Carbon monoxide gas sensor

H. OKAMOTO, H. OBAYASHI, T. KUDO, Carbon monoxide gas sensor made of stabilized zirconia , Soft/State/onzcs, l,p. 319-326,1980. 

Sierra Monitor Corporation offers the 4501-04, 2-Wire Carbon Monoxide Gas Sensor Module. Two-wire, loop-powered gas detectors provide the user with lower cost and easier installation and maintenance. This eliminates the need for separate power runs and associated power distribution and circuit protection for each device. Sierra Monitor Corp., www.sierramonitor.com, (800) 727-4377. Circle 270... 

Hosoya A, Tamura S, Imanaka N (2013) Low-temperature-operative carbon monoxide gas sensor with novel CO oxidizing catalyst. Chem Lett 42 441 143... 

Kotzeva, V.P. and Kumar, R.V. (1999) The response of yttria stabilized zirconia oxygen sensors to carbon monoxide gas. Ionics, 5 (3-4), 220-6. 

We have successfully developed low temperature sensors for the monitoring of carbon monoxide gas in a hydrogen stream. The sensors can detect parts per million concentrations of carbon monoxide in either a pure hydrogen or a hydrogen/carbon-dioxide... 

Afterburn Control. Afterburn is the term for carbon monoxide burning downstream of the regenerator this causes an increase in temperature upstream of the expander. Temperature sensors in the gas stream cause the brake to energize. This provides sufficient resisting torque to prevent acceleration until the afterburn is brought under control by water or steam injection. 

Applicability of Semiconductor Gas Sensors Research into the applications of this type of sensor has mainly been concerned with measuring carbon monoxide concentration in flue gases. Tests show that sensors follow the concentration of carbon monoxide in the flue gas. Improvement in sensor performance has resulted with the introduction of a catalytic additive (palladium or... 

Other usefiil gas sensors include the potentiometric ammonia (64) or hydrogen cyanide probes (65), and amperometric carbon monoxide (66) and nitrogen dioxide (67) devices. The hydrogen cyanide probe is an example of a modem device that relies on changes in the conductivity of electropolymerized film (polyanihne) in the presence of a given gas. 

Up to now, sensors using this parameter have not been taken into consideration, as they are generally not selective. Water for instance is traceable in air because its velocity of sound is significantly higher. The VOS of carbon dioxide is just around 1/3 the VOS of air. In a mixture of air, water and C02 none of the compounds can be quantified. As the VOS of carbon monoxide is similar to that of air, CO cannot be quantifiedby this method either. Hence, sensors based on acoustic principles cannot be taken into consideration neither for the measurement of single species in a flue gas flow nor for the identification of fuel gases. 

Tab. 5.9 Gas sensors and sensor system for detection of carbon monoxide.

Small, portable sensors are now available to monitor the air we breathe for such toxins as carbon monoxide, CO. As soon as the air contains more than a critical concentration of CO, the sensor alerts the householder, who then opens a window or identifies the source of the gas. 

The model analytes, which were used to show the sensor performance of the microsystems include carbon monoxide, CO, and methane, CH4. The sensor microsystems were designed for practical applications, such as environmental monitoring, industrial safety applications or household surveillance, which implies that oxygen and water vapors are present under normal operating conditions. In the following, a brief overview of the relevant gas sensor mechanisms focused on nano crystalline tin-oxide thick-film layers will be given. 

The model sensitive layer, which will be used for gas sensor performance tests throughout this book, was Sn02 that has been doped with 0.2 wt % Pd. The minute Pd-content leads to a better sensitivity to carbon monoxide. The larger response is a consequence of the increased reaction rate. For the sensor arrays in Chap. 6, two additional materials have been prepared. Pure tin oxide shows a good sensor response... 

Recent emission control system development in the automotive industry has been directed mainly towards the use of three-way or dual bed catalytic converters, This type of converter system not only oxidizes the hydrocarbons (HC) and carbon monoxide (CO) in the exhaust gas but will also reduce the nitrous oxides (NO ). An integral part of this type of system is the exhaust oxygen sensor which is used to provide feedback for closed loop control of the air-fuel ratio. This is necessary since this type of catalytic converter system operates efficiently only when the composition of the exhaust gas is very near the stoichiometric point. 

By responding to fumes in cooking areas, car parks, laboratories and similar places, gas sensors can be used to control ventilation fans. In industrial situations the sensor can monitor concentrations of carbon monoxide, ammonia, solvent vapours, hydrocarbon gases, ozone etc., and because of the growing consciousness of environmental pollution and the safety aspects of industrial processes the applications will multiply. 

Zirconia sensors have been used primarily in the exhaust system of automobiles to control the air-to-fuel ratio for meeting the federal requirements on such noxious gases as carbon monoxide, methane and nitrogen oxides. The applicability of zirconia sensors for this particular application is based on the assumption that, under thermodynamic equilibrium, the partial pressure of oxygen in the exhaust gas depends primarily on the air-to-fuel ratio. To compensate for the fact that in reality equilibrium is not reached, catalytic platinum electrics are incorporated in the zirconia sensor design [Stevens, 1986]. In the zirconia sensor, the outside of the zirconia tube is exposed to the exhaust gas while the inside is exposed to the ambient air as a reference atmosphere. 

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