Cesium optical spectra

In this paper, we address two aspects of this general problem. First, we discuss the problem of frequency standards in the optical spectrum. (An analogue in the microwave region of the spectrum is the cesium beam frequency standard.) If one or a few of these reference frequencies can be accurately calibrated (perhaps by a frequency synthesis chain- -) then it may be possible to compare optical spectra to these standards. As an example of the precision that might be achieved, we discuss only optical standards based on stored ions. Second, we discuss the problem of frequency comparison of unknown frequencies to the standards. Here we primarily restrict discussion to generation of wideband frequency "combs". 

The example of absorption data presented in Fig. 3.8 shows the spectrum obtained at the relatively low temperature of 420 °C. The atomic density here is 4 x 10 cm . Under these conditions the dominant stable species in cesium vapor is the neutral atom—the molar fraction of dimers is only about 2%. The optical spectrum contains a series of fundamental absorption lines due to the dipole-allowed electronic transitions " 1/2 the quadrupole allowed 6 Si/2... 

Many elements are present in the earth s crust in such minute amounts that they could never have been discovered by ordinary methods of mineral analysis. In 1859, however, Kirchhoff and Bunsen invented the spectroscope, an optical instrument consisting of a collimator, or metal tube fitted at one end with a lens and closed at the other except for a slit, at the focus of the lens, to admit light from the incandescent substance to be examined, a turntable containing a prism mounted to receive and separate the parallel rays from the lens and a telescope to observe the spectrum produced by the prism. With this instrument they soon discovered two new metals, cesium and rubidium, which they classified with sodium and potassium, which had been previously discovered by Davy, and lithium, which was added to the list of elements by Arfwedson. The spectroscopic discovery of thallium by Sir William Crookes and its prompt confirmation by C.-A. Lamy soon followed. In 1863 F. Reich and H. T. Richter of the Freiberg School of Mines discovered a very rare element in zmc blende, and named it indium because of its brilliant line in the indigo region of the spectrum. 

Rubidium was discovered in 1861 by Bunsen and Kirchoff by means of an optical spectroscope. It was named for the prominent red lines in its spectrum, from the Latin word rubidus, meaning darkest red. Bunsen prepared free rubidium during the same year by an electrolytic method. After cesium, rubidium is the second most electropositive and alkaline element. The two isotopes of natural rubidium are 85Rb [13982-12-1] (72.15%) and 87Rb [13982-13-3] (27.85%). The latter is a beta-emitter having a half-life of 4.9 x 1010 yr. Twenty-four isotopes of rubidium are known. 

The existence of these different practices was not sufficient to create a discipline or subdiscipline of physical chemistry, but it showed the way. One definition of physical chemistry is that it is the application of the techniques and theories of physics to the study of chemical reactions, and the study of the interrelations of chemical and physical properties. That would mean that Faraday was a physical chemist when engaged in electrolytic researches. Other chemists devised other essentially physical instruments and applied them to chemical subjects. Robert Bunsen (1811—99) is best known today for the gas burner that bears his name, the Bunsen burner, a standard laboratory instrument. He also devised improved electrical batteries that enabled him to isolate new metals and to add to the list of elements. Bunsen and the physicist Gustav Kirchhoff (1824—87) invented a spectroscope to examine the colors of flames (see Chapter 13). They used it in chemical analysis, to detect minute quantities of elements. With it they discovered the metal cesium by the characteristic two blue lines in its spectrum and rubidium by its two red lines. We have seen how Van t Hoff and Le Bel used optical activity, the rotation of the plane of polarized light (detected by using a polarimeter) to identify optical or stereoisomers. Clearly there was a connection between physical and chemical properties. 

Caesium fluoride Cesium fluoride Cesium fluoride (CsF) Cesium monofluoride Dicesium difluoride EINECS 236-487-3 NSC 84270 Tricesium trifluoride. Used in optics, catalysis, specialty glasses. Atomergic Chemetals Cerac Noah Cham. Spectrum Chem. Manufacturing. 

Recently, a new technique has been developed [1323] that allows the direct comparison of widely different reference frequencies and thus considerably simplifies the frequency chain from the cesium clock to optical frequencies by reducing it to a single step. Its basic principle can be understood as follows (Fig. 9.91) The frequency spectrum of a mode-locked continuous laser emitting a regular train of short pulses with repetition rate 1/AT consists of a comb of equally spaced frequency components (the modes of the laser resonator). The spectral width Aw = 2jt/T of this comb spectrum depends on the temporal width T/Ar of the laser pulses (Fourier theorem). Using femtosecond pulses from a Tusapphire Kerr lens mode-locked laser, the comb spectrum extends over more than 30 THz. 

Another experimental proof of the localization of cold atoms at the minima of a periodic optical potential was obtained by recording the resonance fluorescence spectra of cesium atoms trapped in three-dimensional optical molasses (Westbrook et al. 1990) and rubidium atoms in a one-dimensional optical potential (Jessen et al. 1992) The resonance fluorescence spectrum of a motionless two-level atom consists of the well-known Mollow triplet, which includes a central peak at the laser frequency u> and two side components displaced to the red and blue sides by an amount equal to the Rabi frequency (Mollow 1969). For a two-level atom oscillating in a potential well at a frequency lower than the Rabi frequency, each component of the Mollow triplet is split into side components corresponding to changes in the vibrational state of the atom. If the ratio between the oscillation amplitude of the atom in the potential well and the radiation wavelength (the Lamb-Dicke factor) is small, each component of the... 

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