphosphino)ethane (dppe) decreased the catalytic activity. It should be noted that frans-cinnamaldehyde was converted into the desired alcohol exclusively and 1,4-reduction products were not observed. [Pg.48]

Ordinary Grignard reagents react with a, -unsaturated carbonyl compounds and afford both 1,2-adduct and 1,4-adduct. However, methylsulfonyhnethylmagnesium bromide or p-tolylsulfonylmethylmagnesium bromide gave only 1,2-adducts in the reaction with conjugated carbonyl compounds such as crotonaldehyde, cinnamaldehyde, trans-4-phenyl-3-buten-2-one, benzalacetophenone and l,5-diphenyl-2,4-pentadien-l-one. [Pg.637]


See other pages where Cinnamaldehyde, reactions is mentioned: [Pg.127]    [Pg.56]    [Pg.331]    [Pg.127]    [Pg.56]    [Pg.331]    [Pg.175]    [Pg.176]    [Pg.315]    [Pg.87]    [Pg.73]    [Pg.47]    [Pg.71]    [Pg.99]    [Pg.637]    [Pg.127]    [Pg.212]    [Pg.439]    [Pg.172]   
See also in sourсe #XX -- [ Pg.305 ]




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Cinnamaldehyde

Cinnamaldehyde reaction with diethylzinc

Cinnamaldehyde reaction with hydrazine

Cinnamaldehyde, 1,2-additions reactions

Cinnamaldehyde, Perkin reaction

Cinnamaldehyde, reaction with Wittig

Cinnamaldehyde, reaction with Wittig reagent

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