5- Anilino-4-hydroxy-2-methyl

By this method, sulfur dyes derived from 4-hydroxydiphenylamine are seen to be essentially identical. Similarly, the sulfur dye from 7-anilino-9-methyl-l,2,4-trichlorophenothiazin-3-one (21) and the sulfur dye from 4-anilino-4 -hydroxy-2-methyldiphenylamine (22) were compared and found to be almost identical, as was the related trichlorophenothiazinone derivative (23) from carbazole when compared with Hydron Blue indophenol, Cl... 

Anilinotrimethylolmetbane N-(Trimethylol-me thane) aniline, P kenylaminotrimethylol-metbane N-Pbenyl-(tris kydroxymetbyl)-methylamine 2-Anilino-2-hydroxymethyl-1,3-dihydroxypropane 2-Anilino-2- hydroxy-methyl-1,3-propanediol or Phenyltrimethylol-methylamine, C6H5, NH.C(CH2OH)3. This may be considered as the parent compd of the derivs described below ... 

Anilino-4-methyl- -2-oxid E2, 662, 784 -Anilino-4-meth yl- -2-selenid K2, 784, 787 -Anihno-4-methyl- -2-sulfid E2, 662 -Benzoyl-4-methyl- -2-oxid E2, 382 -Benzyl-5,5-bis-[chlormethylJ- -2-oxid E2, 367 -Benzyl-5-chlormethyl-5-ethyl- -2-oxid E2, 367 -(Bis- 2-chlor-ethyl]-amino)-5,5-bis-[hydroxy-methyl]- -2-oxid XII/2, 415 2-(Bis-[2-chlor-ethyl]-amino)- -2-oxid XII/2, 415... 

Phenyltrimethylolmethyl amine. See Anilino-trimethylolmethane A441-L N-Phenyl-(tris-hydroxy methyl)-mechylamine. 

Hydroxypyrazine 1 oxide was reduced with hydrogen at atmospheric pressure over Raney nickel to 2-hydroxypyrazine (108) [but failed to react with phosphorus trichloride in chloroform (108)], and 3-hydroxy-2-isobutyl-5-isopropylpyrazine 1,4-dioxide was reduced with hydrogen over nickel to 3-hydroxy-2-isobutyl-5-isopropylpyrazine (740a). 2-(A -Anilino-yV-methylcarbamoyl)-4-methyl-3oxo-3,4-dihydropyrazine 1 oxide with sodium dithionite produced 3-(A -anilino-A -methyl-carbamoyl)- -methyl-2oxo-l, 2-dihydropyrazine (1137). 

Cyan-2-(N-methyl-anilino)-4-methyl- 68 2-(Cyan-methyl)-4-hydroxy- 8, 10, 11 5-Cyan-2-methyl-4-phenyl- 152 5-Cyan-2-(4-methyl-phenyl)-4-trinuormethyl-a us 5-F1 uor-2-(4-methyl-phenyl)-4-trifl uor-methyl-1,3-thiazol/Kaliumcyanid 297 2-[l-Cyan-l-(methylthio-thiocarbouyl)-methyliden -4-pheny l-2,3-dihvdro- 233 5-Cyan-2-morpholino-4-phenyl- 136 2-[2-(3-Cyan-phenyl)-ethenyl]-4-isopropyl- 312... 

Athyl-benzoyl-amino)-l-liydroxy- 646 2-Xthyl-1 - [hutadicn-( 1,2)-yl J- 270 Amino- 570,1047, 1072, 1120. 1127, 1460, 1464, 1578 2-Atnino-l-acetyl- 993. 1100, 1268, 1312 4-Amino-1-acetyl- 993 2-(2-Amino anilino)-l.3.4-lrimelhyl- 1268 4-Ainino-l,3-dimethoxy- 994 2-Amino-3.5-dimethoxy-l -acetyl- 994 6-Amino-l.5-dimethyl- 1334 2-Amino-5-hydroxy-1 -acetyl- 567. 1269 2 mino-5-hydroxy-l,3-di-tert.-butyl- 1336 2-Amino-5-hydroxy-6-mcthyl-l-acetyl- 567 6-Amino-3-hydroxy methyl-1-acetyl- 567 6-Amino-3-hydro. y-2-mcthyl-l -acetyl- 567 6-Amino-5-[2-hydroxy-propvl-(2)]-l,3-di-lerl.-butvl-1342... 

The substituted 2-hydroxybenzophenone, 2-(2-hydroxy-4-di-n-butylamino)-benzoylbenzoic acid underwent reaction with 4-methoxy-2-methyldiphenyl-amine in concentrated sulphuric acid at 10-1 during 20 hours followed by work-up in alkaline solution and a final treatment by refluxing in hot toluene for 2 hours to give 2-anilino-3-methyl-6-dibutylaminofluoran in 88% yield (ref.81). 

Quinoline, amino-2-hydroxy-4-methyl-azo pigments from, 1, 334 Quinoline, 8-amino-6-methoxy-as antimalarial, 2, 517 Quinoline, 4-amino-2-methyl-protonation, 2, 341 Quinoline, anilino-3-substituted... 

CI 4-CH3 2-Carboxy-4-( 4-chlor-anilino) -3,6-dihydroxy-4 -methyl-... 78 180 4-(4-Chlor-anilino)-2,5-di-hydroxy-4 -methyl-. .. 98 198... 

Benzylische Acyloxy-Gruppen wie z.B. in 4,7-Diacetoxy-6-methoxy-2-methyl-l,2,3,4-te-trahydro-isochinolin werden bei der Reaktion mit primaren Aminen unter milden Bedin-gungen durch eine Alkylamino- Oder Arylamino-Gruppe ersetzt gleichzeitig wird die zwei-te Acetoxy-Gruppe im Molekul hydrolysiert, so daB man mit Ethylamin bzw. Anilin 4-Ethylamino-7-hydroxy-6-methoxy-2-methyl- (82%) bzw. 4-Anilino-7-hydroxy-6-meth-oxy-2-methyl-l,2,3,4-tetrahydro-isochinolin (66%) erhalt1. 

Verwcndet man in der 3. Stufe des angegebenen Formelschemas einen Aldehyd anstelle des Alkyl-bromids, so erhalt man einen jS-Amino-alkohol, z. B. durch Metallierung von (2-Anilino-ethyl)-quecksilber-bromid (aus Ethen durch Aminomercurierung) mit Phenyllithium und anschlicBende Umsetzung mit 2-Methyl-propanal l-Anilino-3-hydroxy-4-methyl-pentan (70%)2. 

QfN"CH3 + HO- Y0 20% 48 h 3-Hydroxy-2-hydrOXymethyl-l-methyl-4-( N-methyl-anilino)-1,2,3,4- tetrahydro-chinolin 45 7... 

Benzyl-diethoxy- E2, 134 Benzyl-diisopropyloxy- E2, 134 Benzyl-ethyl-phenyl- -tosylimid E2, 113 Benzyl-methyl-phenyl- -tosylimid E2, 113 Benzyloxy-diphenyl- E2, 17, 18 Benzyloxy-ethoxy-hydroxy- E2, 187 Bis-[2-biphenylyl]- E2, 876 [2,6-bis-(2-tetrahydropyranyloxy-methyl)-phenyl]-Bis-[4-brom-anilino]-phenyl- E2, 416 Bis-[2-brom-ethoxy]-(2-brom-ethyl)- E2, 196 Bis-[butylthio]-ethyi- E2, 79, 408 Bis-[2-chlor-cthoxy]-butyl- E2, 196 Bis-[2-chlor-ethoxy]-(2-chlor-ethyl)- E2, 196 Bis-[2-chlor-ethoxy]-methyl- E2, 196 Bis- 2-chlor-ethoxy]-phenyl- E2, 196, 197, 202 Bis- 2-ehlor-ethoxy]-(2-phcnyl-vinyl)- E2, 196 Bis-(2-ehlor-ethoxy]-vinyl- E2, 196 Bis-j 2-chlor-ethyl]-methyl- E2, 205 Bis-[chlormethyl]-dodecyl- E2, 22 Bis-12-cyan-ethyl]- E2, 223 Bis- diethylamino]-butyl- E2, 486 Bis-[ l-cthinyl-butyl]-phenyl- E2, 197 Bis-[ethoxycarbonyl-methyl]-chlor- E2, 251 Bis-[ethylthio]-ethyl- E2, 408 Bis-[4-methoxy-aniliiio]-phenyl- E2, 416 Bis-[4-methyl-phenylJ-phenyl- K2, 105 Bis- 4-methyl-phcnyl]-phenyl- -phenylsulfonvlimid E2, 105... 

Aminocarbonyl-ethyl)-dibenzyl- XII/1, 154 (Aminocarbonyl-methyl)-di-tert.-butyl- E2, 22 (l-Amino-ethyl)-hydroxy- E2, 309 (4-Amino-phenyl)-diphcnyl- XII/1, 149 [l-(4-Amino-phenyl)-vinyl]-hydroxy- El, 272 (3-Amino propyloxy) hydroxy El, 319 /<-Anilino benzyl) hvdmxy... 

Hydroximino-l-(4-methyl-phenyl)-E14b, 313 (aus En-on) fram-l-tN-Methyl-anilinojA-oxo-E16d, 794 (Anilinierung) Cyclopenten n.s-5-Anilino-3-hydroxy- Vl/la, 1, 461 Cyclopent[b indol 8b-Hydroxy-l,2,3,3a,4,8b-hexahydro- E6b/1, 577 (2-Br —anilin + R-CO-CI/... 

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