Anodic stripping voltammetry ASV

ASV was originally performed with a mercury electrode either in the form of a hanging mercury drop (HMDE) or a thin mercury 

Johnson et al. [81] have developed a pulsed anodic technique at platinum flow-through electrodes and have applied it successfully to the detection of a number of classes of molecules such as alcohols and carbohydrates, amines, and sulphur compounds. The method has also been extended to the detection of analytes at potentials where they are not electroactive. This procedure has been used to detect Cl and CN [82, 83]. 

The key to the characterization of a particular analyte is thus the extent to which it modifies the chronoamperometric response of the platinum electrode to an anodic potential step. 

This is probably the most sensitive technique for lead, and in very low level work the avoidance of contamination is likely to be a more major problem than the approach of the analytical detection limit. Sensitivity may be improved even further by the use of alternative electrodes (e.g. glassy carbon) in place of the commonly used hanging mercury drop. Advantages of ASV are the possibility of simultaneous determination of four metals (Pb, Cd, Cu, Zn) in one sample, and the freedom from matrix effects as a standard additions technique is always used. 

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The speciation scheme of Batley and Florence requires eight measurements on four samples. After removing insoluble particulates by filtration, the solution is analyzed for the concentration of anodic stripping voltammetry (ASV) labile metal and the total concentration of metal. A portion of the filtered solution is passed through an ion-exchange column, and the concentrations of ASV metal and total metal are determined. A second portion of the filtered solution is irradiated with UV light, and the concentrations of ASV metal... 

The methods of investigation of metal species in natural waters must possess by well dividing ability and high sensitivity and selectivity to determination of several metal forms. The catalytic including chemiluminescent (CL) techniques and anodic stripping voltammetry (ASV) are the most useful to determination of trace metals and their forms. The methods considered ai e characterized by a low detection limits. Moreover, they allow detection of the most toxic form of metals, that is, metal free ions and labile complexes. 

Describe clearly the principle and operation of potentiometric stripping analysis (PSA). How it is differed from anodic stripping voltammetry (ASV) What is the quantitative signal What is its advantage over ASV ... 

Anodic stripping voltammetry (ASV) has been used extensively for the determination of heavy metals in samples of biological origin, such as lead in blood. ASV has the lowest detection limit of the commonly used electroanalytical techniques. Analyte concentrations as low as 10 M have been determined. Figure 16 illustrates ASV for the determination of Pb at a mercury electrode. The technique consists of two steps. The potential of the electrode is first held at a negative value for several minutes to concentrate some of the Pb " from the solution into the mercury electrode as Pb. The electrode process is... 

We shall now consider the electrochemical apparatus used (electrodes and electrolytic cell) and the three steps in its procedure more closely, especially for anodic stripping voltammetry (ASV) as most important application. 

Fig. 18b. 12. (a) Voltage-time profile for anodic stripping voltammetry (ASV) and (b) ASV of an unknown solution with two aliquot additions of 100 ppb each of Cd and Pb in the final solution. The peak at —190 mV is that of Cu present in the unknown. Experimental conditions Initial deposition potential, Ed = —800 mV, final potential = 0, deposition time, td — 120 s, quite time, tq — 30 s, step potential = 5 mV, pulse height = 20 mV, pulse delay = 100 ms, sampling width — 17 ms, and sampling frequency — 6000 Hz. 

The voltammetric sensitivity can be improved further by analyte preconcentration in conjunction with stripping analyses (cf. Chapter 5). Anodic stripping voltammetry (ASV) (Section 6.5) is the best known of the stripping techniques, and is capable of detecting concentrations as low as 10 " mol dm . Differential pulse voltammetry, when applied to stripping, can further improve the accuracy of electroanalytical measurement and, in principle, further improve the sensitivity of the technique. 

Anodic stripping voltammetry (ASV). This is an electrochemical technique in which the element to be analyzed is first deposited on an electrode and then redissolved, that is, stripped, from the electrode to form a more concentrated solution. For example, a drop of mercury hanging from a platinum electrode in a solution containing the species to be measured has been used as the deposition electrode. A potential slightly more negative than the half-wave potential for the ion of interest is applied to deposit the element on the electrode. After deposition of the metal for a given... 

Anodic stripping voltammetry (ASV) is the most common version of stripping analysis. It involves the reduction of a metal ion to the metal (which usually dissolves in mercury, i.e., amalgam formation), as the preconcentration step ... 

Anodic stripping voltammetry (ASV) is the oldest, and still the most widely used version of stripping analysis [3]. The technique is applicable to metal ions that can be readily deposited at the working electrode, and particularly for those metals that dissolve in mercury. In this case, the metals are being preconcentrated by electrodeposition into a small-volume mercury electrode (a thin mercury film or a hanging mercury drop). The preconcentration is done by cathodic deposition at a controlled potential and time. The deposition potential is usually ca. 0.3 Y more negative than E° for the least easily reduced metal ion to be determined. The metal ions reach the mercury electrode by diffusion and convection, where they are reduced and concentrated as amalgams ... 

MCPE = magnet carbon paste electrode, SWASV = square wave anodic stripping voltammetry, ASV = anodic stripping voltammetry, PSA = potentiometric stripping analysis, SPEs = screen-printed electrodes, TFGE = thick-film graphite electrode, GCE = glassy carbon electrode. 

Separations may also be made on the basis of complex stability In such cases, a complexant is added to the sample and metal complexes are fractionated by a particular technique and their concentration is monitored (Apte and Batley, 1995 Miller and Bruland, 1997), typically by fluorescence (Aster et al., 1997), ultraviolet-visible (UV-Vis) spectrophotometry (Senesi, 1992 Bjorklund and Morrison, 1997), atomic absorption following solvent extraction (Itabashi et al., 1997), cathodic stripping voltammetry (CSV) (van den Berg et al., 1990 Yokoi et al., 1995 Maxwell and Smyth, 1996 Achterberg et al., 1997) or anodic stripping voltammetry (ASV)... 

Anodic stripping voltammetry (ASV) is a very sensitive instrumental technique for the measurement of metals in solution. Of particular importance are determinations of reactive or ASV-labile metal concentrations. ASV-labile metal is defined as the fraction of the total metal concentration that is measured under a defined set of ASV and solution conditions. Labilities of metal species in natural water have been related to toxicities. Thus, one objective of speciation analysis carried out by ASV is to find conditions where the ASV-labile fraction is a close approximation to the toxic fraction of a metal. In experimental terms, the ASV-labile metal should be equal to the electroactive fraction of the metal. The latter... 

Electrochemical methods for arsenic determination were initially based on polarography with a dropping mercury electrode. More recent methods, based on anodic stripping voltammetry (ASV), anodic stripping chronopotentiometry (SC), and CSV, rely almost exclusively on the detection of As(III), since As(V) is detected with difficulty because of its perceived electro-inactivity. 

Electrochemical techniques anodic stripping voltammetry (ASV) and cathodic stripping voltammetry (CSV) for determining trace elements, and potentiometric sensors for determining dissolved gases (C02, N02, S02, NH3, H2S, HCN, and HF) as well as chloride, fluoride, cyanide, and sulfide. 

Voltammetric techniques have also been employed for on-chip EC detection. For instance, anodic stripping voltammetry (ASV) was used to detect Pb in a Si-Pyrex chip [770] or a polyimide chip [229]. 

The four variations of this technique are to be found in Table 14.2. The schemes of operation are shown in Fig. 14.6. Important applications for trace metals are the use of anodic stripping voltammetry (ASV) to determine trace quantities of copper, cadmium, lead and zinc, and adsorptive stripping voltammetry (AdSV) of trace quantities of nickel and cobalt—pre-concentration by adsorption accumulation of the oxime complexes followed by reduction to the metal is employed, as reoxidation of these metals in ASV is kinetically slow and does not lead to well-defined stripping peaks. 

Anodic stripping voltammetry (ASV) can be very usefiil in studies of metal complexation in natural aquatic systems. The technique can be used, under favorable conditions, to determine metal concentrations as low as 10 molL. Further, and again under appropriate conditions, stabihty constants may be determined in a manner analogous to that used in polarography. The principle of the technique involves deposition of a metal ion in reduced form on a static mercury electrode followed by reoxidation through reversal of the polarity. The reoxidation current is related to the metal concentration in the analyte. In the presence of a... 

Anodic stripping voltammetry (ASV) was applied to the determination of copper traces present as Cu(dik)2. The differential pulse technique was used to strip the amalgamated copper from a hanging mercury drop electrode. The experimental variables such as scan rate of electrode potential, deposition potential, deposition time and stirring speed of the solution could be optimized. The linear range of the calibration plot was 0.05-1 (xM and the LOD was 0.014 fiM Cu(II). A method was used for the determination of copper in breast milk and beer as typical examples of application, consisting of minerahzation of the sample, extraction of Cu(II) from the aqueous solution with a 1 M solution of acacH in chloroform and ASV end analysis . 

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