Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Bandwidth constant

The loss moduli (E") of the latex IPN s shown in Figures 4, 7 and 10 are lower than that of PEMA with its broad secondary loss maximum. A summary of the loss modulus behavior of all the materials is given in Table IV in the form of the temperature bandwidths and the temperature bandwidth constants, as determined by equation 1. The value of E was assumed to be the same for all the materials because of the unavailability of accurate E data and because the calculation of the temperature bandwidth constant is very sensitive to the selection of E . [Pg.322]

The importance of the concentration of polymer having a broad secondary loss maximum upon the loss modulus bandwidth of polymer blend materials is shown in Fig. 11 for the bulk polymerized IPN s of Huelck. (i ) The loss modulus temperature bandwidth constant is strongly dependent upon the concentration of methyl methacrylate, irrespective of whether methyl methacrylate is present in the matrix or the inclusions. Overall the Oberst type of analysis indicates that for a given type of polymer blend the area under the E" curve tends to be constant. In other words, one may have height or width but not both. [Pg.322]

The empirical temperature bandwidth constant (K), a measure of extensional damping effectiveness, is strongly affected by polymer secondary loss mechanisms. Polymers such as PMMA and PEMA form very effective damping materials because they possess broad temperature span lossy modulus curves. [Pg.325]

It was of general interest to investigate the effectiveness of the damping materials in terms of any synergisms that may arise because of special mixing modes. The bandwidth "constant K indeed is not a constant and depends on the chemistry and other factors of the system, see above. However K is only useful for loss moduli-temperature behavior. No similar theory for tan 6 temperature exists, and... [Pg.325]

Figure 11. Temperature bandwidth constant of Oberst (2) calculated for the bulk polymerized IPlfs of Huelck CIO ... Figure 11. Temperature bandwidth constant of Oberst (2) calculated for the bulk polymerized IPlfs of Huelck CIO ...
The pyrolysis of CR NH (<1 mbar) was perfomied at 1.3 atm in Ar, spectroscopically monitoring the concentration of NH2 radicals behind the reflected shock wave as a fiinction of time. The interesting aspect of this experiment was the combination of a shock-tube experiment with the particularly sensitive detection of the NH2 radicals by frequency-modulated, laser-absorption spectroscopy [ ]. Compared with conventional narrow-bandwidth laser-absorption detection the signal-to-noise ratio could be increased by a factor of 20, with correspondingly more accurate values for the rate constant k T). [Pg.2125]

As the number of elements in the mesh increases the sparse banded nature of the global set of equations becomes increasingly more apparent. However, as Equation (6,4) shows, unlike the one-dimensional examples given in Chapter 2, the bandwidth in the coefficient matrix in multi-dimensional problems is not constant and the main band may include zeros in its interior terms. It is of course desirable to minimize the bandwidth and, as far as possible, prevent the appearance of zeros inside the band. The order of node numbering during... [Pg.198]

Spectral bandwidth of excita- Stefan-Boltzmann constant a... [Pg.107]

Variable speed orders analysis In a variable-speed machine, the unique frequencies generated by components such as bearings and gear sets do not remain constant. As the speed changes, the unique frequency components vary in direct proportion to the speed change. For this type of machinery, the analyzer s orders analysis option is used to automatically adjust each of the filters used to set the bandwidth and narrowbands for each data set to the true machine speed. [Pg.715]

Back e.m.f. 505 Back titration 311, 324 Balance analytical care and use, 75 constant load, 73 electronic, 73 free swinging, 73 maximum load of, 74 single pan, 73 Balance top pan, 75 tare facility, 74 Balancing method 652, 656 Bandwidth 663... [Pg.857]

When the silver nanocrystals are organized in a 2D superlattice, the plasmon peak is shifted toward an energy lower than that obtained in solution (Fig. 6). The covered support is washed with hexane, and the nanoparticles are dispersed again in the solvent. The absorption spectrum of the latter solution is similar to that used to cover the support (free particles in hexane). This clearly indicates that the shift in the absorption spectrum of nanosized silver particles is due to their self-organization on the support. The bandwidth of the plasmon peak (1.3 eV) obtained after deposition is larger than that in solution (0.9 eV). This can be attributed to a change in the dielectric constant of the composite medium. Similar behavior is observed for various nanocrystal sizes (from 3 to 8 nm). [Pg.321]

Experimentally, dvz is directly proportional to the laser bandwidth and is a constant dvx is determined by the slit width and is inversely proportional to the ion arrival time (i.e. a ID solid angle factor) and dvy/dt denotes the time-to-speed transformation in the ion TOF measurement, which can readily be derived from the equation of motion. It was found... [Pg.10]

For the Normal distribution, the exponential term has become a constant, and we see that the maximum magnitude of the derivative is inversely proportional to <72 (for the constant area expression) or inversely as a (for the constant height expression). This confirms our observation from figure 54-1. For the Lorentzian distribution, we see that the derivative decreases with the second power of the bandwidth. [Pg.344]

The vibrational frequency of the special pair P and the bacteriochlorophyll monomer B have also been extracted from the analysis of the Raman profiles [39,40,42,44,51]. Small s group has extensively performed hole-burning (HB) measurements on mutant and chemically altered RCs of Rb. Sphaeroides [44,45,48-50]. Their results have revealed low-frequency modes that make important contribution to optical features such as the bandwidth of absorption line-shape, as well as to the rate constant of the ET of the RCs. [Pg.4]

That is, Xw( ) has the Lorentzian shape function. The bandwidth is determined by the damping (or dephasing) constant. [Pg.49]

Remember that the NEP is defined as the incident signal power required to obtain a signal equal to the noise in 1 Hz bandwidth. Note that NEP is a measure of the S/N ratio, not just noise. The NEP and r both depend on the thermal conductance G, and sensitivity and speed of response can be traded off by varying G, with the constant NEP, the value of (r)1/2 being a useful figure of merit. [Pg.337]

Figure 1.4 shows a significant deviation between the isolated cluster calculations and the full calculation. The situation is, however, considerably improved by the presence of the classical point charges in the QM/MM calculation. Here the whole bandwidth of chemical shielding constants is present, and correlation with the reference values is excellent. [Pg.32]


See other pages where Bandwidth constant is mentioned: [Pg.322]    [Pg.328]    [Pg.322]    [Pg.328]    [Pg.716]    [Pg.1210]    [Pg.1234]    [Pg.1522]    [Pg.387]    [Pg.292]    [Pg.293]    [Pg.135]    [Pg.427]    [Pg.59]    [Pg.373]    [Pg.508]    [Pg.567]    [Pg.117]    [Pg.205]    [Pg.325]    [Pg.420]    [Pg.222]    [Pg.150]    [Pg.163]    [Pg.129]    [Pg.148]    [Pg.149]    [Pg.8]    [Pg.224]    [Pg.284]    [Pg.471]    [Pg.473]    [Pg.80]    [Pg.391]   
See also in sourсe #XX -- [ Pg.322 , Pg.326 ]




SEARCH



Bandwidth

© 2024 chempedia.info