Chloryl

Chlorocarbonyl, see Chlo-roformyl Chloroformyl Chlorosyl Chloro thio Chloryl... 

It decomposes rapidly at 25°C, giving the very shock-sensitive chloryl hypofluorite. See other iv-halogen compounds, perchlorate salts of nitrogenous bases... 

Schmeisser, M., Angew. Chem., 1955, 67, 498 The dimeric form is formulated as chloryl perchlorate. 

Calcium azide, 3936 f Carbon disulfide, 0560 Chlorine dioxide, 4042 Chloroacetylene, 0652 Chloryl perchlorate, 4104 Copper(I) azide, 4287 Cyanamide, 0404 Cyanoform, 1383 Cyanogen bromide, 0313 Cyanogen chloride, 0323 Cyanogen fluoride, 0323... 

Bromine bromate, 0276 Bromine dioxide, 0258 Bromine perchlorate, 0235 Bromine trioxide, 0259 Bromyl fluoride, 0239 Chlorine dioxide, 4042 Chlorine perchlorate, 4101 Chlorine trifluoride oxide, 3982 Chlorine trioxide, 4044 Chloryl hypofluorite, 3973 Chloryl perchlorate, 4104 Dichlorine oxide, 4095 Dichlorine trioxide, 4100 Dicyanogen AW -dioxidc. 0998 Dioxygen difluoride, 4320 Fluorine perchlorate, 3976 Hexaoxygen difluoride, 4327 Iodine dioxide trifluoride, 4334 Iodine(V) oxide, 4627 Iodine(VII) oxide, 4628 Oxygen difluoride, 4317 Perbromyl fluoride, 0240 Perchloryl fluoride, 3974... 

Chlorine dioxide, 4042 Chlorosulfuric acid, 3997 Chloryl perchlorate, 4104 Chromic acid, 4229 Chromium pentafluoride, 4226 Chromium trioxide, 4242 Chromyl acetate, 1494... 

Electron distributions are studied in the perchlorate anion and in the radical in order to elucidate the pattern of bonding in these systems. Qualitative considerations are supplemented with numerical calculations. Comparison with other efforts supports the previously suggested interpretation of the radical as a weakly exchange coupled complex of an oxygen diatom and a chloryl radical. 

No effort to examine this possibility was undertaken until Byberg observed a similarity between the quadrupole coupling tensors in chloryl and perchlorate radicals. The species CIO4 could be interpreted as an exchange coupled complex of CIO2 and O2 [7]. 

The analysis in this note lends credibility to the findings of Van Huis and Schaefer and indicates a relation to the complex formation of the chloryl and the oxygen molecule. It will be necessary to include an environment in theoretical calculations to bring this matter further. 

Synonyms Aethylis Aethylis chloridum Aethylisaethylis chloridum AI3-24474 Anodynon CCRIS 3349 Chelen Chlorethyl Chloridum Chloryl Chloryl anesthetic Dublofix EINECS 200-830-5 Ether chloratus Ether chloridum Ether hydrochloric Ether muriatic Ethyl chloride F 160 Hydrochloric ether Kelene MCE Monochlorethane Monochloroethane Muriatic ether Narcotile NCI-C06224 R 160 UN 1037. 

Chloryl fluoride is colorless as a gas and liquid, and white as a solid. It is stable under normal conditions and some of its physical properties are summarized in Table XIV. Although precise measurements of some... 

Chloryl fluoride is stable at ambient temperature in well-passivated and dry containers. Its thermal decomposition in quartz was studied by Schumacher et al. 24, 137). It reaches a measurable rate only above 300°C. The decomposition reaction is monomolecular and its rate is pressure-dependent. The actiyation energy was calculated to be 45 2 kcal mole and the rate constant was determined as = 2.3 x 10 X sec . The following decomposition mechanism was... 

With HCl, chloryl fluoride reacts (255) at —110°C according to HCl + FCIO2 ---------------------- HF + CIO2 + iCl2... 

Chloryl fluoride is a fluorinating agent and a moderately strong oxidizer. Thus it can fluorinate AsFs to the pentafluoride (294) ... 

Chloryl fluoride, like most of the other known chlorine fluorides and oxyfluorides, possesses amphoteric character. Owing to its weak and polar (p—jr )a Cl—F bond (see Section II, C), it exhibits a much stronger tendency to form adducts with Lewis acids than with Lewis bases. The adducts with Lewis acids result in salts containing ClOg" cations, and those with bases result in ClOgFj" salts. Both ions are discussed in detail in Sections III, G and H, respectively. 

Although the chloryl cation does not contain a GIF bond and, therefore, in a strict sense does not belong to the family of the chlorine... 

Chloryl fluoride is slightly less volatile than CIF3O2, and, therefore, most of it can be removed from CIF3O2 by fractional condensation in a —112°C trap. The remaining FClOg, however, has to be removed by complexing with BFg ... 

Synonym(s) Alcide Anthium dioxcide Chlorine(IV) oxide Chlorine Oxide Chlorine Peroxide Chloroperoxide Chloriperoxyl Chloryl Radical Dioxide de cloro [Spanish] Dioxide de chlore [French] Caswell No. 179A Doxcide 50 Chlorous acid, sodium salt Textone... 

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