Cedryl acetate

Acetylation of the alcohol mixture yields cedryl acetate [61789-42-2] (94) and a range of quaUties are available from manufacturers. Gedryl methyl ether [19870-74-7] is readily made and is useful in formulating woody-amber fragrances (188). 

Amyl cinnamic aldehyde Amyl salicylate Anisaldehyde Aurantiol Benzaldehyde Benzyl acetate Benzyl salicylate Brahmanol Cal one Cashmeran Cedramber Cedryl acetate Cinnamic alcohol Citral Citronellal Citronellol Citronellyl acetate Coumarin... 

Otherwise, apart from the greater emphasis on floral notes, the general structure remains very similar to that of Fidji. A different combination of musks is used, including cyclopentadecanolide (4%), and cedryl acetate is incorporated into the woody complex. The woody notes are further emphasized by the use of an intensely powerful amber note—a "captive" material that is not generally available. Although the carnation-salicylate accord is again less than in L Air du Temps, it continues to play an important part in the overall fragrance. 

The mellis accord, which makes up an important part of the fragrance here incorporates amyl salicylate in addition to benzyl salicylate, with the patchouli and woody aspect being accentuated, using cedryl acetate rather than the more traditional products derived from vetiver. Vertofix had yet to be discovered. The dominant spices, in combination with eugenol, are clove and cinnamon. 

Although we have described the perfumes in this family as being based on Hedione, in Coriandre the material used is Magnolione, a closely related material with a very similar though rather more jasminic olfactory character. This makes up some 20% of the formula with 10% of patchouli. Methyl ionone, vetiveryl acetate, cedryl acetate, Vertofix, and sandalwood make up the woody aspect of the fragrance, with a small amount of Galaxolide as the musk. 

The typical chypre base note contains patchouli (6%), methyl ionone (the beta form was used in Aramis), vetiveryl acetate, cedryl acetate, oakmoss, and animalic notes. It is interesting also to find aldehyde Cl 8 being used in a similar way to that of aldehyde C14 in many of the earlier chypres. An important part of the amber character comes from the use of Dynamone, a speciality material derived from cistus, difficult to use, but of great diffusion and persistence. 

The dominant woody aspect of the perfume is made up of Vertofix (12%), vetiver notes, cedryl acetate, and sandalwood, with guaiacwood supporting the rose. The mossy character comes from oakmoss and a complex based on isobutyl quinoline reminiscent of Mousse de Saxe. There is also a small amount of a spicy carnation note including one of the sweet spices such as clove or pimento. The wonderful richness of the perfume suggests the addition of numerous other materials in very small amounts, and it is probable that in the creation of a perfume such as this tinctures of musk, ambergris, and civet would also have been used. 

CijHjfiO, Mr 222.37, mp. 86-87°C, [a]g +10.5° (CHCI3). C. constitutes the actual fragrance substance of cedarwood oil it is often found in cypress oils, sometimes in juniper species (red cedar). C. is the main component in the oil of Juniperus chinensis. To increase the valuable woody, balmy notes, the alcoholic components of cedarwo oil are esterified (e g-, 0-acetyl-C.=cedryl acetate). C. and cedrene-con-taining distillates serve as fixatives for soap perfumes, pine scents, and for perfumes with a woody note in general. 

Acetic acid, cedrol ester. See Cedryl acetate Acetic acid, cellulose ester. See Cellulose acetate... 

CEDEPAL FS-406. See Sodium deceth sulfate CEDEPAL SD-409. See DEA-laureth sulfate CEDEPAL SS-203, -306, -403, -406. See Sodium laureth sulfate CEDEPAL TD-403 MF, CEDEPAL TD-403, CEDEPAL TD-403MF-LD, CEDEPAL TD-403MK-LD, CEDEPAL TD-407, CEDEPAL TDS 484. See Sodium trideceth sulfate CEDEPHOS FA600. See Deceth-4 phosphate Cedepon LA-30. See Ammonium lauryl sulfate Cedepon LT-40. See TEA-lauryl sulfate Cedramber. See Cedrol methyl ether 8-p-H-Cedran-8-ol, acetate Cedranyl acetate Cedran-8-yl acetate. See Cedryl acetate Cedrene... 

Cedrol acetate. See Cedryl acetate Cedrol methyl ether... 

H-3A,7-Methanoazulen-6-ol, octahydro-3,6,8,8-tetramethyl-, acetate. See Cedryl acetate 4H-3A,7-Methanoazulen-4-one, 1,2,3,7,8,8A-hexahydro-3,6,8,8-tetramethyl-, (3R-(3a,3AP,7p,8Aa))-. See Cedrenone Methanoic acid. See Formic acid Methanoic acid, amide. See Formamide... 

R-(3a,3ap,6p,7p,8aa))-Octahydro-6-methoxy-3,6,8,8-tetramethyl-1H-3a,7-methanoazulene. See Cedrol methyl ether Octahydro-3,6,8,8-tetramethyl-1H-3A-methanoazulene-6-yl acetate. See Cedryl acetate... 

Cedrenone Cedrenyl acetate Cedrol Cedrol methyl ether Cedryl acetate Cedryl formate Cetonal Chrysanthal 1,4-Cineole Cinnamaldehyde dimethyl acetal Cinnamon (Cinnamomum zeylanicum) leaf oil trans-Cinnamonitrile Cinnamyl butyrate Cinnamyl isobutyrate Cinnamyl tiglate C9-12 isoparaffin C11-16 isoparaffin Citral Citral dimethyl acetal Citral ethyleneglycol cyclic acetal... 

Cassie (Acacia farnesiana) flowers Cedarwood oil Cedryl acetate Cinnamal Cinnamonitrile trans-Cinnamonitrile Cinnamyl alcohol Cinnamyl anthranilate Citral Citronella (Cymbopogon nardus) oil... 

Cedrol 201-036-1 Cedryl acetate 201-039-8 ADK STAB BT-11 ADK STAB BT-18 ADK STAB BT-23 ADK STAB BT-25 ADK STAB BT-27 Cata-Chek 820 Dabco T-12 Dabco T-12CL Dibutyltin dilaurate Fomrez SUL-4 Jeffcat T-12 Kosmos 19 Metacure T-12 Synpron 1009 TEDA-T411 201-042-4... 

Caryophyllene alcohol acetate Cedryl acetate Famesyl acetate Guaiol acetate Nonoxynol-1 Ci7H OsS Na Sodium nonoxynol-1 sulfate C17H28O8S4... 

Matsui, H., Y. Minamlno, and M. Miyazawa, 1999. Biotransformation of (+) cedryl acetate by Glomerella cingulata, parasitic fungus. Proceedings of 43rd TEAC, 215 216. 

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