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Aromatic nucleus, aliphatic bases with

The Group Containing Aliphatic Bases with an Aromatic Nucleus... [Pg.144]

Because primary aromatic amines are weaker bases/nucleophiles than aliphatic (due to interaction of the electron pair on N with the n orbital system of the aromatic nucleus), a fairly powerful nitrosating agent is required, and the reaction is thus carried out at relatively high acidity. Sufficient equilibrium concentration of unprotonated... [Pg.121]

Unsymmetrical secondary amines are readily prepared in good yields by the catalytic reduction of Schiff bases at moderate temperatures in high-or low-pressure equipment. Many examples have been cited. The intermediate imines are prepared from primary amines and aldehydes—very seldom from ketones—and may be used without isolation (cf. method 431). For the preparation of aliphatic amines, e.g., ethyl-w-propylamine and n-butylisoamylamine, a prereduced platinum oxide catalyst is preferred with alcohol as the solvent. Schiff bases from the condensation of aromatic aldehydes with either aromatic or aliphatic amines are more readily prepared and are reduced over a nickel catalyst. In this manner, a large number of N-alkylbenzylamines having halo, hydroxyl, or methoxyl groups on the nucleus have been made. Reductions by means of sodium and alcohol and lithium aluminum hydride have also been described,... [Pg.782]

The bromine linked to a double bond or linked to an aromatic nucleus are much more stable structures (not easily decomposed to HBr as dibromo neopentylglycol, a saturated aliphatic bromine compound). Thus, a very successful bromine containing diol, produced industrially [4, 24], is based on tetrabromophthalic anhydride. Tetrabromophthalic anhydride is reacted first with diethylene glycol and the resulting half ester is reacted with propylene oxide (PO) (reaction 18.5) [3]. [Pg.483]

Procedures for the identification of this class of compounds can be divided into methods for the identification of alkyl and cycloalkyl halogenides and methods for the identification of aromatic halo compounds. The type of bond between the halogen and the rest of the molecule is decisive for the choice of the identification procedure. While the procedures for the identification of halo compounds with halogen atom boimd to an aliphatic carbon are based on the exchange of a halogen by a suitable residue, the identification of compounds with halogen bound to an aromatic nucleus is generally carried out by additional substitution of the aromatic nucleus. [Pg.136]

This reaction is based on the formation of a color in a mixture of an aqueous sodium nitroprusside solution with carbonyl compounds in an alkaline medium. A positive test is obtained with aliphatic and certain aromatic aldehydes and aromatic and aliphatic ketones. The literature data on this reaction are conflicting and no general rule can be expressed about which carbonyl compounds give the reaction and which do not. For example, the color is not produced with formaldehyde, glyoxal, benzaldehyde, o-hydroxy-benzaldehyde, chloral, vanillin, benzophenone, naphthyl phenyl ketone, trihydroxybenzophenone, benzil, acetophenones substituted on the aromatic nucleus with hydroxyl, etc. The reaction can therefore be used for the differentiation of certain types of aldehydes and ketones, as, for example, acetaldehyde from formaldehyde, and acetophenone from benzophenone or hydroxyacetophenone, etc. Further, various colors formed in alkaline media or after the subsequent acidification of the reaction mixture can also be used for differentiation. Sodium hydroxide can be replaced by ammonia, piperidine... [Pg.234]


See other pages where Aromatic nucleus, aliphatic bases with is mentioned: [Pg.121]    [Pg.143]    [Pg.13]    [Pg.327]    [Pg.72]    [Pg.72]    [Pg.42]    [Pg.42]    [Pg.13]    [Pg.414]    [Pg.362]   
See also in sourсe #XX -- [ Pg.144 ]




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Aliphatic bases

Aliphatic—aromatic

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