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Polysubstituted benzenes

Most pyridines are thermally and photochemically stable but, just as in benzenes, polysubstitution can lead to susceptibility to such reaction modes. [Pg.245]

For example, ia the iadustriaHy important alkylation of benzene with ethylene to ethylbenzene, polyethylbenzenes are also produced. The overall formation of polysubstituted products is minimized by recycling the higher ethylation products for the ethylation of fresh benzene (14). By adding the calculated equiUbrium amount of polyethylbenzene to the benzene feed, a high conversion of ethylene to monoethylbenzene can be achieved (15) (see also... [Pg.552]

Fluorobenzene is readily alkylated with alkenes in the presence of protic acids, however, the isomenc purity of the product is poor, and polysubstitution can result Thus, propene and sulfuric acid alkylate fluorobenzene at 20 C to yield a 45 55 ortho/para ratio of the inonoalkyl product m addition to di- and triiso propylfluorobenzene [i5] The reaction of benzene and trifluoropropene at 25 °C in HF-BF3 gives a mixture of mono-, bis-, and tns(3,3,3-trifluoropropyl)ben zene [72, 75] (equation 12)... [Pg.412]

Consuming hydrogen is mainly a function of the number of benzene substituents. Dealkylation of polysubstituted benzene increases hydrogen consumption and gas production (methane). For example, dealkylating one mole xylene mixture produces two methane moles and one mole of benzene it consumes two moles of hydrogen. [Pg.82]

Toluene (methylbenzene) is similar to benzene as a mononuclear aromatic, but it is more active due to presence of tbe electron-donating metbyl group. However, toluene is much less useful than benzene because it produces more polysubstituted products. Most of tbe toluene extracted for cbemical use is converted to benzene via dealkylation or disproportionation. Tbe rest is used to produce a limited number of petro-cbemicals. Tbe main reactions related to tbe cbemical use of toluene (other than conversion to benzene) are the oxidation of the methyl substituent and the hydrogenation of the phenyl group. Electrophilic substitution is limited to the nitration of toluene for producing mono-nitrotoluene and dinitrotoluenes. These compounds are important synthetic intermediates. [Pg.284]

Ferrocene behaves in many respects like an aromatic electron-rich organic compound which is activated toward electrophilic reactions.In Friedel-Crafts type acylation of aromatic compounds with acyl halides, ferrocene is lO times more reactive than benzene and gives yields over 80%. However, ferrocene is different from benzene in respect to reactivity and yields in the Friedel-Crafts alkylation with alkyl halides or olefins. The yields of ferrocene alkylation are often very low. and the separations of the polysubstituted byproducts are tedious. [Pg.155]

This reaction set may be regarded as parallel reactions with respect to consumption of species B and as a series reaction with respect to species A, V, and W. Common examples include the nitration and halogenation of benzene and other organic compounds to form polysubstituted compounds. To characterize the qualitative behavior of such systems, it is useful to consider reactions 9.3.3 and 9.3.4 as mechanistic equations and to analyze the effects of different contacting patterns on the yield of species V. We shall follow the treatment of Levenspiel (7). [Pg.330]

The polysubstituted benzenes 291 and 292 were also obtained by protonation of the cyclohexadiene derivatives 287 -289 (equation 101)155. The migration of the propynyl... [Pg.789]

The second structural property described by the 4ypc index is the substitution pattern on the benzene ring. The value of the 4ypc index increases sharply with the degree of substitution, while in the isomeric classes of substituted benzenes it increases with the proximity of substituents. Thus, this structural parameter has also been found to be very useful in describing activities and properties of polysubstituted benzenes [103], chlorinated benzenes [279], and polychlorinated biphenyls [286]. [Pg.263]

More important and more widely applicable criteria of protonation sites are available in the effects of more distant substituents, in particular meta and para in benzene derivatives, which are as a rule purely electronic in origin. Exceptionally, they may be complicated by steric effects (e.g., in polysubstituted derivatives). The most widely useful approach is that of Hammett (1940), who suggested that the effects of substituents on the ionization constants of benzoic acid may be taken as a measure of their effectiveness in other systems involving other reaction centres and in reactions other than acid-base equilibria. He thus defined substituent constants, a, by the equation... [Pg.281]

When desired vinylidene-mediated pathways are not sufficiently favorable. Group 9 metal catalysts can access a set of typical side-reaction pathways. Alkyne dimerization to give conjugated enynes or higher oligomers is often observed. Polysubstituted benzenes resulting from [2 + 2 + 2] alkyne cyclotrimerization are also common coproducts. Fortunately, the selectivity of rhodium and iridium catalysts can often be modulated by the variation of spectator ligands. [Pg.280]

Trichlorophenoxyacetic, 2,4,5 Acid Dioxin and Related Compounds Dioxin and Related Compounds HxCDF Hexachlorodibenzofurans TCDD Tetrachlorodibenzodioxins TCDF Tetrachlorodibenzofurans Disubstituted and Polysubstituted Benzene Hydrocarbons Diethyl Benzene... [Pg.5]

Diethyl Benzene under Disubstituted and Polysubstituted Benzene Hydrocarbons Diethyl Ether under Noncyclic Aliphatic or Aromatic Ethers Dihalogenated and Polyhalogenated Ethers... [Pg.1266]

Disubstituted and Polysubstituted Benzene Hydroearbons Elemental Sulfur... [Pg.1267]

Indene Dihydroindene under Disubstituted and Polysubstituted Benzene Hydrocarbons Indene under Polycyclic Hydrocarbons, Nonaltemant Compounds with Two or Three Fused Rings Indeno(l,2,3-C(i0pyrene under Poiycyciic Hydrocarbons, Nonaltemant Compounds with More Than Five Fused Rings Iodine Iron... [Pg.1268]

Xylenes under Disubstituted and Polysubstituted Benzene Hydrocarbons Zinc... [Pg.1271]

Di- and polyalkylation can occur during alkylation with alkyl halides since the product alkylbenzenes are more reactive, although the reactivity difference with reactive alkylation systems is small. Toluene, for example, reacts only about 2-5 times faster in some benzylations than benzene.118,119 As alkylbenzenes, however, dissolve preferentially in the catalyst containing layer, heterogeneous systems can cause enhanced polysubstitution. The use of appropriate solvents and reaction conditions as well as of an excess of aromatics allow the preparation of monoalkyl-ated products in high yields. [Pg.233]

This effect is generally similar to that observed in polysubstituted benzenes. Thus, groups such as N02 and CN reinforce the electron withdrawal from the substituent which is caused by the heteroatom(s). [Pg.251]

Table 6 lists proton chemical shifts for a selection of monosubstituted furans including some with a metal or other less common heteroatom attached to the ring, but perhaps it should be noted that values are not closely comparable unless obtained in closely comparable conditions. Solvents can have a substantial effect upon chemical shifts (66CR(B)(263)1227>, especially benzene (72JA8854). Table 7 lists some ring interproton coupling constants and Table 8 some shift values for disubstituted furans. Polysubstituted furans are covered in the reviews and compilations mentioned above. [Pg.556]


See other pages where Polysubstituted benzenes is mentioned: [Pg.169]    [Pg.169]    [Pg.725]    [Pg.552]    [Pg.83]    [Pg.185]    [Pg.191]    [Pg.581]    [Pg.54]    [Pg.725]    [Pg.293]    [Pg.129]    [Pg.223]    [Pg.184]    [Pg.5]    [Pg.97]    [Pg.97]    [Pg.97]    [Pg.99]    [Pg.101]    [Pg.103]    [Pg.105]    [Pg.107]    [Pg.271]    [Pg.725]    [Pg.286]    [Pg.170]    [Pg.435]    [Pg.219]    [Pg.131]   
See also in sourсe #XX -- [ Pg.261 ]

See also in sourсe #XX -- [ Pg.291 ]

See also in sourсe #XX -- [ Pg.889 , Pg.890 , Pg.891 , Pg.892 , Pg.893 , Pg.894 , Pg.895 , Pg.896 , Pg.897 , Pg.898 , Pg.899 ]

See also in sourсe #XX -- [ Pg.130 ]




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An Introduction to Organic Synthesis Polysubstituted Benzenes

Benzene derivatives polysubstituted

Benzene oxides polysubstituted

Electrophilic Aromatic Substitution in Polysubstituted Benzenes

Polysubstituted

Polysubstituted Benzene Hydrocarbons

Polysubstituted benzene rings

Polysubstituted benzenes, regioselective

Polysubstitution

Synthesis of Polysubstituted Benzenes

The Nomenclature of Disubstituted and Polysubstituted Benzenes

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