Blend composition, effect blends

Unlike most crystalline polymers, PVDF exhibits thermodynamic compatibiUty with other polymers (133). Blends of PVDF and poly(methyl methacrylate) (PMMA) are compatible over a wide range of blend composition (134,135). SoHd-state nmr studies showed that isotactic PMMA is more miscible with PVDF than atactic and syndiotactic PMMA (136). MiscibiUty of PVDF and poly(alkyl acrylates) depends on a specific interaction between PVDF and oxygen within the acrylate and the effect of this interaction is diminished as the hydrocarbon content of the ester is increased (137). Strong dipolar interactions are important to achieve miscibility with poly(vinyhdene fluoride) (138). PVDF blends are the object of many papers and patents specific blends of PVDF and acryflc copolymers have seen large commercial use. 

Figure 3. Effects of blend composition on CTE of graphites manufactured from VWGS 13421 derived products...

The effects of composition distribution on the morphology of PS-fc-P2VP diblock copolymers were investigated by Matsushita et al. [160]. They produced PS- -P2VP samples with various composition distributions but with constant average composition by blending. If the polydispersity indices of each block were lower than 1.7, the expected lamellar domains were detected (Fig. 49). 

A phase diagram of the symmetric PS-fc-PI blended with PS homopolymer of shorter chain lengths was constructed by Bodycomb et al. [ 174]. The effect of blend composition on the ODT is shown in Fig. 56 along with the results of mean-field calculations. In analogy to MFT the addition of homopolymer decreases the ODT temperature for the nearly symmetric diblock copolymer. 

A composite collector blended with a 1 1 ratio of SPA and octanol was found to be an effective collector for flotation of hard rock rutile ores. 

The effect of annealing temperatures (65 - 250 °C) and blend composition of Nafion 117, solution-cast Nafion , poly(vinyl alcohol) (PVA) and Nafion /PVAblend membranes for application to the direct methanol fuel cell is reported in [148], These authors have found that a Nafion /PVAblend membrane at 5 wt% PVA (annealed at 230 °C) show a similar proton conductivity of that found to Nafion 117, but with a three times lower methanol permeability compared to Nafion 117. They also found that for Nafion /PVA (50 wt% PVA) blend membranes, the methanol permeability decreases by approximately one order of magnitude, whilst the proton conductivity remained relatively constant, with increasing annealing temperature. The Nafion /PVA blend membrane at 5 wt% PVA and 230 °C annealing temperature had a similar proton conductivity, but three times lower methanol permeability compared to unannealed Nafion 117 (benchmark in PEM fuel cells). 

Figure 20.7 The effect of pre-heating temperatures and blend composition on the melting temperatures of the PHB/PEN/PET blends , 260°C O, 280 °C A, 300 °C...

Figure 7.5 shows the relative endotherms of PVDF/PMMA blends as a function of PVDF content. A relative endotherm is defined here as the ratio of a melt endotherm at a certain PVDF blend composition to the endotherm of the pure annealed PVDF in DSC measurements. The DSC measurements are at a constant heating rate of lOC/min. For annealed and solution-cast blends, the relative endotherms are in general greater than those of quenched blends of the same composition. Endotherms can be detected at all compositions when the blends are annealed. The quenched PVDF shows only 75% endotherm relative to the annealed PVDF. No endotherm can be detected when the PVDF content is lower than 50 wt % in quenched PVDF/PMMA blends. Obviously the thermal history of the blends has a tremendous effect on the final performance of the material. 

Coleman et al. 2471 reported the spectra of different proportions of poly(vinylidene fluoride) PVDF and atactic poly(methyl methacrylate) PMMA. At a level of 75/25 PVDF/PMMA the blend is incompatible and the spectra of the blend can be synthesized by addition of the spectra of the pure components in the appropriate amounts. On the other hand, a blend composition of 39 61 had an infrared spectrum which could not be approximated by absorbance addition of the two pure spectra. A carbonyl band at 1718cm-1 was observed and indicates a distinct interaction involving the carbonyl groups. The spectra of the PVDF shows that a conformational change has been induced in the compatible blend but only a fraction of the PVDF is involved in the conformational change. Allara M9 250 251) cautioned that some of these spectroscopic effects in polymer blends may arise from dispersion effects in the difference spectra rather than chemical effects. Refractive index differences between the pure component and the blend can alter the band shapes and lead to frequency shifts to lower frequencies and in general the frequency shifts are to lower frequencies. 

For miscible blend phases, these parameters need to be described as a function of the blend composition. In a first approach to describe the behavior of the present PPE/PS and SAN/PMMA phases, these phases will be regarded as ideal, homogeneously mixed blends. It appears reasonable to assume that the heat capacity, the molar mass of the repeat unit, as well as the weight content of carbon dioxide scale linearly with the weight content of the respective blend phase. Moreover, a constant value of the lattice coordination number for PPE/PS and for SAN/PMMA can be anticipated. Thus, the glass transition temperature of the gas-saturated PPE/SAN/SBM blend can be predicted as a function of the blend composition (Fig. 17). Obviously, both the compatibilization by SBM triblock terpolymers and the plasticizing effect of the absorbed carbon dioxide help to reduce the difference in glass transition temperature between PPE and SAN. 

For bulk materials, a co-continuous blend structure is often desirable as it offers synergetic effects [71, 85], For this purpose, numerous investigations on the blend morphology formation were performed, but the precise prediction of the final structure is still rather complex [86-90], Nevertheless, based on numerous investigations concerning the influence of the processing conditions and the blend composition on the morphology development, two key factors can be deduced [43, 87, 91, 92] - the blend composition and the viscosity ratio. 

For the PPE/PS phase, the previously described Chow equation can be combined with the Couchman equation to estimate the Tg as a function of the blend composition. The results are highlighted in Fig. 25. For the prediction, the heat capacity and the molar mass of the repeat unit of the PPE/PS blends is regarded to scale linearly with the mass content of the blend partners, and a constant lattice coordination number of z = 2 is used [75]. While the addition of PS to PPE allows one to reduce continuously the Tg in presence of carbon dioxide, the plasticization effect is less pronounced, mainly driven by the decreasing solubility via addition of PS. 

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