Carbon disulphide monoxide

Caprylic acid, see Octanoic acid Caprylic alcohol, see 1-Octanol Carbitol, see Diethylene glycol monoethyl ether Carbolic acid, see Phenol Carbon disulphide Carbon monoxide Carbon oxysulphide, see Carbonyl sulphide... 

Butyl ether Butyl carbitol /i-Butyl glycidyl ether Butyl mercaptan p-tert-Butyltoluene Carbon disulphide Carbon dioxide Carbon monoxide Carbon tetrachloride Carbonyl sulphide Carbary ... 

Carbon black Carbon dioxide Carbon disulphide Carbon monoxide Carbon tetrachloride Carbonyl chloride (phosgene)... 

Carbon disulphide burns in nitrogen monoxide and this combustion can be explosive. With dinitrogen tetroxide the mixture is supposed to be stable up to 200°C but a shockwave or a spark can cause the mixture to detonate. 

Carbon dioxide, 184, 358, 359 solid see Dry Ice Carbon disulphide, 767 purification of, 175 Carbon monoxide, 185, 1003, 1004 Carbon, decolourising, 127, 128 Carbon tetrachloride, 733, 815 drying of, 734 purification of, 176 Carbonyl chloride, 185 Carborundum chips, 4 Carboxylic acids, equivalent weights of, 1071 ... 

Thionyl chloride is also formed by the oxidation with chlorine monoxide of sulphur in carbon disulphide or even of carbon disulphide itself,6 and in the interaction of carbonyl chloride with sulphur dioxide at temperatures above 200° C.,... 

When sulphur dioxide alone is passed over carbon at a red heat the latter undergoes partial oxidation, the products being carbon monoxide, carbon oxysulphide and carbon disulphide no oxysulphide is obtained at a white heat.2 Both carbon monoxide and methane are oxidised by sulphur dioxide at high temperatures with formation of sulphur. It has been suggested that volcanic sulphur may, in part, be formed by the reduction of sulphur dioxide by methane, carbon monoxide and hydrogen, all of which are emitted by volcanoes.4... 

Carbon Monosulphide, CS.—This sulphur analogue of carbon monoxide is described as resulting8 on passing carbon disulphide vapour over spongy platinum, pumice stone or red-hot charcoal. It is also formed by the action of the silent electric discharge 7 on carbon disulphide or on a mixture of the latter with either hydrogen or carbon monoxide, thus ... 

At 800° C. reaction (2) appears to proceed slowly in either direction, while (1) is very rapid. The fact that the degree of dissociation in (1) is. independent of the amounts of carbon dioxide and carbon disulphide present, shows that carbon monoxide and sulphur are primary products of the decomposition of carbonyl sulphide and are not formed secondarily from the carbon dioxide and carbon disulphide. At temperatures below 400° C. decomposition according to equation (1) is not evident, while at 900° C. it reaches a maximum (64 per cent.) reaction (2) reaches a maximum at about 600° C., at which point 43 per cent, of the carbonyl sulphide is decomposed in this way and 16 per cent, according to reaction (1). The carbon monoxide equilibrium depends upon the pressure, whilst the carbon dioxide equilibrium does not. Nearly all the reactions involved in the thermal decomposition of carbonyl sulphide depend greatly on catalytic influences. Quartz is a pronounced catalyst for reaction (2), but has little influence on reaction (1). Carbonyl sulphide is comparatively rapidly decomposed in quartz vessels, but is stable when kept in glass apparatus. The viscosity of gaseous carbonyl sulphide is as follows x... 

Moist yellow phosphorus in an atm. of carbon dioxide was found by A. R. Leeds10 to produce some phosphine, but not to react with the carbon dioxide and G. Gore showed that a sat. soln. of phosphorus in carbon disulphide has no action on carbon dioxide. J. Davy found that when in contact with yellow phosphorus, carbon monoxide and dioxide become charged with the vapour of that element but A. F. de Fourcroy and L. N. Vauquelin thought that this was not the case with carbon dioxide. G. Gore showed that a mixture of ammonium carbonate and red phosphorus in a red-hot crucible forms phosphorus pentoxide, J. Davy found that phosphorus does not react with carbonyl Chloride even at the sublimation temp, of that element. 

Carbohydrates, published infra-red spectra, 250 Carbolic acid, 884 Carboline, 824 Carbolith, 708 Carbon disulphide, 567 Carbon Disulphide (test), 131 Carbon monoxide, quantification in blood, 20 reference standards, 1171 test on blood, 6 Carbon tetrachloride, 434 Carboneum tetrachloratum medicinale, 434 Carbop B, 178 CarbopakC, 178 Carbostesin, 411 Carbotiroid, 432 Carbowax20M, 179, 180... 

In this contribution the concept of instantaneous normal modes is applied to three molecular liquid systems, carbon monoxide at 80 K and carbon disulphide at ambient temperature and two different densities. The systems were chosen in this way because pairs of them show similarities either in structural or in dynamical properties. The systems and their simulation are described in the following section. Subsequently two different types of molecular coordinates are used cis input to normal mode calculations, external, i.e. translational and rotational coordinates, and internal, i.e. vibrational coordinates of strongly infrared active modes, respectively. The normal mode spectra are related quantitatively to molecular properties and to those of liquid structure and dynamics. Finally a synthesis of both calculations is attempted on qualitative grounds aiming at the treatment of vibrational dephcising effects. 

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