Equation for area

For bubble caps, Ki is the drop through the slots and Ko is the drop through the riser, reversal, and annular areas. Equations for evaluating these terms for various bubble-cap designs are given by BoUes (in chap. 14 of Smith, Equilibrium Stage Processes, McGraw-HiU, New York, 1963), or may be found in previous editions of this handbook. 

STRUCTURAL VOLUME PARAMETER OF UKIQUAC EQUATION STRUCTURAL AR A aARAMETEP FOR UNIOUAC EQUATION STRUCTURAL AREA PARAMETER FOR MODIFIED UNIOUAC EQUAT ION... 

Were we can give these equations for the heat transfer process along radius R. The other processes of heat transfer can be simulated analogously by changing formula for heat transfer area and distances between centers of cells. For Dirichlet cells, bordering a gas medium, an equation of heat balance can be written in the form ... 

A fractal surface of dimension D = 2.5 would show an apparent area A app that varies with the cross-sectional area a of the adsorbate molecules used to cover it. Derive the equation relating 31 app and a. Calculate the value of the constant in this equation for 3l app in and a in A /molecule if 1 /tmol of molecules of 18 A cross section will cover the surface. What would A app be if molecules of A were used ... 

Pressure-area isotherms for many polymer films lack the well-defined phase regions shown in Fig. IV-16 such films give the appearance of being rather amorphous and plastic in nature. At low pressures, non-ideal-gas behavior is approached as seen in Fig. XV-1 for polyfmethyl acrylate) (PMA). The limiting slope is given by a viiial equation... 

Adsorption isotherms in the micropore region may start off looking like one of the high BET c-value curves of Fig. XVII-10, but will then level off much like a Langmuir isotherm (Fig. XVII-3) as the pores fill and the surface area available for further adsorption greatly diminishes. The BET-type equation for adsorption limited to n layers (Eq. XVII-65) will sometimes fit this type of behavior. Currently, however, more use is made of the Dubinin-Raduschkevich or DR equation. Tliis is Eq. XVII-75, but now put in the form... 

The van der Waals p., p. isothenns, calculated using equation (A2.5.3), are shown in figure A2.5.8. It is innnediately obvious that these are much more nearly antisynnnettic around the critical point than are the conespondingp, F isothenns in figure A2.5.6 (of course, this is mainly due to the finite range of p from 0 to 3). The synnnetry is not exact, however, as a carefiil examination of the figure will show. This choice of variables also satisfies the equal-area condition for coexistent phases here the horizontal tie-line makes the chemical potentials equal and the equal-area constniction makes the pressures equal. 

In applying quantum mechanics to real chemical problems, one is usually faced with a Schrodinger differential equation for which, to date, no one has found an analytical solution. This is equally true for electronic and nuclear-motion problems. It has therefore proven essential to develop and efficiently implement mathematical methods which can provide approximate solutions to such eigenvalue equations. Two methods are widely used in this context- the variational method and perturbation theory. These tools, whose use permeates virtually all areas of theoretical chemistry, are briefly outlined here, and the details of perturbation theory are amplified in Appendix D. 

Like the analogous equation for capillary condensation (Equation (3.74) Equation (3.81) is based on the tacit assumption that the pore is of constant cross-section. Integration of Equation (3.81) over the range of the mercury penetration curve gives an expression for the surface area -4(Hg) of the walls of all the pores which have been penetrated by the mercury ... 

In writing the present book our aim has been to give a critical exposition of the use of adsorption data for the evaluation of the surface area and the pore size distribution of finely divided and porous solids. The major part of the book is devoted to the Brunauer-Emmett-Teller (BET) method for the determination of specific surface, and the use of the Kelvin equation for the calculation of pore size distribution but due attention has also been given to other well known methods for the estimation of surface area from adsorption measurements, viz. those based on adsorption from solution, on heat of immersion, on chemisorption, and on the application of the Gibbs adsorption equation to gaseous adsorption. 

The equations for counterflow ate identical to equations for parallel flow except for the definitions of the terminal temperature differences. Counterflow heat exchangers ate much mote efficient, ie, these requite less area, than the parallel flow heat exchangers. Thus the counterflow heat exchangers ate always preferred ia practice. 

It has become quite popular to optimize the manifold design using computational fluid dynamic codes, ie, FID AP, Phoenix, Fluent, etc, which solve the full Navier-Stokes equations for Newtonian fluids. The effect of the area ratio, on the flow distribution has been studied numerically and the flow distribution was reported to improve with decreasing yiR. 

The quantity of undrainable residual moisture caimot be predicted without the benefit of experimental data. Equation 17 (6) indicates the important parameters where the exponents were determined using limited experimentation. Introducing the approximation that is proportional to 1/d, where s is the specific surface area per weight of solid, the modified equation for undrainable liquid becomes... 

Using this equation, the approximate (T — T ) value required for a film of a thermoplastic copolymer to be dry-to-touch, ie, to have a viscosity of 10 mPa-s(=cP), can be estimated (3,4). The calculated (T — T ) for this viscosity is 54°C, which, for a film to be dry-to-touch at 25°C, corresponds to a T value of —29 "C. The calculated T necessary for block resistance at 1.4 kg/cm for two seconds and 25°C, ie, rj = 10 ° mPa(=cP), is 4°C. Because the universal constants in the WLF equation are only approximations, the T values are estimates of the T requited. However, if parameters such as the mass per area appHed for blocking were larger, the time longer, or the test temperature higher, the T of the coating would also have to be higher. 

The term in equation 42 is called a Souders-Brown capacity parameter and is based on the tendency of the upflowing vapor to entrain Hquid with it to the plate above. The term E in equation 43 is called an E-factor. and E to be meaningful the cross-sectional area to which they apply must be specified. The capacity parameter is usually based on the total column cross section minus the area blocked for vapor flow by the downcomer(s). Eor the E-factor, typical operating ranges for sieve plate columns are... 

Equation for is dimensional. Fit to data for effective area quite good for distillation. Good for absorption at low values of Nr.ai Red) correlation is too high at higher values of (Nca,L X A/fle.c)-... 

Section 10 of this Handbook describes the use of orifice meters for flow measurement. In addition, orifices are commonly found within pipelines as flow-restric ting devices, in perforated pipe distributing and return manifolds, and in perforated plates. Incompressible flow through an orifice in a pipehne as shown in Fig. 6-18, is commonly described by the following equation for flow rate Q in terms of pressure drop across the orifice Ap, the orifice area A, the pipe cross-sectional area A, and the density p. 

Equivalent-Area Concept The preceding equations for batch operations, particularly Eq. 11-35 can be appliedforthe calculation of heat loss from tanks which are allowed to cool over an extended period of time. However, different surfaces of a tank, snch as the top (which would not be in contact with the tank contents) and the bottom, may have coefficients of heat transfer which are different from those of the vertical tank walls. The simplest way to resolve this difficulty is to nse an equivalent area A in the appropriate equations where... 

Bakowsld [B/ Chem. Eng., 8, 384, 472 (1963) 14, 945 (1969)]. It is based on tbe assumption that tbe mass-transfer rate for a component moving to tbe vapor phase is proportional to tbe concentration of tbe component in tbe liquid and to its vapor pressure. Also, tbe interfacial area is assumed proportional to liquid depth, and surface renewal rate is assumed proportional to gas velocity. The resulting general equation for binaiy distillation is... 

The former requires measurement of the initial settling rate of a pulp at different solids concentrations varying from feed to final underflow value. The area reqmrement for each solids concentration tested is calciilated by equating the net overflow rate to the corresponding interfacial settling rate, as represented by the following equation for the unit area ... 

Vessel Siting The area needed for vapor disengaging is calculated by the equations given earlier in the section on horizontal blowdown drums. 

In this chapter some important equations for corrosion protection are derived which are relevant to the stationary electric fields present in electrolytically conducting media such as soil or aqueous solutions. Detailed mathematical derivations can be found in the technical literature on problems of grounding [1-5]. The equations are also applicable to low frequencies in limited areas, provided no noticeable current displacement is caused by the electromagnetic field. 

Component reliability will vary as a function of the power of a dimensional variable in a stress function. Powers of dimensional variables greater than unity magnify the effect. For example, the equation for the polar moment of area for a circular shaft varies as the fourth power of the diameter. Other similar cases liable to dimensional variation effects include the radius of gyration, cross-sectional area and moment of inertia properties. Such variations affect stability, deflection, strains and angular twists as well as stresses levels (Haugen, 1980). It can be seen that variations in tolerance may be of importance for critical components which need to be designed to a high reliability (Bury, 1974). 

Erom C-1.1 the equation for capacitance of a parallel plate capacitor (plate area A, separation d) s ... 

From Figure 10.11, using the equation for the area of a trapezoid... 

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