Application of Isotherms

Example 4 Application of Isotherms Thomas [Ann. N.Y. Acad. Sci., 49, 161 (1948)] provides the following Langmuir isotherm for the adsorption of anthracene from cyclohexane onto alumina ... 

Figure 6.11 shows a famous example of the application of isothermal calorimetry. Gordon (1955) deformed high-purity copper and annealed samples in his precision calorimeter and measured heat output as a function of time. In this metal, the heat output is strictly proportional to the fraction of metal recrystallised. 

Third, the rheological properties of plastisols during isothermal filling of thin moulds (the applicability of isothermal injection into thin flat moulds will be referred to below) at some medium range y (corresponding to the flow with qx) and considerations of dimensions suggest that the filling time for a flat mould, tm, as a function of pressure may be represented as ... 

Ladbury JE (2004) Application of isothermal titration calorimetry in the biological sciences things are heating up . Biotechniques 37(6) 665-687 Leung DH, Bergman RG, Raymond KN (2008) Enthalpy-entropy compensation reveals solvent reorganization as a driving force for supramolecular encapsulation in water. 1 Am Chem Soc... 

Phipps MA, Mackin LA. Application of isothermal microcalorimetry in solid state drug development. PSTT 2000 3(1) 9 17. 

Application of Isothermal Titration Calorimetry to Thermodynamic Studies of Biomolecular Interactions. 

A survey of the year 2002 hteramre on applications of isothermal titration calorimetry. J. Mol. Recognit. 16. 383-391. 

Buckton G. Principles and Pharmaceutical Applications of Isothermal Microcalorimetry. In Craig IX M. Reading M. eds. Thermal Analysis of Pharmaceuticals. Boca Raton. USA CRC Press. 2(X)7 265-86. 

Jakobsen DF, Frokjer S, Larsen C, Niemann H, Buur A. Application of isothermal microcalorimetry in preformulation. J. Hygroscopicity of drug substances. Int J Pharm 1997 156 67-77. 

There is another particular application of isothermal DSC that requires modification of a traditional DSC, and this is in rapid photopolymerization (Scott et al, 2002) such as of multifunctional acrylates (Peinado et al, 2002). In a typical photo-DSC experiment, the... 

Ladbury, J. E., and Chowdhry, B. Z. (1996). Sensing the heat The application of isothermal titration calorimetry to thermodynamic studies of biomolecular interactions. Chem. Biol. 3(10), 791-801. 

Buckton, G. (1995) Applications of isothermal micrpharmaceutical sciences, Thermochim. Acta, 148,117-129. 

Several applications of isothermal titration calorimetry to biochemical systems have been published recently. Franghanel et al. [240] proposed a new calorimetric method to investigate slow conformational changes in proteins and peptides, Tsamaloukas et al. [241] studied the interactions of cholesterol with unsaturated phospholipids and D Amico et al. [242] determined the binding enthalpies of a-amylases to different substrates. 

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