4-tert-butyltoluene

Trinitro-3-tert-butyltoluene, m.p. 97°C, yellow crystals. Used in perfumery and known as musk hour. 

The reaction of N bromosuccimmide with the following com pounds has been reported in the chemical literature Each compound yields a single product in 95% yield Identify the product formed from each starting material (a) p-tert Butyltoluene (b) 4 Methyl 3 nitroanisole... 

When two positions are comparably activated by alkyl groups substitution usually occurs at the less hindered site Nitration of p tert butyltoluene takes place at positions ortho to the methyl group m preference to those ortho to the larger tert butyl group This IS an example of a stenc effect... 

Butyl ether Butyl carbitol /i-Butyl glycidyl ether Butyl mercaptan p-tert-Butyltoluene Carbon disulphide Carbon dioxide Carbon monoxide Carbon tetrachloride Carbonyl sulphide Carbary ... 

Butyl cellosolve (2-butoxy ethanol) n-Butyl glycidyl ether n-Butyl mercaptan n-Butylamine p-tert-Butyltoluene... 

Butyl cellosolve, see 2-Butoxyethanol tert-Butyl chromate (as CrOj) n-Butyl glycidyl ether n-Butyl lactate Butyl mercaptan p-tert-Butyltoluene Cadmium, dust and salts (as Cd) Cadmium, fume (as Cd)... 

Ring-substituted benzyl alcohols sometimes undergo such reduction more effectively than unsubstituted alcohols. For example, treatment of a dichloromethane solution of 2,4,6-trimethylbenzyl alcohol with trifluoroacetic acid and triphenylsilane produces a 41% isolated (89% by GLC) yield of isodurene.26 Treatment of 2-me(hyl-4,6-di-/m-buty I benzyl alcohol with a three-fold excess of triethylsilane and trifluoroacetic acid in dichloromethane at room temperature gives an 85% yield of 2-mclhyl-4,6-di-/m-butyltoluene together with 15% of 3,5-di-ferf-butyltoluene. The latter is presumably formed by loss of protonated formaldehyde from the Cl ring-protonated substrate.128 Similar treatment of 2,4,6-tri-ferf-butylbenzyl alcohol produces a 90% yield of 2,4,6-tri-tert-butyltoluene within one hour (Eq. 21).128... 

SAMPLE SOLUTION (a) The only benzylic hydrogens in p-tert-butyltoluene are those of the methyl group that is attached directly to the ring. Substitution occurs there to give p-tert-butylbenzyl bromide. 

Refs 3 Sc 6) 2,4,6- Trinitro-3-(iso-butyl)-toluene, crysts(from dil ale), having an odor resembling that of musk, mp 124° was prepd by nitrating m-iso butyltoluene(Refs l 5) and2,4,6-Trinitro 3-(tert-butylytoluene, It yel ndls(from ale), having an odor of musk, mp 96-7° readily sol in ale, eth, chlf, benz Sc petr eth insol in w was prepd by nitrating m-tert-butyltoluene(Refs 2,4,6 7). 

Toluene p-tert-Butyltoluene 4-rert-Butyl- 2-nitrotoluene... 

Since the extreme oxidizing power of the oxyl spin centers is successfully employed in waste water treatment, an application of these intermediates seems to be self-contradictory in terms of synthetic use. However, alkoxylation of hydrocarbons is a very important technical field since it allows the installation of functionalities without using the detour via halogenations. The selective introduction of functional groups on a completely nonactivated hydrocarbon has not yet been realized by BDD technology. In contrast, the direct anodic methoxylations of activated carbons exhibiting benzylic or allylic moieties can be performed at BDD anodes. The results obtained with BDD electrodes are quite similar to those when graphite serves as anode [57]. The anodic synthesis of benzaldehyde dimethyl ketals is industrially relevant and performed on the scale of several thousand tons. A detailed study of the anodic methoxylation of 4-tert-butyltoluene (10) at BDD was performed [58]. Usually, the first methoxylation product 11 and the twofold functionalized derivative 12 are found upon electrochemical treatment (Scheme 5). 

Zollinger D, Griesbach U, Putter H, Comninellis C (2004) Methoxylation of p-tert-butyltoluene on boron-doped diamond electrodes. Electrochem Commun 6 600-604... 

By contrast, oxidations catalyzed by Co(OAc)2-HC1 were much less selective, and tert-butyltoluene, for example, gave considerable amounts of products resulting from C—C bond cleavage ... 

---