Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Bond order four

For interactions of known bond order, the quantities Ad for a stretch to lower order follow directly from Table 1, provided it occurs in a region of uniform slope. Energy differences are in general proportional to AZ) = r" — r + = = T+. As bond order is not an absolute measure, only relative slopes can be stipulated. Also, whereas d may change continuously, bond order changes in discrete steps, determined by the interference of standing waves. We therefore assume that equation (5) correctly describes a hypothetical linear response for a stretch from bond order four d = 0.6) to zero, with a slope of 0.1 measured in Fig. 3. For any intermediate stretch of different slope ct, a multiplicative scale factor that represents an effective slope of j = ct/0.1 is added to Eq. (5). [Pg.105]

Abstract A molecular orbital analysis of model unbridged complexes with Cr-Cr formal bond orders four and five is presented, based on density functional calculations. The orbital and symmetry analysis discloses a special type of 8 bmiding in the case of the [Ct2L4] complexes that induces a significant bond shortening going from quadruple Cr°-Cr to quintuple Cr -Cr bonds. [Pg.249]

The natural bond length varies between 1.503 A and 1.337 A for bond orders between 0 and 1, these are the values for pure single and double bonds between two sp -carbons. Similarly the force constant varies between the values used for isolated single and double bonds. The rotational barrier for an isolated double bond is 60kcal/mol, since there are four torsional contributions for a double bond. [Pg.28]

In the H2 molecule, there are two Is electrons. They fill the crls orbital giving a single bond. In the He2 molecule, there would be four electrons, two from each atom. These would fill the bonding and antibonding orbitals. As a result, the number of bonds (the bond order) in He2 is zero. The general relation is... [Pg.651]

Metal-metal bonds of order four. J. L. Templeton, Prog. Inorg. Chem., 1979, 26, 211-300 (255). [Pg.31]

It can be seen that the two bonds whose bond order is 1 are unchanged in the two products, but for the other four bonds there is a change. If the 1,4-diene is formed, the change is 5 + 5 + 5 -l- 5, while formation of the 1,3-diene requires a change of j + j + l + Since a greater change is required to form the 1,3-diene, the principle of least motion predicts formation of the 1,4-diene. This may not be the only factor, because the NMR spectrum of 46 shows that the 6 position has a somewhat greater electron density than the 2 position, which presumably would make the former more attractive to a proton. [Pg.1011]

In order to calculate the orbitals for a methane molecule, the four Lv functions of the four hydrogen atoms and the functions 2s, 2px, 2py and 2pz of the carbon atom are combined to give eight wave functions, four of which are bonding and four of which are antibonding. The four bonding wave functions are ... [Pg.87]

Thus there are five bonding electrons giving a bond order of 2.5, consistent with the bond length of 115 pm, versus 121 pm for the four-electron bond in O2 and 110 pm for the six-electron bond in N2. For these and other related molecules, the double-quartet model is a convenient and useful alternative to the conventional molecular orbital model. Moreover, it shows that for a singly bonded terminal atom such as F or Cl there is a ring of six nonbonding electrons rather than three separate lone pairs. As we will see in Chapters 7 and 8, this conclusion is confirmed by the analysis of electron density distributions. [Pg.103]

In order to complete its octet, each carbon atom must share a total of four electron pairs. The order of a bond is the number of electron pairs shared in that bond. The total number of shared pairs is called the total bond order of an atom. Thus, carbon must have a total bond order of four (except in CO). A single bond is a sharing of one pair a double bond, two and a triple bond, three. Therefore, in organic compounds, each carbon atom forms either four single bonds, a double bond and two single bonds, a triple bond and a single bond, or two double bonds. As shown in the table below, each of these possibilities corresponds to a total bond order of 4. [Pg.317]

The effect of probe molecules on the 27A1 NMR has attracted some attention recently. In particular, the determination of the quadrupole coupling constant, Cq, is a sensitive means to learn more about the bonding situation at the aluminum in acid sites, and how it reflects the interaction with basic probe molecules. If one of the four oxygen atoms in an AIO4 tetrahedral coordination is protonated, as in a zeolitic acid site, the coordination is somewhat in between a trigonal and a tetrahedral A1 environment [232]. The protonated oxygen decreases its bond order to A1 to approximately half of its size compared to an unprotonated zeolite. [Pg.213]

Through an interaction of the two singly occupied ji orbitals, a transannular six-center four-electron 71 -ji bond with a formal bond order of 0.67 results... [Pg.390]


See other pages where Bond order four is mentioned: [Pg.44]    [Pg.44]    [Pg.1759]    [Pg.143]    [Pg.251]    [Pg.62]    [Pg.59]    [Pg.1000]    [Pg.248]    [Pg.67]    [Pg.73]    [Pg.75]    [Pg.49]    [Pg.264]    [Pg.304]    [Pg.694]    [Pg.107]    [Pg.136]    [Pg.34]    [Pg.169]    [Pg.74]    [Pg.207]    [Pg.179]    [Pg.179]    [Pg.76]    [Pg.512]    [Pg.199]    [Pg.105]    [Pg.112]    [Pg.205]    [Pg.210]    [Pg.225]    [Pg.260]    [Pg.408]    [Pg.444]    [Pg.479]    [Pg.505]    [Pg.252]    [Pg.168]   
See also in sourсe #XX -- [ Pg.44 ]




SEARCH



Bond Ordering

Bond order

Bond/bonding orders

© 2024 chempedia.info