Capillary Drilling

Electrostatics, effect on weighing, 26 243 Electrostatic self-assembly (ESA), of thin-films, 1 724-725 Electrostatic separators, 16 642 Electrostatic separation, 16 642-644 Electrostatic spray coating, 7 56-58, 74-75 Electrostatic stabilization, 10 119-121 of latex, 14 708-709 Electrosteric stabilization, 10 122 Electrostream (capillary drilling), 9 600 Electrostrictive coefficient tensor, 11 93 Electrostrictive devices, applications of, 11 103-104... 

The direct insertion probe consists of a metal sample holder drilled to accept standard melting point capillaries up to 1 inch in length. This is inserted into the ion source through a vacuum lock and may be heated to 250°C at varying rates. 

Shale stability is an important problem faced during drilling. Stability problems are attributed most often to the swelling of shales. It has been shown that several mechanisms can be involved [680,681]. These can be pore pressure diffusion, plasticity, anisotropy, capillary effects, osmosis, and physicochemical alterations. Three processes contributing to the instability of shales have to be considered [127] ... 

Initially devised to measure interactions in single soap films (air/water/air) [8], the TFB technique has been progressively improved and its application has been broadened to emulsion films (oil/water/oil) [ 12] and asymmetric films (air/water/oil or air/water/solid) [13,14]. In a classical setup, a thin porous glass disk is fused on the side to a capillary tube and a small hole is drilled in the center of the disk. The liquid solution fills the disk, part of the capillary, and a thin horizontal film is formed across the hole. The disk is enclosed in a hermetically sealed box, with the capillary tube exposed to a constant reference pressure Pr. Under the effect of the pressure difference AP between the box and the reference, the... 

Productive wells in vapour-dominated systems discharge steam only. Characteristically, wells in liquid-dominated systems discharge a mixture of water and steam. The steam forms essentially by depressurization boiling of the reservoir water. It is, however, not uncommon that some wells drilled into liquid-dominated systems discharge dry steam or possess a higher steam to water ratio than can be accounted for by depressurization boiling. The reason for this is partial or complete immobilization of the water in the aquifer due to the effects of capillary pressure and relative permeability. 

The solute is solubilized in supercritical fluid at high pressure in an autoclave, and later the solution is decompressed through the nozzle. One key component of the apparatus is the nozzle, of which two types are used - a capillary of suitable diameter (< 100 qm) or laser-drilled nozzles of 20-60 qm diameter. 

A commonly employed method to minimise ohmic potential drop effects is to place the reference electrode very close to the working electrode by means of a Luggin capillary. The disadvantage of very close placement, which may be unacceptable, is disturbance of the fluid flow. To avoid this, other methods are sometimes used. For example, a rotating disc electrode has been described in which the reference electrode is placed in a tiny compartment within the rotating electrode assembly and linked to the solution via a tiny orifice (0.7 mm) drilled in the centre of the disc [88]. 

The interaction between the two gas-liquid interfaces across a foam film can directly be measured by a thin-film balance (TFB) [571-573], A single thin foam film is formed in a hole drilled through a porous glass plate (Fig. 12.19). The plate, and therefore the liquid in the foam, is connected to a reservoir with a constant reference pressure Pr by a capillary tube. The film holder is placed into a closed cell. A constant pressure Pg is applied to the gas in the... 

The innovative thermostated separation system published by de Bokx et al. [17] represents an interesting example and comprises a capillary cross intersection for sample injection and a 100 pi fluorescence detector cell based on fiber optics. This apparatus shows basically all features that are required to perform automated fast and efficient electrophoretic separations and has been used to separate a mixture of laser dyes in 35 seconds with moderate efficiency. However, in order to keep all dead volumes at the junctions sufficiently small, the connections had to be done by tedious laser-based drilling of holes through the capillary walls. A similar approach to interconnect capillaries was described for a postcolumn derivatization reactor for CE [18], and many more inventive capillary coupling devices have been designed. 

The detector consisted of a Wheatstone network of capillary tubes that were drilled out of a high conductivity copper block and was fairly compact. The reference flow of mobile phase and the eluent from the column entered at two opposing junctions of the bridge arms (the center of tube (C)) such that the eluent was contained in one vertical arm (C) and the pure mobile phase in a parallel vertical arms (A) and (B). The increase in pressure at the base of tube (C) due to the presence of solute in (C) applied a pressure to the bottom of tube (A). This caused a flow of gas through the anemometer from tube (A) to tube (B) providing an output that was fed to a recording milliammeter. Subsequently all flows exited from the top and bottom of tube (C). 

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