Antimony Chloride, Solution

Antimony Trichloride Solution, Antimony chloride solution liquid butter of antimony. Contains 36-38% SbClj and 10-12% free HQ. 

According to Hargreaves, finely powdered ore can bo troatofl with hot hydrochloric acid. Lime is used to neutralise tho solution, which is then to be treated with zinc or iron for precipitation of the antimony. The precipitated metal is to be washed succossivoly with antimony chloride solution, hydrochloric acid, and water, and then fused with potash in crucibles. 

Hydrochloric acid digestion takes place at elevated temperatures and produces a solution of the mixed chlorides of cesium, aluminum, and other alkah metals separated from the sUiceous residue by filtration. The impure cesium chloride can be purified as cesium chloride double salts such as cesium antimony chloride [14590-08-0] 4CsCl SbCl, cesium iodine chloride [15605 2-2], CS2CI2I, or cesium hexachlorocerate [19153 4-7] Cs2[CeClg] (26). Such salts are recrystaUized and the purified double salts decomposed to cesium chloride by hydrolysis, or precipitated with hydrogen sulfide. Alternatively, solvent extraction of cesium chloride direct from the hydrochloric acid leach Hquor can be used. 

Chlor-. of or combined with chlorine, chloro (as Chlorbenzoeadure, chlorobenzoic acid), chloride of (as Chlorzink, zinc chloride), chlorahnlich, a. like chlorine, chlorinous. Chlor-alaun, m. chloralum, -alkalien, n.pl. alkali-metal chlorides, -allyl, n, allyl chloride, -aluminium, n. aluminum chloride, -ammon, m., -ammonium, n. ammonium chloride, -amyl, n, amyl chloride, -antimon, n, antimony chloride, -arsenlk, n. chloride of arsenic, -arsenikldsung, /, (Pkarm.) solution of arsenious add, hydrochloric solution of arsenic, -arsinkampfstoff, m. chlorodi-phenylarsine, adamsite, chlorartig, a. like chlorine, chlorinous,... 

Another way to obtain, under suitable conditions, stable dispersions of sur-factant-stabihzed nanoparticles consists in the direct suspension of some materials in w/o microemulsions. The formation of stable dispersions of rutile (size 80-450 mn) and carbon black (200-500 nm) in AOT// -xylene and of rutile, lead chloride, aluminium, antimony in solutions of calcium soaps in benzene has been reported [219,220],... 

V. H. Aprahamian and D. G. Demopoulos, The Solution Chemistry and Solvent Extraction Behaviour of copper, iron, nickel, zinc, lead, tin, Ag, arsenic, antimony, bismuth, selenium and tellurium in Acid Chloride Solutions Reviewed from the Standpoint of PGM Refining, Mineral Processing and Extractive Metallurgy Review, Vol. 14, p. 143,1995. 

As might now be expected, certain similar occurrences are present in copper electrolysis. Table IV lists the concentration of antimony analyzed in the copper cathode when various levels of the additives were in the electrolyte. The data indicate a critical concentration of antimony in solution is necessary (approximately 300 ppm) before appreciable amounts are taken into the cathode. Glue does not alter the results for 600 ppm antimony but chloride ion reduces the effective antimony to 200 ppm or less. 

A brownish-purple solid salt, T SbCls, made by reacting thianthrene with antimony(V) chloride at room temperature in chloroform (62BCJ1137, 62JCS4963 67BCJ2539), was shown, by comparison with a methylene chloride solution of the salt, to have the radical as free in the solid as in solution (69BCJ548). Antimony(V) chloride was used to oxidize a thianthrene-containing polymer, —[T—C(Ph)=C(Ph) presumably... 

By pouring a solution of antimonious chloride in dilute hydrooUorio acid into a boiling solution of sodic carbonate —... 

Zinc chloride is much less reactive than aluminum chloride and usually requires higher reaction temperatures. However, it has the advantage that, unlike aluminum chloride, it is less sensitive to moisture and can sometimes even be used in aqueous media.88 Concentrated aqueous solutions of ferric chloride, bismuth chloride, zinc bromide, stannous chloride, stannic chloride, and antimony chloride are also alkylation catalysts, particularly in the presence of hydrochloric acid.89... 

Schmidt, a complex is formed between methyl azide and antimony pentachloride in methylene chloride solution.1 1 Under the influence of dry hydrogen chloride, the complex decomposes at room temperature into methylenimmonium hexachloroantimonate (26) (Scheme V). By use of deuterium chloride instead of hydrogen chloride, N-monodeuterated methylenimmonium hexachloroantimonate was obtained. 

Mass-Action.—The action of mass, that is, the quantity of a compound in unit volume, is well illustrated by the action of water on antimonious chloride. A solution of this salt in hydrochloric acid gives a precipitate on adding water SbCl3.nHCl.Aq + H20 = OSbCl + (n + zJHCl.Aq. Here the increase in the number of molecules of water... 

Antimony (III) chloride-acetic acid A 20% antimony (III) chloride solution in 75% chloroform-acetic acid solution is sprayed on the plate, which upon heating at 100°C (5 min) yields a variety of colors. 

Antimony (V) chloride A 20% antimony (V) chloride solution in chloroform or carbon tetrachloride is sprayed on the plate yielding a variety of colors upon heating. 

Infrared and Raman spectroscopy have been extensively employed to elucidate the nature of bonding in these derivatives. For example, the Raman spectrum of tetramethyl-antimony chloride in aqueous solution has been found to be consistent with tetrahedral... 

Ferric ammonium antimony chloride, 2FeCl3.9NH4C1.3SbCl4, crystallises in black octahedra from solutions of the constituent chlorides in concentrated hydrochloric acid.8... 

ANTIMONIO (TRICLORURO di) ANTIMONOUS CHLORIDE ANTIMONOUS CHLORIDE (DOT) ANTIMONTRICHLORID ANTIMONY BUTTER ANTIMONY CHLORIDE ANTIMONY CHLORIDE (DOT) O ANTIMONY TRICHLORIDE ANTIMONY TRICHLORIDE, Uquid (DO"P ANTIMONY TRICHLORIDE, solid (DOT) ANTIMONY TRICHLORIDE, solution (DOT) ANTIMO-ONTRICHL-ORIDE BUTTER of ANTIMONY CHLORID ANTIMONITY CHLORURE ANTIMONIEUX C.I. 77056 STIBINE, TRICHLORO- TRICHLOROSTIBINE TRICHLORURE d ANTIMOINE... 

Replacement of halogen atoms by alkoxy groups may be hindered in N(7)- and N(9)-unsubstituted purines because of anion formation although this has been overcome to some extent by use of antimony chloride followed by the alcohol (71MI40904). Aryloxypurines have similarly been prepared from halogenopurines and hot alkaline phenol solutions. Since alkylation of oxopurines tends to lead almost exclusively to Af-alkyl derivatives (see Section 4.09.5.2.2(iv)), direct replacement of halogen atoms assumes special importance as a route to the alkoxypurine derivatives. 

The action of the chlorides of these elements still further illustrates the progressive change in their chemical properties. The complete hydrolysis of the chlorides of phosphorus has already been observed. Arsenious chloride becomes hydrolyzed to a very great extent although some arsenious ions still exist in solution, as was stated above. Antimony chloride forms an oxychloride and bismuth chloride a basic chloride when these compounds are added to water. These facts indicate partial hydrolysis in both cases. 

Chloro(dimethyl)sulfonium salts are readily formed in 92% yield by the action of chlorine on the dimethyl sulfide-antimony chloride adduct627 in methylene dichloride solution ... 

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