Chromyl chloride oxidative halogenation

Hydratropaldehyde has been prepared by hydrolysis of phenylmethylglycidic ester,2 3 4 by chromyl chloride oxidation of cumene,5 by the elimination of halogen acid or water from halohydrins or glycols,5 8 and by the distillation at ordinary pressure of methylphenylethylene oxide.9,10... [Pg.45]

Halogens, or Oxidants, or Tin(IV) chloride Mellor, 1941, Vol. 2, 11, 90 1941, Vol. 7, 446 1943, Vol. 11, 395 Turpentine ignites in contact with fluorine (at —210°C), chlorine, iodine, chromium trioxide, and chromyl chloride, and usually with tin(IV) chloride. Other highly unsaturated hydrocarbons may be expected to react similarly. [Pg.2612]

BENSULFOID (7704-34-9) Combustible solid (flash point 405°F/207°C). Finely divided dry materia forms explosive mixture with air. The vapor reacts violently with lithium carbide. Reacts violently with many substances, including strong oxidizers, aluminum powders, boron, bromine pentafluoride, bromine trifluoride, calcium hypochlorite, carbides, cesium, chlorates, chlorine dioxide, chlorine trifluoride, chromic acid, chromyl chloride, dichlorine oxide, diethylzinc, fluorine, halogen compounds, hexalithium disilicide, lampblack, lead chlorite, lead dioxide, lithium, powdered nickel, nickel catalysis, red phosphorus, phosphorus trioxide, potassium, potassium chlorite, potassium iodate, potassium peroxoferrate, rubidium acetylide, ruthenium tetraoxide, sodium, sodium chlorite, sodium peroxide, tin, uranium, zinc, zinc(II) nitrate, hexahydrate. Forms heat-, friction-, impact-, and shock-sensitive explosive or pyrophoric mixtures with ammonia, ammonium nitrate, barium bromate, bromates, calcium carbide, charcoal, hydrocarbons, iodates, iodine pentafluoride, iodine penloxide, iron, lead chromate, mercurous oxide, mercury nitrate, mercury oxide, nitryl fluoride, nitrogen dioxide, inorganic perchlorates, potassium bromate, potassium nitride, potassium perchlorate, silver nitrate, sodium hydride, sulfur dichloride. Incompatible with barium carbide, calcium, calcium carbide, calcium phosphide, chromates, chromic acid, chromic... [Pg.156]

GUM SPIRITS or GUM TURPENTINE (8006-64-2) Forms explosive mixture with air (flash point 95°F/35°C). Violent reaction with strong oxidizers, halogens, chlorine, fluorine, iodine, calcium hypochloride, chromyl chloride, dichlorine oxide, ethylene, nitric acid, tin(IV) chloride. Incompatible with strong acids, chromic anhydride, chromyl chloride, diatomaceous earth, hexachloromelamine, stannic chloride. Attacks ordinary rubber. [Pg.606]

SULFUR or SULFUR, MOLTEN or SULFUR, SOLID (7704-34-9) Combustible solid (flash point 405°F/207°C). Finely divided dry material forms explosive mixture with air. The vapor reacts violently with lithium carbide. Reacts violently with many substances, including strong oxidizers, aluminum powders, boron, bromine pentafluoride, bromine trifluoride, calcium hypochlorite, carbides, cesium, chlorates, chlorine dioxide, chlorine trifluoride, chromic acid, chromyl chloride, dichlorine oxide, diethylzinc, fluorine, halogen compounds, hexalithium disilicide, lampblack, lead chlorite, lead dioxide, lithium, powdered nickel, nickel catalysts, red phosphorus, phosphorus trioxide, potassium, potassium chlorite, potassium... [Pg.1103]

Ammonia, anhydrous Mercury, halogens, hypochlorites, chlorites, chlorine(I) oxide, hydrofluoric acid (anhydrous), hydrogen peroxide, chromium(VI) oxide, nitrogen dioxide, chromyl(VI) chloride, sulflnyl chloride, magnesium perchlorate, peroxodisul-fates, phosphorus pentoxide, acetaldehyde, ethylene oxide, acrolein, gold(III) chloride... [Pg.1207]