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Chemical coupling with

With knowledge of how to manipulate and transform chemicals, coupled with the basic hazard data that can be accessed readily from a variety of sources, chemists have the power to reduce or eliminate the risk posed to themselves and society in general by the chemical enterprise (Anastas and Warner, 1998). Specifically in the areas of solvent use, this text will provide leading articles and examples of its practice. Researchers at the vanguard of innovation in this new area know that these goals can be accomplished. [Pg.15]

In the final step chemical coupling with EDCI and DMAP was used to introduce pure EPA into the sn-2 position of adducts (S)-15a-15h to afford the asymmetrically structured MLM type TAG final products (S)-16a-16h in high to excellent yields (78-92%) after purification using silica gel chromatography. This can be noticed from Table 24.4 also showing the specific rotation for each product. The reaction was conducted in dichloromethane at room temperature for 12-15 hours. Stoichiometric amount of EPA was used, 20% molar excess of EDCI and 0.4 equivalents of DMAP. As previously observed, no acyl migration took place during this reaction. [Pg.443]

Another important problem that has received a great deal of attention is the fixation between the implants, for example made of the apatite, and the surrounding tissues. Haque et al.142 studied synthetic HAp as a nano-biocomposite by chemical coupling with a polymer matrix. Similar investigations were presented by Jena et al. In the cited work, the problem of different microstructures of HAp... [Pg.80]

The use of pesticides in Kenya dates back to the colonial era. The major areas of application include agricultural pest control and the public health control of mosquitoes, snails, and tsetse flies. However, with the rapid development of resistance of pests to the chemicals, coupled with environmental persistence, most of the organochlorines have been banned for agricultural use and restricted in the case of public health vector control. Nevertheless, there are detectable residue levels of these compoimds in amounts that lead to concern for food chain magnification. These levels arise either fi om previous application or unscrupulous use through illegal means. [Pg.124]

A prevalent problem is interpretation of the interaction occurring in the calorimeter as physical or chemical. Coupled with this problem... [Pg.90]

It seems likely that the use of penit lin-amidase supported on cellulose by chemical coupling with triazines will soon be employed commercially to convert penicillin to other forms. The use of amylo-glucosidase supported on a cellulosic support also appears to be a good possibility for the near future. [Pg.91]

A typical comonomer could be a polydimethylsilane to increase the toughness of the polymerized film, or an amine functional silane for chemical coupling with an epoxy adhesive. [Pg.445]

Periodate activation. Partial periodate oxidation of dextran leads to the formation of aldehydes that are suitable for chemical coupling with the drug of interest. The concentration of aldehyde functions in oxidized dextran (D-CHO) was determined from the iodine numberThe results obtained for varying amounts of periodate are summarized in table 2. [Pg.309]


See other pages where Chemical coupling with is mentioned: [Pg.312]    [Pg.98]    [Pg.137]    [Pg.144]    [Pg.292]    [Pg.292]    [Pg.295]    [Pg.299]    [Pg.306]    [Pg.308]    [Pg.15]    [Pg.222]    [Pg.164]    [Pg.79]    [Pg.447]    [Pg.205]    [Pg.15]    [Pg.312]    [Pg.33]    [Pg.137]    [Pg.144]    [Pg.706]    [Pg.300]    [Pg.214]    [Pg.119]   


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