Blown Oxidation

Chem. Descrip. Blown/oxidized tall oil Chem. Analysis 0.4% max. moisture... 

The process of extraction requires first smelting (to obtain the crude metal) and then refining. In smelting, iron ore (usually an oxide) is mixed with coke and limestone and heated, and hot air (often enriched with oxygen) is blown in from beneath (in a blast furnace). At the lower, hotter part of the furnace, carbon monoxide is produced and this is the essential reducing agent. The reduction reactions occurring may be represented for simplicity as ... 

In the fumace/ketde batch process, a charge of drossed blast furnace buUion is treated in a reverberatory furnace or a kettie (see Fig. 12). Oxygen is supphed in the form of compressed air or as lead oxide blown into the bath through submerged pipes. The formation of lead oxide serves by mass action to assure the removal of the impurities to the desired low concentrations. The softening reactions are... 

The continuous softening process used by The Broken Hill Associated Smelters Pty., Ltd. is particularly suitable for lead buUion of fairly uniform impurity content. The copper-drossed blast furnace buUion continuously flows in the feed end of a reverberatory furnace at 420°C, and the softened lead leaves the opposite end at 750°C. Oxidation and agitation is provided by compressed air blown through pipes extending down through the arch of the furnace into the bath. 

Uses. The sinter oxide form is used as charge nickel in the manufacture of alloy steels and stainless steels (see Steel). The oxide furnishes oxygen to the melt for decarburization and slagging. In 1993, >100, 000 metric tons of nickel contained in sinter oxide was shipped to the world s steel industry. Nickel oxide sinter is charged as a granular material to an electric furnace with steel scrap and ferrochrome the mixture is melted and blown with air to remove carbon as CO2. The melt is slagged, pouted into a ladle, the composition is adjusted, and the melt is cast into appropriate shapes. A modification of the use of sinter oxide is its injection directiy into the molten metal (33). 

Thermoplasticity. High molecular weight poly(ethylene oxide) can be molded, extmded, or calendered by means of conventional thermoplastic processing equipment (13). Films of poly(ethylene oxide) can be produced by the blown-film extmsion process and, in addition to complete water solubiUty, have the typical physical properties shown in Table 3. Films of poly(ethylene oxide) tend to orient under stress, resulting in high strength in the draw direction. The physical properties, melting behavior, and crystallinity of drawn films have been studied by several researchers (14—17). 

Oxidation. Oxidized or blown castor oils are clear viscous oils that are made by the intimate mixing (blowing) of castor oil and air or oxygen at 80—130°C, with or without the use of a catalyst. The reaction is a combination of oxidation and polymerization promoted by transitionary metals like iron, copper, and manganese (60,61). The range of the properties of commercially available oils are given in Table 8. 

In the blast furnace reduction slag-making materials are also added together with a small amount of iron, the function of which is to reduce any sulphide which remains, to the product of the roasting operation to produce a sinter. The sinter is then reduced with coke in a vertical shaft blast furnace in which air is blown tluough tuyeres at the bottom of tire shaft. The temperature in the heartlr where metal is produced must be controlled to avoid the vaporization of any zinc oxide in the sinter. The products of tlris process are normally quite complex, and can be separated into four phases. Typical compositions of these are shown in Table 13.1. 

Asphalt Manufacture Saleable asphalts are produced from the residua of selected crudes. The residuum itself may be sold as straight reduced cuts to make it easier to handle, producing the so called cut-back asphalts. Another variation is air blown or oxidized asphalts for improved tenacity, greater resistance to weathering, and decreased brittleness. Emulsified asphalts are made for application at relatively low temperatures. 

Oxidized solution is delivered from the pumping tank to the top of the absorber tower, where it contacts the gas stream in a counter-current flow. The reduced solution flows from the contactor to the solution flash drum. Hydrocarbon gases that have been dissolved in the solution are flashed and the solution flows to the base of the oxidizer vessel. Air is blown into the oxidizer, and the solution, now re-oxidized, flows to the pumping tank. 

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